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    • 1. 发明申请
    • GELS MADE FROM TRIBLOCK COPOLYMERS
    • 凝胶由三嵌段共聚物制成
    • WO1997000292A1
    • 1997-01-03
    • PCT/GB1996001381
    • 1996-06-10
    • RAYCHEM LIMITEDGRAULUS, HendrikOVERBERGH, NoelHUDSON, JohnHAMMOND, Philip, JamesYU, JianmingPERKINS, Anthony
    • RAYCHEM LIMITED
    • C08L53/00
    • C08F220/18C08L53/00
    • Gels of oil-extended methacrylate-alkylene-methacrylate (M-A-M) triblock copolymers having higher glass transition temperatures than known styrene-alkylene-styrene triblock gels. The preferred M-A-M triblocks for making the new gels have polymethylmethacrylate end blocks and butadiene or ethylene/butylene mid-block, and are synthesised by methods in the public domain (inter alia Shell EP-A-0431706). Includes gels of new triblocks having end blocks of higher alkyl (e.g. isobornyl) methacrylate homopolymer or copolymers. Mixed methyl- and higher alkyl- methacrylate end blocks are preferred to reduce gel-formation problems which may arise from solubility parameter of homo-isobornylmethacrylate end blocks being too close to that of extender oil. Includes gels of new multi- (preferably penta-) block copolymers including styrene (S) blocks, e.g. M-S-A-S-M.
    • 具有比已知的苯乙烯 - 亚烷基 - 苯乙烯三嵌段凝胶更高的玻璃化转变温度的油 - 甲基丙烯酸酯 - 亚烷基 - 甲基丙烯酸酯(M-A-M)三嵌段共聚物的凝胶。 用于制备新凝胶的优选的M-A-M三嵌段具有聚甲基丙烯酸甲酯端嵌段和丁二烯或乙烯/丁烯中嵌段,并且通过公共领域(尤其是Shell EP-A-0431706)中的方法合成。 包括具有高级烷基(如异冰片基)甲基丙烯酸酯均聚物或共聚物端嵌段的新三嵌段凝胶。 混合的甲基和高级烷基 - 甲基丙烯酸酯封端是优选的,以减少可能由甲基异丁烯酸异冰片酯甲磺酸酯末端嵌段的溶解度参数产生的凝胶形成问题太接近于增量油的溶解度参数。 包括新的多(优选五嵌段)嵌段共聚物的凝胶,包括苯乙烯(S)嵌段。 M-S-A-S-M。
    • 7. 发明申请
    • GEL SEALING ARTICLES
    • 凝胶密封文章
    • WO1997035127A1
    • 1997-09-25
    • PCT/GB1997000775
    • 1997-03-20
    • RAYCHEM LIMITEDHAMMOND, Philip, JamesPERCY, Michael, JohnBLUCK, David
    • RAYCHEM LIMITED
    • F16J15/02
    • C09K3/1028C09K2200/06C09K2200/0642C09K2200/0695F16J15/022
    • A gel profile article comprising a multi-filament yarn carrier carrying an elongate body of gel which encloses more than 50 %, preferably more than 75 %, more preferably substantially all, of the perimeter of the carrier as viewed in transverse cross section, wherein the carrier is at least partly composed of synthetic polymeric material, preferably polyester filaments (e.g. polyethylene terephthalate) or spun yarns of a co-mingled blend of polyacrylonitrile staple fibres and polyamide staple fibres ("baby wool"), the proportion of polyamide preferably being at least 30 %, more preferably 40-60 %, by weight of the said spun yarn(s). The gel is preferably melt-coated, especially pressure-extruded, around the carrier at a gel temperature less than the softening temperature of at least a component of the carrier, and the selected class of carrier materials enhances the processability, cohesion, and appearance of the resulting profile.
