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1. 发明申请

US20050107383A1 3-ARYLPHENYL SULFIDE DERIVATIVE AND INSECTICIDE AND MITICIDE 有权
公开(公告)号：US20050107383A1
公开(公告)日：2005-05-19
申请号：US10981722
申请日：2004-11-05
申请人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
发明人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
IPC分类号： A01N41/10 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/76 , A01N43/78 , A61K31/4164 , A61K31/4196 , A61K31/445 , A61K31/495 , A61K31/498 , A61K31/50 , A61K31/513 , A61K31/53 , C07C309/00 , C07C317/14 , C07C317/22 , C07C317/32 , C07C323/09 , C07C323/18 , C07C323/31 , C07D211/54 , C07D213/52 , C07D213/57 , C07D213/64 , C07D231/12 , C07D249/08 , C07D253/00 , C07D263/32 , C07D277/26 , C07D307/56 , C07D333/24 , C07D333/28
CPC分类号： C07D213/12 , A01N31/08 , A01N31/14 , A01N33/10 , A01N37/08 , A01N37/34 , A01N41/10 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/653 , A01N43/76 , A01N43/78 , A01N47/18 , C07C317/32 , C07C317/48 , C07C323/18 , C07C323/20 , C07C323/36 , C07C323/63 , C07D213/32 , C07D213/48 , C07D213/57 , C07D213/64 , C07D239/36 , C07D239/38 , C07D239/40 , C07D249/08 , C07D333/24
摘要： 3-Arylphenyl sulfide derivatives represented by general formula (I): (wherein R is a C2-C6 alkyl group, a C2-C6 alkenyl group, a C2-C6 alkynyl group or the like, B0 to B2 and B3 are hydrogen atoms, halogen atoms, cyano groups, C1-C4 haloalkyl groups or the like, n is 0, 1 or 2, and Ar is a phenyl ring, a pyridine ring, a thiophene ring, a pyrazole ring or the like), and insecticides and miticides containing the 3-arylphenyl sulfide derivatives as an active ingredient.
摘要翻译：由通式（I）表示的3-芳基苯基硫醚衍生物：其中R是C 2 -C 6烷基，C 2 - -C 6亚烷基，C 2 -C 6亚炔基等，B 0〜B 2个和3个3个是氢原子，卤素原子，氰基，C 1 -C 4卤代烷基或 n为0,1或2，Ar为苯环，吡啶环，噻吩环，吡唑环等），含有3-芳基苯基硫醚衍生物的杀虫剂和杀螨剂为活性成分。

2. 发明授权

US5877120A Nicotinic acid derivatives and herbicides 失效
标题翻译：烟酸衍生物和除草剂
公开(公告)号：US5877120A
公开(公告)日：1999-03-02
申请号：US704610
申请日：1996-09-18
申请人： Masahiro Miyazaki , Sumio Yokota , Yoshihiro Ito , Nobuyuki Ohba , Nobuhide Wada , Shigehiko Tachikawa , Takeshige Miyazawa
发明人： Masahiro Miyazaki , Sumio Yokota , Yoshihiro Ito , Nobuyuki Ohba , Nobuhide Wada , Shigehiko Tachikawa , Takeshige Miyazawa
IPC分类号： A01N43/54 , A01N43/90 , A01P13/00 , A61K31/44 , C07D213/00 , C07D213/80 , C07D239/00 , C07D307/00 , C07D401/06 , C07D401/14 , C07D405/14 , C07D409/14 , C07D491/04 , C07D491/048 , A01N43/66
CPC分类号： A01N43/54 , A01N43/90 , C07D401/06 , C07D401/14 , C07D405/14 , C07D409/14 , C07D491/04
摘要： A nicotinic acid derivative represented by general formula (I) or (II), a salt thereof, and a herbicide containing the same as the active ingredient, wherein A represents substituted phenyl, or 5- or 6- membered heterocycle, e.g., thienyl or pyridyl; R represents hydroxy, optionally substituted alkoxy or optionally substituted benzyloxy; R.sup.1 and R.sup.2 represent each independently alkoxy or halogen; R.sup.3 and R.sup.4 represent each independently hydrogen, hydroxy, cyano or alkoxycarbonyl, or they may be combined together to represent oxygen; X represents halogen, alkyl or alkoxy; n represents 0, 1 or 2; and Z represents methine or nitrogen. The compound and salts thereof can control annual or perennial weed growing on the land where various crops such as rice plant, wheat, cotton and corn grow for a wide period ranging from the pre-emergence to growth in a remarkably small dose. ##STR1##
摘要翻译： PCT No.PCT / JP94 / 00453 Sec。 371日期1996年9月18日 102（e）1996年9月18日PCT 1994年3月22日PCT公布。公开号WO95 / 25730 日期：1995年9月28日由通式（I）或（II）表示的烟酸衍生物，其盐和含有该活性成分的除草剂，其中A表示取代的苯基或5-或6-元杂环，例如噻吩基或吡啶基; R表示羟基，任选取代的烷氧基或任选取代的苄氧基; R1和R2各自独立地表示烷氧基或卤素; R3和R4各自独立地表示氢，羟基，氰基或烷氧基羰基，或者它们可以组合在一起代表氧; X表示卤素，烷基或烷氧基; n表示0,1或2; Z表示次甲基或氮。其化合物及其盐可以控制在各种作物如水稻，小麦，棉花和玉米等土地上种植一年生或多年生杂草，其生长时间从出苗前到生长非常小。（I）（II）

