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1. 发明专利

CA2676333A1 PEAT DERIVED CARBON-BASED METAL CATALYSTS 未知
公开(公告)号：CA2676333A1
公开(公告)日：2011-02-21
申请号：CA2676333
申请日：2009-08-21
申请人： XU CHUNBAO , OHTSUKA YASUO , DONALD JALCYN
发明人： XU CHUNBAO , OHTSUKA YASUO , DONALD JALCYN
IPC分类号： B01J23/755 , B01J23/745 , B01J32/00 , B01J37/02 , B01J37/08 , C01B3/04 , C01B31/08
摘要： The present invention provides catalysts, and methods of making the catalysts using peat as a raw material for highly stable activated carbon-based catalysts based on the transition metals and noble metals. Particular embodiments include two new carbon-based Ni/Fe catalysts useful for catalytic decomposition of ammonia into N2 and H2. These catalysts are prepared using a porous activated carbon (AC) support derived from peat by H3PO4 activation. The newly developed catalysts proved to be highly active for ammonia decomposition. The conversion of 2000 ppm NH3 diluted in helium over the Fe catalyst reached as high as 90% at 750°C and at a space velocity of 45000 h-1, compared with only about 15% with the activated carbon alone without metal loading. The new catalyst of Fe/AC was also much more active than a previously reported Fe catalyst supported on a commercial activated carbon. In addition, the new Fe/Ni catalysts showed superior performance with respect to their resistance to catalyst deactivation. Both catalysts remained active as the reaction time increased up to 10 hours without showing signs of deactivation. Fresh and spent catalysts were characterized by XRD, XPS and TPD. Possible catalytic mechanisms are discussed, and a cycle mechanism, involving both metal phosphides and metal nitrides, is proposed for the NH3 decomposition reactions over the new Fe/Ni catalysts.

2. 发明申请

WO2009048724A3 COMPOSITIONS FOR CATALYTIC GASIFICATION OF A PETROLEUM COKE AND PROCESS FOR THEIR CONVERSION TO METHANE 审中-公开
标题翻译：石油焦炭催化气化组合物及其转化甲烷的方法
公开(公告)号：WO2009048724A3
公开(公告)日：2009-06-25
申请号：PCT/US2008076991
申请日：2008-09-19
申请人： GREATPOINT ENERGY INC , OHTSUKA YASUO
发明人： OHTSUKA YASUO
IPC分类号： C10J3/00 , C10J3/46 , C10L3/08 , C10L5/00 , C10L9/00
CPC分类号： C10L5/00 , C10J3/00 , C10J3/463 , C10J2300/0903 , C10J2300/0943 , C10J2300/0973 , C10J2300/0986 , C10J2300/1853 , C10L5/366 , C10L9/00 , Y02P20/52
摘要： The present invention relates to particulate compositions of a lower ash type petroleum coke containing at least two preselected components (alkali metal and calcium) that exhibit an efficient, enhanced-yielding gasification to value added gaseous products, particularly when used in a steady-state integrated gasification process. The compositions of the present invention are particularly useful for catalytic gasification of petroleum coke at moderate temperatures ranging from about 450°C to about 900°C. Advantageously, the compositions can be readily incorporated into fluidized bed gasification units, and can result in a cost-effective, high-yielding production of methane gas from petroleum coke.
摘要翻译：本发明涉及含有至少两种预选组分（碱金属和钙）的低灰分型石油焦炭的颗粒组合物，其表现出对增值气态产物的有效增强的气化，特别是当用于稳态一体化气化过程。本发明的组合物特别可用于在约450℃至约900℃的中等温度下对石油焦炭进行催化气化。有利地，组合物可以容易地结合到流化床气化单元中，并且可以导致来自石油焦炭的甲烷气体的成本有效的高产量生产。

