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1. 发明授权

US4975521A Polyamide, polyimide, and polyamide-imide polymers and copolymers using 3,5-diamino-t-butylbenzene 失效
标题翻译：使用3,5-二氨基 - 叔丁基苯的聚酰胺，聚酰亚胺和聚酰胺 - 酰亚胺聚合物和共聚物
公开(公告)号：US4975521A
公开(公告)日：1990-12-04
申请号：US509165
申请日：1990-04-16
申请人： Douglas E. Fjare , Neal R. Nowicki
发明人： Douglas E. Fjare , Neal R. Nowicki
IPC分类号： C08G69/32 , H05K1/03 , H05K3/00
CPC分类号： C08G69/32 , H05K1/0346 , H05K3/0017
摘要： Soluble, film-forming, polyamides, polyimides, and polyamide-imides and their copolymers made using 3,5-diamino-t-butylbenzene are described. These polymers have some solubility in organic solvents such as N-methylpyrrolidone, a high Tg, excellent thermal stability, lower density and lower moisture uptake and are useful in films, fibers and composites, and in the electronics industry as electrical component substrates, protective coatings, interlevel dielectrics and the like.
摘要翻译：描述了可溶性，成膜，聚酰胺，聚酰亚胺和聚酰胺 - 酰亚胺及其使用3,5-二氨基 - 叔丁基苯制备的共聚物。这些聚合物在诸如N-甲基吡咯烷酮的有机溶剂中具有一定的溶解度，Tg高，热稳定性优异，密度低，吸湿性更低，并且可用于膜，纤维和复合材料，并且在电子工业中用作电子元件基材，保护涂层，层间电介质等。

2. 发明授权

US4786752A Catalyst recovery and recycle of catalysts in pseudocument oxidation process 失效
标题翻译：催化剂在假文件氧化过程中的回收和再循环
公开(公告)号：US4786752A
公开(公告)日：1988-11-22
申请号：US92479
申请日：1987-09-03
申请人： Juergen K. Holzhauer , Wayne P. Schammel , Neal R. Nowicki
发明人： Juergen K. Holzhauer , Wayne P. Schammel , Neal R. Nowicki
IPC分类号： B01J23/889 , C07C51/265
CPC分类号： B01J23/8892 , C07C51/265 , Y02P20/584
摘要： A method is disclosed for recovery and recycle of metal catalyst components of a catalyst from the liquid-phase oxidation of pseudocumene in the presence of an oxidation catalyst comprising cobalt, manganese, and bromine components or cobalt, manganese, zirconium and bromine components wherein said catalyst components are recovered by oxalate precipitation from aqueous residue.
摘要翻译：公开了一种用于在包含钴，锰和溴组分或钴，锰，锆和溴组分的氧化催化剂存在下从假阳离子的液相氧化中回收和再循环催化剂的金属催化剂组分的方法，其中所述催化剂组分通过草酸盐从水性残渣中沉淀回收。

3. 发明授权

US4652674A Method for monitoring the fluorescence of 4-carboxy-p-terphenyl in crude terephthalic acid 失效
标题翻译：用于监测粗对苯二甲酸中4-羧基 - 对三联苯的荧光的方法
公开(公告)号：US4652674A
公开(公告)日：1987-03-24
申请号：US800726
申请日：1985-11-22
申请人： David E. James , Neal R. Nowicki , Robert W. McCoy
发明人： David E. James , Neal R. Nowicki , Robert W. McCoy
IPC分类号： G01N21/78 , C07C51/265 , C07C63/26 , C09K11/06 , G01N21/64 , G01N21/76 , G01N30/74 , C07C51/42 , G01N30/02
CPC分类号： G01N21/64 , C07C51/265 , Y10T436/201666
摘要： A method is disclosed for separating and measuring the fluorescence of 4-carboxy-p-terphenyl in crude terephthalic acid formed by the liquid-phase oxidation of p-xylene in a solvent.
摘要翻译：公开了一种用于分离和测量在溶剂中通过对二甲苯的液相氧化形成的粗对苯二甲酸中4-羧基 - 对三联苯的荧光的方法。

