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1. 发明申请

US20140107275A1 COATING AGENT COMPOSITION FOR BATTERY ELECTRODE OR SEPARATOR 审中-公开
标题翻译：电池电极或分离器用涂料组合物
公开(公告)号：US20140107275A1
公开(公告)日：2014-04-17
申请号：US14123486
申请日：2012-05-31
申请人： Taichi Uemura , Satoshi Yamazaki , Mitsuo Shibutani , Kazuo Aiba
发明人： Taichi Uemura , Satoshi Yamazaki , Mitsuo Shibutani , Kazuo Aiba
IPC分类号： H01M4/62
CPC分类号： H01M4/62 , C09D5/022 , C09D5/027 , C09D133/04 , C09D133/12 , C09D151/00 , C09D153/00 , H01M2/145 , H01M2/1653 , H01M2/166 , H01M2/1686 , H01M4/0409 , H01M4/366 , H01M4/628 , H01M10/0525 , H01M10/4235 , H01M2220/20 , H01M2220/30 , C09D129/04 , C08L53/02 , C08L29/04
摘要： A coating agent composition for battery electrode or separator, comprises a vinyl alcohol copolymer having a structural unit represented by the general formula (1), and an aqueous emulsion of a synthetic resin obtained by polymerizing a copolymerizable monomer having an acrylic monomer as a main component, or an aqueous emulsion of a styrene thermoplastic elastomer.
摘要翻译：用于电池电极或隔膜的涂料组合物包括具有由通式（1）表示的结构单元的乙烯醇共聚物和通过聚合具有丙烯酸类单体作为主要成分的可共聚单体得到的合成树脂的水性乳液，或苯乙烯热塑性弹性体的水性乳液。

2. 发明申请

US20130131270A1 RESIN COMPOSITION AND MOLDED ARTICLE THEREOF 有权
标题翻译：树脂组合物及其成型品
公开(公告)号：US20130131270A1
公开(公告)日：2013-05-23
申请号：US13813046
申请日：2011-07-28
申请人： Mitsuo Shibutani , Kaoru Inoue , Norihito Sakai
发明人： Mitsuo Shibutani , Kaoru Inoue , Norihito Sakai
IPC分类号： C08L29/04
CPC分类号： C08L29/04 , C08L51/08 , C08L53/02 , C08L2205/03 , C08L53/025 , C08L87/005 , C08L77/00
摘要： There is provided a resin composition affording a melt-molded article having excellent gas barrier properties and flex crack resistance. The present invention relates to a resin composition comprising a polyvinyl alcohol resin (A) having a 1,2-diol structural unit represented by the following general formula (1), a styrene-based thermoplastic elastomer (B), and a polyamide graft block copolymer (C) containing a polymer block of an aromatic vinyl compound and a polymer block of an olefinic compound in a main chain and having a graft chain composed of a polyamide: wherein each of R1, R2, and R3 independently represents a hydrogen atom or an organic group, X represents a single bond or a linking chain, and each of R4, R5, and R6 independently represents a hydrogen atom or an organic group.
摘要翻译：提供了提供具有优异的阻气性和抗开裂性的熔融模制品的树脂组合物。本发明涉及一种树脂组合物，其包含具有由以下通式（1）表示的1,2-二醇结构单元的聚乙烯醇树脂（A），苯乙烯类热塑性弹性体（B）和聚酰胺接枝嵌段共聚物（C），其包含芳族乙烯基化合物的聚合物嵌段和主链中的烯属化合物的聚合物嵌段，并且具有由聚酰胺构成的接枝链：其中R 1，R 2和R 3各自独立地表示氢原子或有机基团，X表示单键或连接链，R 4，R 5和R 6各自独立地表示氢原子或有机基团。