3. 发明申请

WO1997000258A1 TRICYCLIC BENZAZEPINE COMPOUNDS 审中-公开
标题翻译：三氯苯甲腈化合物
公开(公告)号：WO1997000258A1
公开(公告)日：1997-01-03
申请号：PCT/JP1996001628
申请日：1996-06-14
申请人： MEIJI SEIKA KABUSHIKI KAISHA , OHTSUKA, Yasuo , NISHIZUKA, Toshio , SHIOKAWA, Sohjiro , TSUTSUMI, Seiji , FUSIHARA, Kenichi , KAWAGUCHI, Mami , IMAI, Megumi , SHITO, Keiko , TSUCHIYA, Koji , IWASAKI, Takako , OGINO, Hiroko , SHISHIKURA, Takashi
发明人： MEIJI SEIKA KABUSHIKI KAISHA
IPC分类号： C07D487/04
CPC分类号： C07D405/06 , C07D249/04 , C07D487/04 , C07D491/14 , Y02P20/55
摘要： Tricyclic benzazepine compounds represented by general formula (I) and pharmacologically acceptable salts thereof. Because of having antiallergic effects, these compounds are useful in the treatment and prevention of bronchial asthma, eczema, urticaria, allergic gastrointestinal disorders, allergic rhinitis, allergic conjunctivitis, etc., wherein R represents hydrogen, substituted C1-6 alkyl or a protecting group; R , R , R and R represent each hydrogen, hydroxy, substituted C1-4 alkyl, substituted C2-12 alkenyl, substituted C1-12 alkoxy or substituted amino.
摘要翻译：由通式（I）表示的三环苯并氮杂化合物及其药理学上可接受的盐。由于具有抗过敏作用，这些化合物可用于治疗和预防支气管哮喘，湿疹，荨麻疹，过敏性胃肠疾病，过敏性鼻炎，过敏性结膜炎等，其中R表示氢，取代的C 1-6烷基或保护基 ; R 1，R 2，R 3和R 4分别表示氢，羟基，取代的C 1-4烷基，取代的C 12-12烯基，取代的C 1-12烷氧基或取代的氨基。

4. 发明申请

WO2009048723A3 COMPOSITIONS FOR CATALYTIC GASIFICATION OF A PETROLEUM COKE AND PROCESS FOR CONVERSION THEREOF TO METHANE 审中-公开
标题翻译：用于石油焦炭催化气化的组合物及其转化为甲烷的方法
公开(公告)号：WO2009048723A3
公开(公告)日：2009-06-25
申请号：PCT/US2008076988
申请日：2008-09-19
申请人： GREATPOINT ENERGY INC , OHTSUKA YASUO
发明人： OHTSUKA YASUO
IPC分类号： C10J3/00 , C10J3/46 , C10L3/08 , C10L5/00 , C10L9/00
CPC分类号： C10J3/463 , C10J3/00 , C10J2300/0903 , C10J2300/0943 , C10J2300/0973 , C10J2300/0986 , C10J2300/1853 , C10L5/00 , C10L5/366 , C10L9/00 , Y02P20/52
摘要： The present invention relates to particulate compositions of a lower ash type petroleum coke containing at least two preselected components (alkali metal and iron) that exhibit an efficient, enhanced-yielding gasification to value added gaseous products, particularly when used in a steady-state integrated gasification process. The compositions of the present invention are particularly useful for catalytic gasification of petroleum coke at moderate temperatures ranging from about 4500C to about 9000C. Advantageously, the compositions can be readily incorporated into fluidized bed gasification units, and can result in a cost-effective, high-yielding production of methane gas from petroleum coke.
摘要翻译：本发明涉及含有至少两种预选组分（碱金属和铁）的低灰分型石油焦炭的颗粒组合物，其表现出对增值气态产物有效的增强产生的气化，特别是当用于稳态积分气化过程。本发明的组合物特别可用于在约45℃至约900℃的中等温度下对石油焦炭进行催化气化。有利地，组合物可以容易地结合到流化床气化单元中，并且可以导致来自石油焦炭的甲烷气体的成本有效的高产量生产。