4. 发明授权

US4876329A Polyimide polymers and copolymers using 3,5-diaminobenzotrifluoride 失效
标题翻译：使用3,5-二氨基三氟甲苯的聚酰亚胺聚合物和共聚物
公开(公告)号：US4876329A
公开(公告)日：1989-10-24
申请号：US212508
申请日：1988-06-28
申请人： Weilong L. Chiang , Douglas E. Fjare , Neal R. Nowicki
发明人： Weilong L. Chiang , Douglas E. Fjare , Neal R. Nowicki
IPC分类号： C08G73/10
CPC分类号： C08G73/1039 , C08G73/1042 , C08G73/1067 , C08G73/1071
摘要： Partially soluble, film-forming polyimides and their copolymers made using 3,5-diaminobenzotrifluoride are described. Thin films and coatings of these materials are relatively colorless and the polymers have a high Tg, excellent thermal stability, lower moisture uptake, and lower dielectric constant. They are useful as films, fibers, molded articles and as protective coatings, interlevel dielectrics, electric circuit substrates and the like for the electronics industry.
摘要翻译：描述了使用3,5-二氨基三氟甲苯制备的部分可溶性成膜聚酰亚胺及其共聚物。这些材料的薄膜和涂层是相对无色的，聚合物具有高Tg，优异的热稳定性，较低的吸湿性和较低的介电常数。它们作为电子工业的薄膜，纤维，模制品以及作为保护涂层，层间电介质，电路基板等是有用的。

5. 发明授权

US4822527A Process for preparation of anthraquinones and fluorenones 失效
标题翻译：制备蒽醌和芴酮的方法
公开(公告)号：US4822527A
公开(公告)日：1989-04-18
申请号：US134839
申请日：1987-12-14
申请人： David E. James , Neal R. Nowicki
发明人： David E. James , Neal R. Nowicki
IPC分类号： C07C50/18 , C07C45/00
CPC分类号： C07C50/18 , Y02P20/584
摘要： A process is disclosed for producing cyclized aromatic compounds by the liquid-phase air oxidation of 2-methyl-substituted biphenyls and diphenylmethanes in an acetic acid medium in the presence of a cobalt-manganese-bromine catalyst or a zirconium-cobalt-manganese-bromine catalyst wherein the mole ratio of cobalt-to-manganese is about 1.0:0.1 to about 1.0:10.0 and the ratio of zirconium-to-cobalt is about 0.005:1.0 to about 0.20:1.0, and mole ratio of bromine to total metals of said cobalt-manganese-bromine catalyst or zirconium-cobalt-manganese-bromine catalyst is from about 0.2:1.0 to about 20.0:1.0, which process comprises conducting the reaction in a batch process at a temperature of from 75.degree. C. to about 250.degree. C. at a pressure of from 1 to 100 atmospheres, or continuously in two stages comprising a first-stage reaction at a temperature of about 75.degree. C. to about 200.degree. C. and a second-stage reaction at a temperature of about 150.degree. C. to about 250.degree. C. and recycling the cobalt-manganese catalyst or the zircnium-cobalt-manganese catalyst by oxalate precipitation of the catalyst at temperatures of about 110.degree. C. to about 200.degree. C. prior to the separation of mother liquor and using about 0.25 to about 2.5 moles of oxalic acid per mole of cobalt and manganese or mole of zirconium-cobalt-manganese and continuously recycling the recovered catalyst metals to the oxidation stages. The products of this novel process, anthraquinones and fluorenones, are useful for the manufacture of dyestuffs and pharmaceuticals.
摘要翻译：公开了在钴锰溴催化剂或锆 - 钴 - 锰 - 溴存在下，通过在乙酸介质中通过2-甲基取代的联苯和二苯基甲烷的液相空气氧化来生产环化芳族化合物的方法催化剂，其中钴与锰的摩尔比为约1.0:0.1至约1.0:10.0，锆与钴的摩尔比为约0.005:1.0至约0.20:1.0，溴与总金属的摩尔比为所述钴 - 锰 - 溴催化剂或锆 - 钴 - 锰 - 溴催化剂的量为约0.2:1.0至约20.0:1.0，该方法包括在75℃至约250℃的间歇过程中进行反应在1〜100个大气压的压力下，或者在约75℃至约200℃的温度下包括第一阶段反应的两个阶段的连续两个阶段，以及在约 150℃至约250℃并回收钴锰催化剂或锆 - 钴 - 锰催化剂，在母液分离之前，在约110℃至约200℃的温度下草酸盐沉淀催化剂，并使用约0.25至约2.5摩尔的草酸每摩尔钴和锰或摩尔的锆 - 钴 - 锰，并将回收的催化剂金属连续循环到氧化阶段。该新方法的产物，蒽醌和芴酮可用于制造染料和药物。