3. 发明申请

US20120157627A1 POLYVINYL ALCOHOL RESIN COMPOSITION AND MOLDED ARTICLE THEREOF 有权
标题翻译：聚乙烯醇树脂组合物及其成型品
公开(公告)号：US20120157627A1
公开(公告)日：2012-06-21
申请号：US13407278
申请日：2012-02-28
申请人： Mitsuo SHIBUTANI , Kazutoshi TSUJI , Kaoru INOUE , Norihito SAKAI
发明人： Mitsuo SHIBUTANI , Kazutoshi TSUJI , Kaoru INOUE , Norihito SAKAI
IPC分类号： C08L29/04
CPC分类号： C08L29/04 , C08L53/02 , C08L53/025 , C08L2205/02 , C08L2205/03
摘要： Disclosed is a polyvinyl alcohol resin composition capable of providing a melt-molded article with superior gas barrier properties and flex crack resistance. The resin composition comprises (A) a PVA resin having 1,2-diol unit in side chain thereof; and (B) a mixture of block copolymers each having an aromatic vinyl polymer block, and a conjugated diene polymer block and/or hydrogenated thereof, wherein the (B) mixture of block copolymers includes (B1) a block copolymer having no carboxyl group and (B2) a block copolymer modified with a carboxyl group-containing compound.
摘要翻译：公开了一种聚乙烯醇树脂组合物，其能够提供具有优异的阻气性和抗起裂性的熔融模制品。树脂组合物包含（A）其侧链上具有1,2-二醇单元的PVA树脂; 和（B）各自具有芳族乙烯基聚合物嵌段和共轭二烯聚合物嵌段和/或氢化的嵌段共聚物的混合物，其中嵌段共聚物的（B）混合物包括（B1）不具有羧基的嵌段共聚物和（B2）用含羧基的化合物改性的嵌段共聚物。

4. 发明申请

US20120110683A1 NON-HUMAN ANIMAL MODEL OF MYOCARDIAL INFARCTION AND METHOD FOR CREATING THE SAME 审中-公开
标题翻译：非人类动物模型的心肌梗塞及其创造方法
公开(公告)号：US20120110683A1
公开(公告)日：2012-05-03
申请号：US13288158
申请日：2011-11-03
申请人： Yuzo SHOMURA , Mitsuo SHIBUTANI , Taizo TANIGUCHI , Yasuo HARA
发明人： Yuzo SHOMURA , Mitsuo SHIBUTANI , Taizo TANIGUCHI , Yasuo HARA
IPC分类号： A01K67/00 , A61K9/14 , A61M25/10 , A61K31/765
CPC分类号： A01K67/027 , A01K2207/30 , A01K2227/105 , A01K2267/0375
摘要： The present invention provides a non-human animal model of myocardial infarction, which can be created by a less invasive method, shows an extremely low mortality during and after surgical induction of myocardial infarction, ensures the blood reflow after necrosis of cardiac muscles caused by blocking blood flow, and therefore, is usable in topical therapy for myocardial infarction and studies on regenerative medicine. The present invention also provides a method for creating the non-human animal model comprising administering a temporary embolic agent to a branch blood vessel of a heart coronary artery to block blood flow in the branch blood vessel; and after a definite period of time after said vascular branch blockage, administering a temporary embolic agent to the target coronary artery which is intended to induce myocardial infarction to block blood flow in the target coronary artery.
摘要翻译：本发明提供了一种心肌梗塞非人动物模型，其可以通过较少侵入性的方法产生，在心肌梗塞手术诱导期间和之后显示极低的死亡率，确保由阻塞引起的心肌坏死后的血液回流血液流动，因此可用于心肌梗死的局部治疗和再生医学研究。本发明还提供了一种用于产生非人动物模型的方法，其包括向心脏冠状动脉的分支血管施用临时栓塞剂以阻断分支血管中的血流; 并且在所述血管分支阻塞后的一定时间段之后，向旨在诱导心肌梗死的目标冠状动脉施用临时栓塞剂以阻断目标冠状动脉中的血流。

5. 发明申请

US20100029846A1 Aqueous Emulsion and Uses Thereof 有权
标题翻译：水性乳液及其用途
公开(公告)号：US20100029846A1
公开(公告)日：2010-02-04
申请号：US12226575
申请日：2006-04-25
申请人： Mitsuo Shibutani , Masahiro Saito
发明人： Mitsuo Shibutani , Masahiro Saito
IPC分类号： C08F2/32 , C08F2/22
CPC分类号： C08F2/30 , C08F261/04 , C08L29/02 , C08L31/04 , C08L33/00 , C08L33/08 , C08L2666/04 , C09J133/08 , C09J151/003 , C08F220/12 , C08L2666/06
摘要： The invention is to provide: an aqueous emulsion which is excellent in emulsion polymerization stability when produced, and is excellent in mechanical stability, freezing stability, stability to long-term standing at high temperatures, water resistance adhesive property, and redispersibility; and a redispersible resin and adhesive where the aqueous emulsion is used. The invention relates to an aqueous emulsion comprising a polyvinyl alcohol-based resin (A) comprising a 1,2-diol component in a side chain and having an average degree of polymerization of 50 to 2,500 and a polymer (B) comprising at least one unsaturated monomer selected from an ethylenically unsaturated monomer and a diene-based monomer.
摘要翻译：本发明提供一种制造时的乳液聚合稳定性优异，机械稳定性，冷冻稳定性，长期高温稳定性，耐水性粘合性，再分散性优异的水性乳液。以及使用水性乳液的可再分散树脂和粘合剂。本发明涉及一种水性乳液，其包含在侧链中包含1,2-二醇组分的平均聚合度为50至2,500的聚乙烯醇类树脂（A）和包含至少一种选自烯属不饱和单体和二烯类单体的不饱和单体。