3. 发明授权

US5087289A Alkanoic acid derivatives and herbicidal compositions 失效
标题翻译：酸性衍生物和除草剂组合物
公开(公告)号：US5087289A
公开(公告)日：1992-02-11
申请号：US571118
申请日：1990-08-23
申请人： Koichiro Kaku , Nobuhide Wada , Akira Takeuchi , Yasufumi Toyokawa , Takeshige Miyazawa , Ryo Yoshida , Kazuhiko Sugiyama
发明人： Koichiro Kaku , Nobuhide Wada , Akira Takeuchi , Yasufumi Toyokawa , Takeshige Miyazawa , Ryo Yoshida , Kazuhiko Sugiyama
IPC分类号： A01N43/54 , A01N43/66 , C07D239/34 , C07D239/38 , C07D239/52 , C07D239/60 , C07D251/20 , C07D251/34 , C07D251/38 , C07D405/12 , C07D409/12
CPC分类号： A01N43/54 , A01N43/66 , C07D239/34 , C07D239/38 , C07D239/52 , C07D239/60 , C07D251/20 , C07D251/34 , C07D251/38 , C07D405/12 , C07D409/12
摘要： A herbicidal alkanoic acid derivative of the formula: ##STR1## wherein R.sup.3 is a hydrogen atom, a halogen atom, a halogen-substituted alkyl group, an alkyl group, a cycloalkyl group, an alkylthioalkyl group, a hydroxyalkyl group, a hydroxyl group, a cyano group, an acyloxyalkyl group, a thienyl group, a naphthyl group, a dihydronaphthyl group ##STR2## wherein R.sup.8 is a hydrogen atom, a halogen atom, a nitro group, an alkyl group, an alkoxy group or --S(O).sub.n R.sup.9 wherein R.sup.9 is an alkyl group, and n is an integer of from 0 to 2, m is an integer of from 0 to 2, each of R.sup.2 and R.sup.4 which may be the same or different is a hydrogen atom or an alkyl group, or R.sup.2 and R.sup.4 form together with the adjacent carbon atom a 3-, 4-, 5- or 6-membered ring which may contain an oxygen atom and may be substituted by one or two alkyl groups, each of R.sup.5 and R.sup.6 which may be the same or different is a hydrogen atom or an alkyl group, R.sup.7 is an alkyl group or a phenyl group, or R.sup.6 and R.sup.7 form --(CH.sub.2).sub.l -- wherein l is an integer of 3 or 4 which may be substituted by one or two alkyl groups, or R is an alkenyl group, a dihyronaphthyl group, a tetrahydronaphthyl group, a 1-oxo-1,2,3,4-tetrahydronaphthyl group, a 1,2-epoxycycloalkyl group or an indanyl group which may be substituted by an alkyl or alkoxy group; R.sup.1 is a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, a phenyl group, an alkylideneamino group, an alkoxyalkyl group, an alkoxycarbonylalkyl group, a halogen-substituted alkyl group, a cycloalkyl group, a nitro-substituted phenylthioalkyl group, a halogen atom or a benzyl group which may be substituted by an alkyl or alkoxy group; or R and R.sup.1 form a ring; A is an alkyl group, an alkoxy group, an alkylthio group, a halogen atom, a halogen-substituted alkoxy group, an amino group, an alkylamino group or a dialkylamino group; B is a hydrogen atom, an alkyl group, an alkoxy group or a halogen-substituted alkoxy group; X is an oxygen atom or a sulfur atom; and Z is a methine group or a nitrogen atom; and a salt thereof.