6. 发明授权

US5206091A Low dielectric constant, low moisture uptake polyimides and copolyimides for interlevel dielectrics and substrate coatings 失效
标题翻译：低介电常数，低吸湿聚酰亚胺和共聚酰亚胺，用于层间电介质和基底涂层
公开(公告)号：US5206091A
公开(公告)日：1993-04-27
申请号：US436301
申请日：1989-11-13
申请人： Allyson J. Beuhler , Neal R. Nowicki , Douglas E. Fjare
发明人： Allyson J. Beuhler , Neal R. Nowicki , Douglas E. Fjare
IPC分类号： C08G73/10 , H05K1/03
CPC分类号： C08G73/105 , C08G73/1071 , H05K1/0346 , Y10T428/31681 , Y10T428/31721
摘要： A group of polyimides and copolyimides made from 6FDA, IPAN, or their acid or ester forms, and selected aromatic diamines are disclosed which are useful for substrate coatings and interlevel dielectrics in on-chip and multi-chip package applications. In such applications these polymers exhibit lower dielectric constant, lower moisture uptake and reduced dielectric constant variation with temperature and humidity than existing polymers, yet they are both thermally stable at required processing temperatures and can form suitably adherent, pinhole-free coatings on electronic component substrates.
摘要翻译：公开了一组由6FDA，IPAN或其酸或酯形式制备的聚酰亚胺和共聚酰亚胺，以及选择的芳族二胺，其可用于片上和多芯片封装应用中的底物涂层和层间电介质。在这些应用中，这些聚合物表现出比现有聚合物更低的介电常数，更低的吸湿性和降低的温度和湿度的介电常数变化，但它们在所需的加工温度下都是热稳定的，并且可以在电子部件基底上形成适当粘附的无针孔涂层。

7. 发明授权

US4973659A Polyamide from diamino-t-butylbenzene 失效
标题翻译：来自二氨基叔丁基苯的聚酰胺
公开(公告)号：US4973659A
公开(公告)日：1990-11-27
申请号：US277756
申请日：1988-11-30
申请人： David J. Fenoglio , Douglas E. Fjare , John L. Melquist , Edwin F. Morello , Neal R. Nowicki
发明人： David J. Fenoglio , Douglas E. Fjare , John L. Melquist , Edwin F. Morello , Neal R. Nowicki
IPC分类号： C08G69/32 , H05K1/03 , H05K3/00
CPC分类号： C08G69/32 , H05K1/0346 , H05K3/0017
摘要： Resinous condensation polymers of polycarboxylic acid compounds and aromatic diprimary amines comprising diamino-t-butylbenzenes are described. In particular, film-forming polyamides, polyimides and polyamide-imides and their copolymers made using diamono-t-butylbenzenes which have amino groups meta or para to each other on a benzene ring are described. These polymers have some solubility in organic solvents such as N-methylpyrrolidone, a high glass transition temperature, excellent thermal stability, and are useful in films, fibers and composites, and in the electronics industry as electrical component substrates, protective coatings, interlevel dielectrics and the like.
摘要翻译：描述了包含二氨基叔丁基苯的聚羧酸化合物和芳族二胺的树脂缩聚物。特别地，描述了使用在苯环上彼此间隔或间隔氨基的二亚氨基叔丁基苯制备的成膜聚酰胺，聚酰亚胺和聚酰胺 - 酰亚胺及其共聚物。这些聚合物在有机溶剂如N-甲基吡咯烷酮中具有一定的溶解度，玻璃化转变温度高，热稳定性优异，并且可用于膜，纤维和复合材料，并且在电子工业中可用作电组件衬底，保护涂层，层间电介质和类似。

