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1. 发明申请

WO1997041160A1 ALKYL METHACRYLATE POLYMERS 审中-公开
标题翻译：甲基丙烯酸烷基酯聚合物
公开(公告)号：WO1997041160A1
公开(公告)日：1997-11-06
申请号：PCT/GB1997001128
申请日：1997-04-24
申请人： N V RAYCHEM S A , RAYCHEM LIMITED , YU, Jianming , OVERBERGH, Noel , HUDSON, John, Michael , HAMMOND, Phillip, James
发明人： N V RAYCHEM S A , RAYCHEM LIMITED
IPC分类号： C08F20/18
CPC分类号： C08F220/18 , C08F297/026
摘要： M-A-M triblock copolymers of higher alkyl (especially isobornyl) methacrylates, potentially for forming gels of improved temperature rating over PMMA triblock gels, are synthesized by anionic polymerization of an alkylene (pref. butadiene or isoprene) mid-block (A) followed by anionic polymerization of the methacrylate end blocks (M) using alkali metal alkyl initiators. Mixed end blocks (M) comprising random or block copolymers of methylmethacrylate and one or more higher alkyl (pref. isobornyl) methacrylates are preferred for forming gels with elevated softening temperatures without loss of structure which apparently tends to occur with IBMA homopolymer ends blocks.
摘要翻译：通过阴离子聚合亚烷基（预丁二烯或异戊二烯）中间嵌段（A），然后进行阴离子聚合，合成高分子（特别是异冰片基）甲基丙烯酸酯的MAM三嵌段共聚物，潜在地用于形成改进的温度等级优于PMMA三嵌段凝胶的凝胶的甲基丙烯酸酯嵌段（M）使用碱金属烷基引发剂。包含甲基丙烯酸甲酯和一种或多种高级烷基（优选的异冰片基）甲基丙烯酸酯的无规或嵌段共聚物的混合端嵌段（M）优选用于形成具有升高的软化温度的凝胶而不损失明显倾向于与IBMA均聚物末端嵌段发生的结构。

2. 发明申请

WO8800603A3 GELS COMPRISING BLOCK COPOLYMERS 审中-公开
标题翻译：包含嵌段共聚物的凝胶
公开(公告)号：WO8800603A3
公开(公告)日：1988-03-24
申请号：PCT/GB8700506
申请日：1987-07-17
申请人： RAYCHEM LTD , FRANCIS JANE VALERIE , OVERBERGH NOEL MARCEL MICHIEL , VANSANT JAN LODEWIJK M F G
发明人： FRANCIS JANE VALERIE , OVERBERGH NOEL MARCEL MICHIEL , VANSANT JAN LODEWIJK M F G
IPC分类号： C08K5/01 , C08L53/00 , C08L53/02 , C08L71/12 , C08L71/04
CPC分类号： C08L53/02 , C08L2666/14
摘要： A gel or gelloid liquid-extended polymer composition having (i) an ASTM D217 cone penetration value within the range from 100 to 400 (10-1 millimetres), (ii) an ASTM D412 ultimate elongation greater than 100 % with substantially elastic deformation to an elongation of at least 100 %, (iii) an ASTM D412 ultimate tensile strength of less than 1 MegaPascal, and (iv) a dynamic storage modulus at 23oC of less than 50000 Pascals; the composition comprising an intimate mixture of a) mainly a block copolymer containing relatively hard blocks and relatively elastomeric blocks; b) additional polymer or copolymer material having at least partial compatibility with, and a higher glass transition, softening or melting temperature than, the hard blocks of the said block copolymer; and c) at least 500 parts by weight of extender liquid per 100 parts by weight of the said block copolymer, which liquid extends and softens the elastomeric blocks of the said block copolymer. SEBS triblock copolymers with polyphenylene ether "alloys" as the added material are preferred, the extender liquid preferably being an oil of substantially zero aromatic content.