    • 一种凝胶型材制品,其包括承载细长体凝胶体的复丝纱线载体,其以横截面观察,其包围载体周长的多于50%,优选大于75%,更优选基本上全部的,其中 载体至少部分由合成聚合物材料,优选聚酯长丝(例如聚对苯二甲酸乙二醇酯)或聚丙烯腈短纤维和聚酰胺短纤维(“婴儿羊毛”)的共混混合物的短纤纱组成,聚酰胺的比例优选为 至少30%,更优选40-60%。 凝胶优选在小于载体组分的软化温度的凝胶温度下在载体周围进行熔体涂覆,特别是压力挤出,并且所选择的载体材料种类增强了加工性,内聚力和外观 生成的配置文件。
    • 8. 发明申请
    • GEL-CARRYING ELONGATE ARTICLES
    • 凝胶制品
    • WO1997035126A1
    • 1997-09-25
    • PCT/GB1997000773
    • 1997-03-20
    • RAYCHEM LIMITEDHAMMOND, Philip, JamesDRINKWATER, IanLAIRD, Iain
    • RAYCHEM LIMITED
    • F16J15/02
    • F16J15/022
    • Gel-carrying sealant profiles having a C-, V-, or U-shaped plastics channel carrier with gel on its external and/or internal surfaces for sealing between opposed surfaces of structures such as equipment housings or doors and windows. The profiles may have a projecting formation, preferably integral with the carrier, for fixing the profile to an object, e.g. by means of an enlarged portion of the formation being received in an aperture in the object. Carriers in a form similar to known "flipper" seals are especially useful for door and window seals or other multi-entry closures. Preferred gels are triblock or multi-block copolymers having a highly oil-extended polyalkylene elastomeric mid-block and harder end blocks, preferably of polystyrene or polyalkylmethacrylate.
    • 具有凝胶的密封剂型材,其具有在其外表面和/或内表面上具有凝胶的C形,V形或U形塑料通道载体,用于在诸如设备外壳或门窗的结构的相对表面之间进行密封。 轮廓可以具有突出的形状,优选地与载体成一体,用于将轮廓固定到物体,例如。 借助于地层的放大部分被接纳在物体的孔中。 类似于已知的“导板”密封件的形式的承载器对于门窗密封件或其他多入口封闭件特别有用。 优选的凝胶是三嵌段或多嵌段共聚物,其具有高度油延伸的聚亚烷基弹性体中间嵌段和更硬的端嵌段,优选聚苯乙烯或聚甲基丙烯酸烷基酯。
    • 9. 发明申请
    • TAPE OR SHEET COATED WITH GEL ADHESIVE
    • 胶带或薄片涂胶凝胶
    • WO1997009391A1
    • 1997-03-13
    • PCT/GB1996002170
    • 1996-09-04
    • RAYCHEM LIMITEDPERCY, Michael, JohnEGENTON, William, JosephBRADLEY, Paul, AndrewLAIRD, IanHUDSON, John, MichaelHUTT, NormanHAMMOND, Philip, JamesSUTHERLAND, Alistair, Alfred, PrestonHORNER, Patrick, James
    • RAYCHEM LIMITED
    • C09J07/02
    • H01M2/08C09J7/22C09J7/38
    • Low-cost general purpose sealing product comprising thick gel coating on thin burst-resistant film backing useful as cost-effective bung in refrigerator casing foam injection and many other uses. Hot lamination and specific gel backing thickness ratios are described, the preferred materials being oil-extended styrene-elastomer-styrene triblock copolymer gels on EVA backing. Double-sided gel tape, or unsupported gel tape, preferably of at least 15 % triblock content, wrapped around cable to seal wall feedthrough. Includes different gels on opposite sides of backing; reticulated foam backing filled by gel; closed cell foam backing; gel tape in plane of carrier sheet; unsupported gel profile (of any shape) in automotive headlamps; non-aqueous gels of any form in acid or alkali, especially electrolyte compartments and barriers in batteries and dry cells; gel layers (preferably thermally conductive) in face-to-face contact with printed circuit boards; gel profiles as gland packing materials, e.g. for masts of ships; gel-filled foams as mats e.g. non-slip mats for boats; and gel seals in glazing frames.
    • 低成本的通用密封产品,包括在薄耐爆薄膜背衬上的厚凝胶涂层,可用作冰箱套管泡沫注射中的成本效益的胶囊和许多其他用途。 描述了热层压和特定的凝胶背衬厚度比,优选的材料是EVA背衬上的油延伸的苯乙烯 - 弹性体 - 苯乙烯三嵌段共聚物凝胶。 双面胶带或无支撑的胶带,优选至少15%的三嵌段含量,缠绕在电缆上以密封壁馈通。 在背衬的两侧包括不同的凝胶; 用凝胶填充的网状泡沫背衬; 闭孔泡沫背衬; 胶带平面载体片; 汽车前照灯中无支撑的凝胶型材(任何形状); 酸性或碱性中任何形式的非水凝胶,特别是电解槽和电池和干电池中的屏障; 凝胶层(优选导热)与印刷电路板面对面接触; 凝胶型材作为压盖包装材料,例如 船舶桅杆 凝胶填充泡沫如垫子 船用防滑垫; 和玻璃框架中的凝胶密封。