8. 发明授权

US4876385A Batch or semicontinuous pseudocumene oxidation and catalyst recovery and recycle 失效
标题翻译：分批或半连续假阳离子氧化和催化剂回收和再循环
公开(公告)号：US4876385A
公开(公告)日：1989-10-24
申请号：US173711
申请日：1988-03-25
申请人： Neal R. Nowicki , Donald E. Thomka
发明人： Neal R. Nowicki , Donald E. Thomka
IPC分类号： B01J23/889 , C07C51/265
CPC分类号： B01J23/8892 , C07C51/265 , Y02P20/584
摘要： A method is disclosed for the liquid-phase oxidation of pseudocumene in the presence of an oxidation catalyst comprising cobalt, manganese, and bromine components wherein the metal catalyst are recycled to the oxidation reactor in the form of their oxalates.
摘要翻译：公开了一种在含有钴，锰和溴组分的氧化催化剂存在下对假枯烯进行液相氧化的方法，其中金属催化剂以其草酸盐的形式再循环到氧化反应器中。

9. 发明授权

US4816601A Process for the manufacture of trimellitic acid 失效
标题翻译：制备偏苯三酸的方法
公开(公告)号：US4816601A
公开(公告)日：1989-03-28
申请号：US72527
申请日：1987-07-13
申请人： James D. Lowry , Neal R. Nowicki , Walter Partenheimer
发明人： James D. Lowry , Neal R. Nowicki , Walter Partenheimer
IPC分类号： B01J23/889 , C07C51/265
CPC分类号： B01J23/8892 , C07C51/265 , Y02P20/584
摘要： A continuous process is disclosed for producing trimellitic acid by the liquid-phase air oxidation of pseudocumene in an acetic acid medium in the presence of a cobalt-manganese-bromine catalyst or a zirconium-cobalt-manganese-bromine catalyst wherein the mole ratio of cobalt-to-manganese is about 1.0:0.1 to about 1:5 and the ratio of zirconium-to-cobalt is about 0.005:1 to about 0.20:1, and mole ratio of bromine to total metals of said cobalt-manganese-bromine catalyst or zirconium-cobalt-manganese-bromine catalyst is from about 0.2:1.0 to about 2.0:1.0, which process comprises conducting the reaction continuously in two stages comprising a first-stage reaction at a temperature of about 250.degree. F. to about 350.degree. F. and a second-stage reaction at a temperature of about 350.degree. F. to about 450.degree. F. and recycling the cobalt-manganese catalyst or the zirconium-cobalt-manganese catalyst by oxalate precipitation of the catalyst at temperatures of about 250.degree. F. to about 375.degree. F. prior to the separation of mother liquor and using about 0.25 to about 2.5 moles of oxalic acid per mole of cobalt and manganese or mole of zirconium-cobalt-manganese and continuously recycling the recovered catalyst metals to the first-stage oxidation. The product of this novel process, trimellitic acid, is useful for the manufacture of polyamide-imides which are used as fibers or molded articles, including automotive parts.
摘要翻译：公开了一种在钴 - 溴 - 溴催化剂或锆 - 钴 - 锰 - 溴催化剂存在下，在乙酸介质中通过假阳离子的液相空气氧化制备偏苯三酸的连续方法，其中钴 - 锰为约1.0：0.1至约1:5，锆与钴的比例为约0.005：1至约0.20：1，溴与所述钴 - 锰 - 溴催化剂的总金属摩尔比或锆 - 钴 - 锰 - 溴催化剂的量为约0.2:1.0至约2.0:1.0，该方法包括在约250°F至约350℃的温度下连续进行包括第一阶段反应的两个步骤的反应在约350°F至约450°F的温度下进行第二阶段反应，并在大约250℃的温度下通过草酸盐沉淀催化剂再循环钴 - 锰催化剂或锆 - 钴 - 锰催化剂 F.至约375°F 或母液的分离，并使用约0.25至约2.5摩尔草酸/摩尔钴和锰或摩尔的锆 - 钴 - 锰，并将回收的催化剂金属连续循环至第一阶段氧化。该新方法偏苯三酸的产物可用于制造用作纤维或模塑制品的聚酰胺 - 酰亚胺，包括汽车部件。