5. 发明申请

WO2009048724A2 COMPOSITIONS FOR CATALYTIC GASIFICATION OF A PETROLEUM COKE 审中-公开
标题翻译：石油焦炭催化气化组合物
公开(公告)号：WO2009048724A2
公开(公告)日：2009-04-16
申请号：PCT/US2008/076991
申请日：2008-09-19
申请人： GREATPOINT ENERGY, INC. , OHTSUKA, Yasuo
发明人： OHTSUKA, Yasuo
IPC分类号： C10J3/46 , C10L5/00 , C10L3/08
CPC分类号： C10L5/00 , C10J3/00 , C10J3/463 , C10J2300/0903 , C10J2300/0943 , C10J2300/0973 , C10J2300/0986 , C10J2300/1853 , C10L5/366 , C10L9/00 , Y02P20/52
摘要： The present invention relates to particulate compositions of a lower ash type petroleum coke containing at least two preselected components (alkali metal and calcium) that exhibit an efficient, enhanced-yielding gasification to value added gaseous products, particularly when used in a steady-state integrated gasification process. The compositions of the present invention are particularly useful for catalytic gasification of petroleum coke at moderate temperatures ranging from about 450°C to about 900°C. Advantageously, the compositions can be readily incorporated into fluidized bed gasification units, and can result in a cost-effective, high-yielding production of methane gas from petroleum coke.
摘要翻译：本发明涉及含有至少两种预选组分（碱金属和钙）的低灰分型石油焦炭的颗粒组合物，其表现出对增值气态产物的有效增强的气化，特别是当用于稳态一体化气化过程。本发明的组合物特别可用于在约450℃至约900℃的中等温度下对石油焦炭进行催化气化。有利地，组合物可以容易地结合到流化床气化单元中，并且可以导致来自石油焦炭的甲烷气体的成本有效的高产量生产。

6. 发明申请

WO2009048723A2 COMPOSITIONS FOR CATALYTIC GASIFICATION OF A PETROLEUM COKE 审中-公开
标题翻译：石油焦炭催化气化组合物
公开(公告)号：WO2009048723A2
公开(公告)日：2009-04-16
申请号：PCT/US2008/076988
申请日：2008-09-19
申请人： GREATPOINT ENERGY, INC. , OHTSUKA, Yasuo
发明人： OHTSUKA, Yasuo
IPC分类号： C10L5/00 , C10J3/46 , C10L3/08
CPC分类号： C10J3/463 , C10J3/00 , C10J2300/0903 , C10J2300/0943 , C10J2300/0973 , C10J2300/0986 , C10J2300/1853 , C10L5/00 , C10L5/366 , C10L9/00 , Y02P20/52
摘要： The present invention relates to particulate compositions of a lower ash type petroleum coke containing at least two preselected components (alkali metal and iron) that exhibit an efficient, enhanced-yielding gasification to value added gaseous products, particularly when used in a steady-state integrated gasification process. The compositions of the present invention are particularly useful for catalytic gasification of petroleum coke at moderate temperatures ranging from about 4500C to about 9000C. Advantageously, the compositions can be readily incorporated into fluidized bed gasification units, and can result in a cost-effective, high-yielding production of methane gas from petroleum coke.
摘要翻译：本发明涉及含有至少两种预选组分（碱金属和铁）的低灰分型石油焦炭的颗粒组合物，其表现出对增值气态产物有效的增强产生的气化，特别是当用于稳态积分气化过程。本发明的组合物特别可用于在约45℃至约900℃的中等温度下对石油焦炭进行催化气化。有利地，组合物可以容易地结合到流化床气化单元中，并且可以导致来自石油焦炭的甲烷气体的成本有效的高产量生产。