4. 发明授权

US5019151A 2-phenoxyprimidine derivative and herbicidal composition 失效
标题翻译： 2-苯氧基嘧啶衍生物和除草组合物
公开(公告)号：US5019151A
公开(公告)日：1991-05-28
申请号：US511346
申请日：1990-04-19
申请人： Nobuhide Wada , Yoshihiro Saito , Shoji Kusano , Yasufumi Toyokawa , Takeshige Miyazawa , Satoru Takahashi , Takayoshi Takehi
发明人： Nobuhide Wada , Yoshihiro Saito , Shoji Kusano , Yasufumi Toyokawa , Takeshige Miyazawa , Satoru Takahashi , Takayoshi Takehi
IPC分类号： A01N43/54 , C07D239/52 , C07D239/60 , C07D401/12
CPC分类号： C07D401/12 , A01N43/54 , C07D239/52 , C07D239/60
摘要： A 2-phenoxypridimine derivative having the formula: ##STR1## wherein X is a halogen atom or ##STR2## wherein X.sup.1 is a halogen atom, a lower alkyl group or a lower alkoxy group and k is 0, 1, or 2; R.sup.1 is a hydrogen atom, a benzyl group, --(CH.sub.2).sub.m R.sup.3 is a cyano group, a formyl group, a dialkylamino group, a phenyl group, a pyridyl group, a trimethylsilyl group, a naphthyl group, an alkoxycarbonyl group, a benzoyl group, an alkylthio group, a phenylthio group, an alkylsulfonyl group or a benzyloxy group and m is 1, 2, or ##STR3## wherein R.sup.4 is a hydrogen atom or a lower alkyl group, R.sup.5 is a lower alkyl group or ##STR4## wherein X.sup.2 is a hydrogen atom, a halogen atom, a lower alkyl group, a lower alkoxy group or a nitro group, n is 0 or 1, provided that when R.sup.5 is an alkyl group, n is 1; and R.sup.2 is a chlorine atom or a methoxy group, provided that when R.sup.1 is a hydrogen atom or a benzyl group, X is ##STR5## and R.sup.2 is a methoxy group, when R.sup.1 is ##STR6## X is a chlorine atom at the 6-position and R.sup.2 is a methoxy group, and when R.sup.1 is --(CH.sub.2).sub.m R.sup.3, X is a halogen atom at the 6-position.

5. 发明授权

US4923501A Pyrimidine derivatives, processes for their production, and herbicidal method and compositions 失效
标题翻译：嘧啶衍生物，其制备方法，除草方法和组合物
公开(公告)号：US4923501A
公开(公告)日：1990-05-08
申请号：US264015
申请日：1988-10-28
申请人： Yoshihiro Saito , Nobuhide Wada , Shoji Kusano , Takeshige Miyazawa , Satoru Takahashi , Yasuhumi Toyokawa , Ikuo Kajiwaca
发明人： Yoshihiro Saito , Nobuhide Wada , Shoji Kusano , Takeshige Miyazawa , Satoru Takahashi , Yasuhumi Toyokawa , Ikuo Kajiwaca
IPC分类号： A01N43/54 , A01P13/00 , C07D239/46 , C07D239/60
CPC分类号： A01N43/54 , C07D239/60
摘要： A pyrimidine derivative having the formula: ##STR1## wherein X is a halogen atom, a lower alkyl group or a phenoxy group (wherein said phenoxy group may be substituted by halogen, lower alkyl or lower alkoxy), and R is a hydrogen atom, a lower alkyl group, an alkoxyalkyl group, a benzyloxyalkyl group, an alkoxycarbonyl alkyl group, a cyanoalkyl group or a ##STR2## group (wherein R.sup.1 is a hydrogen atom or a lower alkyl group, and R.sup.2 is a lower alkyl group or a phenyl group which may be substituted by nitro), or a salt thereof.

6. 发明授权

US4900352A 2-Phenoxypyimidine derivative and herbicidal composition 失效
标题翻译： 2-苯氧基嘧啶衍生物和除草组合物
公开(公告)号：US4900352A
公开(公告)日：1990-02-13
申请号：US291353
申请日：1988-12-29
申请人： Nobuhide Wada , Yoshihiro Saito , Shoji Kusano , Yasuhumi Toyokawa , Takeshige Miyazawa , Ikuo Kajiwara , Satoru Takahashi
发明人： Nobuhide Wada , Yoshihiro Saito , Shoji Kusano , Yasuhumi Toyokawa , Takeshige Miyazawa , Ikuo Kajiwara , Satoru Takahashi
IPC分类号： A01N43/54 , C07D239/34 , C07D239/52 , C07D239/60
CPC分类号： C07D239/60 , A01N43/54 , C07D239/34 , C07D239/52
摘要： A 2-phenoxypyrimidine derivative having the formula: ##STR1## wherein R.sup.1 is a formyl group, a dimethoxymethyl group or --COOR.sup.4 (wherein R.sup.4 is a hydrogen atom, a lower alkyl group, a benzyl group, an alkali metal atom, an alkaline earth metal atom or an organic ammonium group), R.sup.2 is a chlorine atom, a methyl group, a methoxy group or a difluoromethoxy group, R.sup.3 is a methyl group or a methoxy group, X is a halogen atom, a lower alkyl group, a lower alkoxy group, an amino group, a hydroxyl group, a nitro group or a cyano group, and n is 1 or 2.