3. 发明申请

WO1988000603A2 GELS COMPRISING BLOCK COPOLYMERS 审中-公开
标题翻译：包含嵌段共聚物的凝胶
公开(公告)号：WO1988000603A2
公开(公告)日：1988-01-28
申请号：PCT/GB1987000506
申请日：1987-07-17
申请人： RAYCHEM LIMITED , FRANCIS, Jane, Valerie , OVERBERGH, Noel, Marcel, Michiel , VANSANT, Jan, Lodewijk, M., F., G.
发明人： RAYCHEM LIMITED
IPC分类号： C08L53/02
CPC分类号： C08L53/02 , C08L2666/14
摘要： A gel or gelloid liquid-extended polymer composition having (i) an ASTM D217 cone penetration value within the range from 100 to 400 (10 millimetres), (ii) an ASTM D412 ultimate elongation greater than 100 % with substantially elastic deformation to an elongation of at least 100 %, (iii) an ASTM D412 ultimate tensile strength of less than 1 MegaPascal, and (iv) a dynamic storage modulus at 23 C of less than 50000 Pascals; the composition comprising an intimate mixture of a) mainly a block copolymer containing relatively hard blocks and relatively elastomeric blocks; b) additional polymer or copolymer material having at least partial compatibility with, and a higher glass transition, softening or melting temperature than, the hard blocks of the said block copolymer; and c) at least 500 parts by weight of extender liquid per 100 parts by weight of the said block copolymer, which liquid extends and softens the elastomeric blocks of the said block copolymer. SEBS triblock copolymers with polyphenylene ether "alloys" as the added material are preferred, the extender liquid preferably being an oil of substantially zero aromatic content.
摘要翻译：具有（i）ASTM D217锥形穿透值在100至400（10 -1毫米）范围内的凝胶或者胶体液体扩展聚合物组合物，（ii）具有大体弹性的ASTM D412极限伸长率大于100％变形至伸长率至少为100％，（iii）ASTM D412极限拉伸强度小于1兆帕，和（iv）23℃下的动态储能模量小于50000帕斯卡; 该组合物包含a）主要是含有相对硬的嵌段和相对弹性嵌段的嵌段共聚物的紧密混合物; b）与所述嵌段共聚物的硬嵌段具有至少部分相容性和更高的玻璃化转变温度或熔融温度的另外的聚合物或共聚物材料; 和c）每100重量份所述嵌段共聚物至少500重量份的增量液体，该液体延伸并软化所述嵌段共聚物的弹性体嵌段。作为添加材料的具有聚苯醚“合金”的SEBS三嵌段共聚物是优选的，增量剂液体优选为基本上为零的芳香族含量的油。

4. 发明申请

WO1997000292A1 GELS MADE FROM TRIBLOCK COPOLYMERS 审中-公开
标题翻译：凝胶由三嵌段共聚物制成
公开(公告)号：WO1997000292A1
公开(公告)日：1997-01-03
申请号：PCT/GB1996001381
申请日：1996-06-10
申请人： RAYCHEM LIMITED , GRAULUS, Hendrik , OVERBERGH, Noel , HUDSON, John , HAMMOND, Philip, James , YU, Jianming , PERKINS, Anthony
发明人： RAYCHEM LIMITED
IPC分类号： C08L53/00
CPC分类号： C08F220/18 , C08L53/00
摘要： Gels of oil-extended methacrylate-alkylene-methacrylate (M-A-M) triblock copolymers having higher glass transition temperatures than known styrene-alkylene-styrene triblock gels. The preferred M-A-M triblocks for making the new gels have polymethylmethacrylate end blocks and butadiene or ethylene/butylene mid-block, and are synthesised by methods in the public domain (inter alia Shell EP-A-0431706). Includes gels of new triblocks having end blocks of higher alkyl (e.g. isobornyl) methacrylate homopolymer or copolymers. Mixed methyl- and higher alkyl- methacrylate end blocks are preferred to reduce gel-formation problems which may arise from solubility parameter of homo-isobornylmethacrylate end blocks being too close to that of extender oil. Includes gels of new multi- (preferably penta-) block copolymers including styrene (S) blocks, e.g. M-S-A-S-M.
摘要翻译：具有比已知的苯乙烯 - 亚烷基 - 苯乙烯三嵌段凝胶更高的玻璃化转变温度的油 - 甲基丙烯酸酯 - 亚烷基 - 甲基丙烯酸酯（M-A-M）三嵌段共聚物的凝胶。用于制备新凝胶的优选的M-A-M三嵌段具有聚甲基丙烯酸甲酯端嵌段和丁二烯或乙烯/丁烯中嵌段，并且通过公共领域（尤其是Shell EP-A-0431706）中的方法合成。包括具有高级烷基（如异冰片基）甲基丙烯酸酯均聚物或共聚物端嵌段的新三嵌段凝胶。混合的甲基和高级烷基 - 甲基丙烯酸酯封端是优选的，以减少可能由甲基异丁烯酸异冰片酯甲磺酸酯末端嵌段的溶解度参数产生的凝胶形成问题太接近于增量油的溶解度参数。包括新的多（优选五嵌段）嵌段共聚物的凝胶，包括苯乙烯（S）嵌段。 M-S-A-S-M。