7. 发明申请

WO9518130A9 TRICYCLIC BENZAZEPINE AND BENZOTHIAZEPINE DERIVATIVES 审中-公开
标题翻译：三氯苯并苯并噻唑衍生物
公开(公告)号：WO9518130A9
公开(公告)日：2007-07-19
申请号：PCT/JP9402282
申请日：1994-12-28
申请人： MEIJI SEIKA CO , OHTSUKA YASUO , SHISHIKURA TAKASHI , OGINO HIROKO , FUSHIHARA KENICHI , KAWAGUCHI MAMI , TSUTSUMI SEIJI , IMAI MEGUMI , SHITO KEIKO , TSUCHIYA KOJI , TANAKA JUNKO , IWASAKI TAKAKO , HOSHIKO SHIGERU , TSURUOKA TAKASHI
发明人： OHTSUKA YASUO , SHISHIKURA TAKASHI , OGINO HIROKO , FUSHIHARA KENICHI , KAWAGUCHI MAMI , TSUTSUMI SEIJI , IMAI MEGUMI , SHITO KEIKO , TSUCHIYA KOJI , TANAKA JUNKO , IWASAKI TAKAKO , HOSHIKO SHIGERU , TSURUOKA TAKASHI
IPC分类号： C07D249/04 , C07D487/04 , C07D513/04
CPC分类号： C07D487/04 , C07D249/04 , C07D513/04 , Y02P20/55
摘要： Tricyclic benzazepine and benzothiazepine derivatives represented by general formula (I) and pharmacologically acceptable salts thereof, wherein Z represents CO, -CR 6 R 7 - or -S(O)n; R represents hydrogen, alkyl, phenylalkyl or a triazole-protective group; and R 1 to R 5 represent each hydrogen, alkyl, alkenyl, alkoxy, amino, oxime or hydroxy. The compounds have an antiallergic activity and hence are useful for treating and preventing allergic diseases.
摘要翻译：由通式（I）表示的三环苯并吖庚因衍生物和苯并硫氮杂衍生物及其药理学上可接受的盐，其中Z表示CO，-CR 6，R 7 - 或-S（O）n ; R代表氢，烷基，苯基烷基或三唑保护基; R 1至R 5表示每个氢，烷基，烯基，烷氧基，氨基，肟或羟基。该化合物具有抗过敏活性，因此可用于治疗和预防过敏性疾病。

8. 发明申请

WO1995018130A1 TRICYCLIC BENZAZEPINE AND BENZOTHIAZEPINE DERIVATIVES 审中-公开
标题翻译：三氯苯并苯并噻唑衍生物
公开(公告)号：WO1995018130A1
公开(公告)日：1995-07-06
申请号：PCT/JP1994002282
申请日：1994-12-28
申请人： MEIJI SEIKA KABUSHIKI KAISHA , OHTSUKA, Yasuo , SHISHIKURA, Takashi , OGINO, Hiroko , FUSHIHARA, Kenichi , KAWAGUCHI, Mami , TSUTSUMI, Seiji , IMAI, Megumi , SHITO, Keiko , TSUCHIYA, Koji , TANAKA, Junko , IWASAKI, Takako , HOSHIKO, Shigeru , TSURUOKA, Takashi
发明人： MEIJI SEIKA KABUSHIKI KAISHA
IPC分类号： C07D487/04
CPC分类号： C07D487/04 , C07D249/04 , C07D513/04 , Y02P20/55
摘要： Tricyclic benzazepine and benzothiazepine derivatives represented by general formula (I) and pharmacologically acceptable salts thereof, wherein Z represents CO, -CR R - or -S(O)n; R represents hydrogen, alkyl, phenylalkyl or a triazole-protective group; and R to R represent each hydrogen, alkyl, alkenyl, alkoxy, amino, oxime or hydroxy. The compounds have an antiallergic activity and hence are useful for treating and preventing allergic diseases.
摘要翻译：由通式（I）表示的三环苯并吖庚因衍生物和苯并硫氮杂衍生物及其药理学上可接受的盐，其中Z表示CO，-CR 6 R 7或-S（O）n; R代表氢，烷基，苯基烷基或三唑保护基; R 1至R 5各自代表氢，烷基，烯基，烷氧基，氨基，肟或羟基。该化合物具有抗过敏活性，因此可用于治疗和预防过敏性疾病。

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