7. 发明授权

US06858639B2 3-Arylphenyl sulfide derivative and insecticide and miticide 有权
标题翻译： 3-芳基苯硫醚衍生物和杀虫剂和杀螨剂
公开(公告)号：US06858639B2
公开(公告)日：2005-02-22
申请号：US10121833
申请日：2002-04-15
申请人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
发明人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
IPC分类号： A01N41/10 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/76 , A01N43/78 , A61K31/4164 , A61K31/4196 , A61K31/445 , A61K31/495 , A61K31/498 , A61K31/50 , A61K31/513 , A61K31/53 , C07C309/00 , C07C317/14 , C07C317/22 , C07C317/32 , C07C323/09 , C07C323/18 , C07C323/31 , C07D211/54 , C07D213/52 , C07D213/57 , C07D213/64 , C07D231/12 , C07D249/08 , C07D253/00 , C07D263/32 , C07D277/26 , C07D307/56 , C07D333/24 , C07D333/28 , A07N43/56
CPC分类号： C07D213/12 , A01N31/08 , A01N31/14 , A01N33/10 , A01N37/08 , A01N37/34 , A01N41/10 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/653 , A01N43/76 , A01N43/78 , A01N47/18 , C07C317/32 , C07C317/48 , C07C323/18 , C07C323/20 , C07C323/36 , C07C323/63 , C07D213/32 , C07D213/48 , C07D213/57 , C07D213/64 , C07D239/36 , C07D239/38 , C07D239/40 , C07D249/08 , C07D333/24
摘要： 3-Arylphenyl sulfide derivatives represented by general formula (I): (wherein R is a C2-C6 alkyl group, a C2-C6 alkenyl group, a C2-C6 alkynyl group or the like, B0 to B2 and B3 are hydrogen atoms, halogen atoms, cyano groups, C1-C4 haloalkyl groups or the like, n is 0, 1 or 2, and Ar is a phenyl ring, a pyridine ring, a thiophene ring, a pyrazole ring or the like), and insecticides and miticides containing the 3-arylphenyl sulfide derivatives as an active ingredient.
摘要翻译：由通式（I）表示的3-芳基苯基硫醚衍生物:(其中R为C2-C6烷基，C2-C6烯基，C2-C6炔基等，B0至B2和B3为氢原子，卤素原子，氰基，C 1〜C 4卤代烷基等，n为0,1或2，Ar为苯环，吡啶环，噻吩环，吡唑环等），杀虫剂和杀螨剂含有3-芳基苯基硫醚衍生物作为活性成分。

8. 发明授权

US06225505B1 Trifluoro methylthiomethyl benzene derivatives and process for production same 有权
标题翻译：三氟甲基硫代甲基苯衍生物和生产方法相同
公开(公告)号：US06225505B1
公开(公告)日：2001-05-01
申请号：US09463845
申请日：2000-02-01
申请人： Yoshikazu Kimura , Hidetaka Hiyoshi , Keiji Toriyabe , Nobuhide Wada
发明人： Yoshikazu Kimura , Hidetaka Hiyoshi , Keiji Toriyabe , Nobuhide Wada
IPC分类号： C07C31914
CPC分类号： C07C319/14 , C07C323/07 , C07C323/22 , C07C323/56 , C07C323/60
摘要： The present invention lies in a process for producing a trifluoromethylthiomethylbenzene derivative represented by the following general formula (2): (wherein R is a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group, a cyano group, a nitro group, or a benzoyl group which may be substituted with halogen atom, alkyl group, alkoxy group, aliphatic or aromatic acyl group, nitro group, cyano group or alkoxycarbonyl group; n is an integer of 1 to 5; when n is an integer of 2 or more, a plurality of R's may be the same of each independently different), which process comprises reacting, in acetonitrile, a benzyl halide derivative represented by the following general formula (1): (wherein R and n have the same definitions as given above; and X is a halogen atom, an alkylsulfonyloxy group or an arylsulfonyloxy group which may be substituted with alkyl group or halogen atom) with thiophosgene and potassium fluoride.
摘要翻译：本发明在于制备由以下通式（2）表示的三氟甲硫基甲基苯衍生物的方法：其中R是氢原子，卤素原子，烷基，烷氧基，烷氧基羰基，氰基，硝基或可被卤素原子，烷基，烷氧基，脂肪族或芳香族酰基，硝基，氰基或烷氧基羰基取代的苯甲酰基，n为1〜5的整数，n为1〜5的整数， 2个以上的整数，多个R可以各自独立地不同），该方法包括在乙腈中使由以下通式（1）表示的苄基卤衍生物:(其中R和n具有相同的定义如上所述; X为卤素原子，烷基磺酰氧基或可被烷基或卤原子取代的芳基磺酰氧基）与硫光气和氟化钾反应。