10. 发明授权

US4804501A Process for preparation of anthraquinones and fluorenones 失效
标题翻译：制备蒽醌和芴酮的方法
公开(公告)号：US4804501A
公开(公告)日：1989-02-14
申请号：US185432
申请日：1988-04-25
申请人： David E. James , Neal R. Nowicki
发明人： David E. James , Neal R. Nowicki
IPC分类号： C07C50/18 , C07B33/00 , C07C45/00
CPC分类号： C07C50/18 , Y02P20/584
摘要： A process is disclosed for producing cyclized aromatic compounds by the liquid-phase air oxidation of 2-methyl-substituted biphenyls and diphenylmethanes in an acetic acid medium in the presence of a cobalt-manganese-bromine catalyst or a zirconium-cobalt-manganese-bromine catalyst wherein the mole ratio of cobalt-to-manganese is about 1.0:0.1 to about 1.0:10.0 and the ratio of zirconium-to-cobalt is about 0.005:1.0 to about 0.20:1.0, and mole ratio of bromine to total metals of said cobalt-manganese-bromine catalyst or zirconium-cobalt-manganese-bromine catalyst is from about 0.2:1.0 to about 20.0:1.0, which process comprises conducting the reaction in a batch process at a temperature of from 75.degree. C. to about 250.degree. C. at a pressure of from 1 to 100 atmospheres, or continuously in two stages comprising a first-stage reaction at a temperature of about 75.degree. C. to about 200.degree. C. and a second-stage reaction at a temperature of about 150.degree. C. to about 250.degree. C. and recycling the cobalt-manganese catalyst or the zirconium-cobalt-manganese catalyst by oxalate precipitation of the catalyst at temperatures of about 110.degree. C. to about 200.degree. C. prior to the separation of mother liquor and using about 0.25 to about 2.5 moles of oxalic acid per mole of cobalt and manganese or mole of zirconium-cobalt-manganese and continuously recycling the recovered catalyst metals to the oxidation stages. The products of this novel process, anthraquinones and fluorenones, are useful for the manufacture of dyestuffs and pharmaceuticals.
摘要翻译：公开了在钴锰溴催化剂或锆 - 钴 - 锰 - 溴存在下，通过在乙酸介质中通过2-甲基取代的联苯和二苯基甲烷的液相空气氧化来生产环化芳族化合物的方法催化剂，其中钴与锰的摩尔比为约1.0:0.1至约1.0:10.0，锆与钴的摩尔比为约0.005:1.0至约0.20:1.0，溴与总金属的摩尔比为所述钴 - 锰 - 溴催化剂或锆 - 钴 - 锰 - 溴催化剂的量为约0.2:1.0至约20.0:1.0，该方法包括在75℃至约250℃的间歇过程中进行反应在1〜100个大气压的压力下，或者在约75℃至约200℃的温度下包括第一阶段反应的两个阶段的连续两个阶段，以及在约 150℃至约250℃并回收钴 - 锰催化剂或锆 - 钴 - 锰催化剂，在母液分离之前，在约110℃至约200℃的温度下草酸盐沉淀催化剂，并使用约0.25至约2.5摩尔的草酸每摩尔钴和锰或摩尔的锆 - 钴 - 锰，并将回收的催化剂金属连续循环到氧化阶段。该新方法的产物，蒽醌和芴酮可用于制造染料和药物。

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