5. 发明申请

WO1994023471A1 SEALING GROUND WIRES USING HEAT SHRINKABLE SLEEVES 审中-公开
标题翻译：使用热收缩套管密封接地线
公开(公告)号：WO1994023471A1
公开(公告)日：1994-10-13
申请号：PCT/GB1994000593
申请日：1994-03-23
申请人： RAYCHEM LIMITED , N.V. RAYCHEM S.A. , KULKARNI, Narendra, Jagannath , OVERBERGH, Noel, Marcel, Michiel , DE BLICK, Gerry
发明人： RAYCHEM LIMITED , N.V. RAYCHEM S.A.
IPC分类号： H01R04/72
CPC分类号： H02G15/1813 , H02G15/013
摘要： A method of forming a seal between a heat shrinkable sleeve and an elongate substrate wherein at least a portion of the elongate substrate is provided with a sealing material and a discontinuous spacer adjacent thereto, and heat is applied to the sleeve to cause shrinkage of the sleeve and flow of the sealing material into interstitial spaces in the discontinuous spacer and to form the desired seal.
摘要翻译：一种在热收缩套管和细长衬底之间形成密封件的方法，其中细长衬底的至少一部分设置有密封材料和与其相邻的不连续间隔件，并且将热量施加到套筒以引起套筒收缩并将密封材料流入不连续间隔物中的间隙空间并形成所需的密封。

6. 发明专利

CA1299686C RECOVERABLE FABRIC SLEEVE 未知
公开(公告)号：CA1299686C
公开(公告)日：1992-04-28
申请号：CA558385
申请日：1988-02-08
申请人： OVERBERGH NOEL M M
发明人： OVERBERGH NOEL M M , VANSANT JAN L M F G
IPC分类号： B65D59/04 , B29C61/06 , B29C63/42 , B29C70/06 , B29K105/02 , B29K105/06 , B32B5/08 , B32B7/02 , B65D75/06 , H01R4/70 , H02G15/08 , H02G15/18
摘要： A sleeve suitable for making a cable splice case comprises a matrix material and a recoverble fabric by virtue of which the sleeve is recoverable. The sleeve comprises recoverable weft fibres in bundles of 2-6 running circumferentially, and longitudinal heat-stable warp fibres.

7. 发明申请

WO1998015584A1 METHACRYLATE-ALKYLENE-METHACRYLATE BLOCK COPOLYMERS 审中-公开
标题翻译：甲基丙烯酸甲酯 - 甲基丙烯酸酯嵌段共聚物
公开(公告)号：WO1998015584A1
公开(公告)日：1998-04-16
申请号：PCT/GB1997002764
申请日：1997-10-08
申请人： N.V. RAYCHEM S.A. , RAYCHEM LIMITED , YU, Jianming , OVERBERGH, Noel , HUDSON, John, Michael , HAMMOND, Phillip, James
发明人： N.V. RAYCHEM S.A. , RAYCHEM LIMITED
IPC分类号： C08F297/02
CPC分类号： C07D303/16 , C08F297/02
摘要： Glycidyl methacrylate - alkylene (pref. butadiene) - glycidyl methacrylate triblock copolymers of potentially interesting reactive character. These epoxy-modified methacrylate triblocks may be useful for making oil-extended gels and possibly for other purposes.
摘要翻译：甲基丙烯酸缩水甘油酯 - 亚烷基（预丁二烯） - 甲基丙烯酸缩水甘油酯三嵌段共聚物具有潜在的有趣的反应性。这些环氧改性的甲基丙烯酸酯三嵌段可用于制备延油凝胶并且可能用于其它目的。