9. 发明授权

US5081244A Pyrimidine derivatives, processes for their production, and herbicidal method and compositions 失效
标题翻译：吡嗪衍生物，其生产方法和除草剂方法和组合物
公开(公告)号：US5081244A
公开(公告)日：1992-01-14
申请号：US454937
申请日：1989-12-22
申请人： Nobuhide Wada , Shoji Kusano , Yasuhumi Toyokawa
发明人： Nobuhide Wada , Shoji Kusano , Yasuhumi Toyokawa
IPC分类号： C07D239/52 , A01N43/54 , A01P13/00 , C07D239/54 , C07D239/553 , C07D239/60
CPC分类号： C07D239/553 , A01N43/54 , C07D239/60
摘要： A pyrimidine derivative having the formula: ##STR1## wherein R is hydrogen atom, --CH.sub.2 CH.sub.2 S(O).sub.n R.sub.1 (wherein R.sub.1 is a lower alkyl group, and n is an integer of from 0 to 2) or ##STR2## (wherein each R.sub.1 is a lower alkyl group), A is a chlorine atom or a methoxy group, and each of D and E which may be the same or different, is a hydrogen atom, a halogen atom, a lower alkyl group, a lower alkoxy group or a halogen-substituted lower alkoxy group, or a salt thereof.

10. 发明授权

US07767626B2 3-arylphenyl sulfide derivative and insecticide and miticide 有权
标题翻译： 3-芳基苯基硫化物衍生物和杀虫剂和杀螨剂
公开(公告)号：US07767626B2
公开(公告)日：2010-08-03
申请号：US12269549
申请日：2008-11-12
申请人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
发明人： Keiji Toriyabe , Nobuo Takefuji , Minoru Itou , Tetsuya Hirade , Kiyotoshi Nishiyama , Mitsuharu Asahida , Yasunobu Maeda , Nobuhide Wada , Toyokazu Fujisawa , Hiroyuki Yano , Masaaki Komatsu , Osamu Tada
IPC分类号： C07D333/08 , A01N43/00
CPC分类号： C07D213/12 , A01N31/08 , A01N31/14 , A01N33/10 , A01N37/08 , A01N37/34 , A01N41/10 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/54 , A01N43/56 , A01N43/653 , A01N43/76 , A01N43/78 , A01N47/18 , C07C317/32 , C07C317/48 , C07C323/18 , C07C323/20 , C07C323/36 , C07C323/63 , C07D213/32 , C07D213/48 , C07D213/57 , C07D213/64 , C07D239/36 , C07D239/38 , C07D239/40 , C07D249/08 , C07D333/24
摘要： 3-Arylphenyl sulfide derivatives represented by general formula (I): (wherein R is a C2-C6 alkyl group, a C2-C6 alkenyl group, a C2-C6 alkynyl group or the like, B0 to B2 and B3 are hydrogen atoms, halogen atoms, cyano groups, C1-C4 haloalkyl groups or the like, n is 0, 1 or 2, and Ar is a phenyl ring, a pyridine ring, a thiophene ring, a pyrazole ring or the like), and insecticides and miticides containing the 3-arylphenyl sulfide derivatives as an active ingredient.
摘要翻译：由通式（I）表示的3-芳基苯基硫醚衍生物：其中R为C2-C6烷基，C2-C6烯基，C2-C6炔基等，B0至B2和B3为氢原子，卤素原子，氰基，C 1〜C 4卤代烷基等，n为0,1或2，Ar为苯环，吡啶环，噻吩环，吡唑环等），杀虫剂和杀螨剂含有3-芳基苯基硫醚衍生物作为活性成分。

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