8. 发明申请

WO1994012581A1 HEAT-RECOVERABLE COMPOSITION AND ARTICLE 审中-公开
标题翻译：热可恢复组合物和物品
公开(公告)号：WO1994012581A1
公开(公告)日：1994-06-09
申请号：PCT/US1993011686
申请日：1993-12-02
申请人： RAYCHEM CORPORATION , PIESLAK, George , GREUEL, Walter, J., Jr. , ALVERNAZ, Tony, G. , VAN BEERSEL, Jozef , OVERBERGH, Noel, Marcel, Michel
发明人： RAYCHEM CORPORATION
IPC分类号： C09D151/06
CPC分类号： C09J123/04 , C08L2666/02 , C08L2666/24 , C09D123/04 , C09D151/06 , C09J7/22 , C09J7/35 , C09J151/06
摘要： An adhesive composition suitable for sealing to polypropylene. The composition comprises 10 % to 90 % by weight ethylene polymer, e.g. an ethylene homopolymer such as polyethylene or an ethylene copolymer, 10 % to 90 % by weight modified polypropylene, 0 % to 30 % by weight rubber, and 0 % to 25 % by weight tackifier. The composition is useful when it is part of a heat-recoverable article (2) which is used to provide a protective coating onto a polypropylene-coated steel pipeline (4), particularly at a joint or weld (12) in the pipe.
摘要翻译：适用于密封聚丙烯的粘合剂组合物。该组合物包含10重量％至90重量％的乙烯聚合物，例如乙烯均聚物如聚乙烯或乙烯共聚物，10重量％至90重量％的改性聚丙烯，0重量％至30重量％的橡胶和0重量％至25重量％的增粘剂。当组合物是用于在聚丙烯涂覆的钢管道（4）上提供保护涂层（特别是管道中的接头或焊接处）（12）的可热回收制品（2）的一部分时，该组合物是有用的。

9. 发明申请

WO1993000214A1 COVERING FOR PIPELINES 审中-公开
标题翻译：管道覆盖
公开(公告)号：WO1993000214A1
公开(公告)日：1993-01-07
申请号：PCT/GB1992001049
申请日：1992-06-11
申请人： RAYCHEM LIMITED , N.V. RAYCHEM S.A. , OVERBERGH, Noel, Marcel, Michiel , LEEST, Yvo
发明人： RAYCHEM LIMITED , N.V. RAYCHEM S.A.
IPC分类号： B29C61/06
CPC分类号： F16L58/181 , B29C61/06 , B29C61/0616 , F16L58/16 , Y10S174/08 , Y10T428/1328
摘要： A method of covering a joint (4) between pipelines (2) comprises installing a heat recoverable polymer sheet (8) coated on its inner surface with a hot-melt adhesive (10) comprising a mixture of 25-40 parts by weight of a polyethylene alkyl acrylate terpolymer containing maleic anhydride and having a melt flow index as determined according to ASTM D1238-70 of at least 40, and 25-70 parts by weight of a polyethylene alkyl acrylate copolymer having a melt flow index as determined according to ASTM D1238-70 of at least 40.
摘要翻译：覆盖管道（2）之间的接头（4）的方法包括用热熔粘合剂（10）安装涂覆在其内表面上的可热回收聚合物片（8），所述热熔粘合剂（10）包含25-40重量份的含有马来酸酐并具有根据ASTM D1238-70测定的至少40的熔体流动指数的聚丙烯酸烷基酯三元共聚物和25-70重量份具有根据ASTM D1238测定的熔体流动指数的聚乙烯丙烯酸烷基酯共聚物 -70至少40。

10. 发明申请

WO1991005024A1 ADHESIVE COMPOSITION 审中-公开
标题翻译：粘合剂组合物
公开(公告)号：WO1991005024A1
公开(公告)日：1991-04-18
申请号：PCT/GB1990001504
申请日：1990-10-02
申请人： RAYCHEM LIMITED , N.V. RAYCHEM S.A. , OVERBERGH, Noel, Marcel, Michiel
发明人： RAYCHEM LIMITED , N.V. RAYCHEM S.A.
IPC分类号： C09J177/00
CPC分类号： H02G15/1806 , B29C61/0616 , C09D177/00 , C08L2666/02 , C08L75/04
摘要： An adhesive composition comprises a blend of: (a) at least one polyamide; and (b) at lest one acrylate-terminated prepolymer. The adhesive may be applied as a coating on a dimensionally recoverable, preferably heat shrinkable, sleeve for the environmental protection of substrate.
摘要翻译：粘合剂组合物包含以下混合物：（a）至少一种聚酰胺; 和（b）至少一个丙烯酸酯封端的预聚物。粘合剂可以作为涂层施加在尺寸可恢复的，优选地是可热收缩的套筒上，用于衬底的环境保护。

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