6. 发明授权

US07491766B2 Aqueous emulsion and use thereof 有权
标题翻译：水乳液及其用途
公开(公告)号：US07491766B2
公开(公告)日：2009-02-17
申请号：US11081360
申请日：2005-03-04
申请人： Mitsuo Shibutani , Kiyoharu Kitamura , Kinji Taki , Masaaki Yamada
发明人： Mitsuo Shibutani , Kiyoharu Kitamura , Kinji Taki , Masaaki Yamada
IPC分类号： C08K3/20 , C08F16/26
CPC分类号： C08F263/00 , C08F261/04 , C08L29/04 , C08L33/00 , C08L51/003 , C08L2666/02 , C09J151/003 , C08L2666/04
摘要： The present invention provides an aqueous emulsion having excellent polymerization stability and standing stability and a redispersible powder. Specifically, the present invention relates to an aqueous emulsion of a polymer obtained by polymerizing an acrylic monomer in the presence of a polyvinyl alcohol containing an acetoacetic ester group; wherein the polyvinyl alcohol containing an acetoacetic ester group has block character [η] of 0.3 to 0.6, hydrolysis degree of at least 97% by mol and acetoacetic esterification degree of 0.01 to 1.5% by mol, and the value obtained by dividing the maximum value by the minimum value of the respective average acetoacetic esterification degree for each of the polyvinyl alcohol containing an acetoacetic ester group separated by particle size of 44 to 74, 74 to 105, 105 to 177, 177 to 297, 297 to 500 and 500 to 1680 μm is 1.0 to 3.0. Also, the present invention relates to a redispersible fiber obtained by drying the aqueous emulsion.
摘要翻译：本发明提供了具有优异的聚合稳定性和稳定性的水性乳液和可再分散的粉末。具体地说，本发明涉及通过在含有乙酰乙酸酯基的聚乙烯醇存在下聚合丙烯酸类单体获得的聚合物的水性乳液; 其中含有乙酰乙酸酯基的聚乙烯醇的嵌段特性η为0.3〜0.6，水解度为97摩尔％以上，乙酰乙酸酯化度为0.01〜1.5摩尔％，通过除去最大值通过分别由44〜74,74〜105,105〜177,177〜297,297〜500和500〜1680分隔的含有乙酰乙酸酯基的各聚乙烯醇的各自的平均乙酰乙酸酯化度的最小值妈妈是1.0到3.0。此外，本发明涉及通过干燥水性乳液获得的可再分散纤维。

7. 发明授权

US06613853B1 Production method of vinyl resin 有权
标题翻译：乙烯基树脂的生产方法
公开(公告)号：US06613853B1
公开(公告)日：2003-09-02
申请号：US09696495
申请日：2000-10-25
申请人： Mitsuo Shibutani
发明人： Mitsuo Shibutani
IPC分类号： C08F220
CPC分类号： C08F2/20
摘要： A production method of a vinyl resin, which comprises subjecting a vinyl compound to suspension polymerization in a polymerization tank equipped with a reflux condenser in the presence of a dispersion stabilizer, wherein a polyvinyl alcohol resin (A) having a degree of hydrolysis of not less than 65 mol %, a polymerization degree of not less than 700 and satisfying the following formula (1) 0.0300≦(3−Y)/X
摘要翻译：一种乙烯基树脂的制造方法，其特征在于，在分散稳定剂的存在下，在配备有回流冷凝器的聚合槽中使乙烯基化合物进行悬浮聚合，其中，水解度为聚乙烯醇树脂（A） 65摩尔％，聚合度不低于700，满足下式（1）其中X为水解度（摩尔％），Y为碘吸收度，以聚合转化率乙烯基化合物不低于30％。本发明的乙烯基树脂的制造方法提供了具有高堆积密度的乙烯基树脂，其表现出优异的消泡效果以抑制在中间和后期聚合期间产生的干燥泡沫。

8. 发明授权

US06573327B1 Highly stable aqueous solution of partially saponified vinyl ester resin 有权
标题翻译：高度稳定的部分皂化乙烯基酯树脂水溶液
公开(公告)号：US06573327B1
公开(公告)日：2003-06-03
申请号：US09402111
申请日：1999-09-29
申请人： Mitsuo Shibutani
发明人： Mitsuo Shibutani
IPC分类号： C08L2904
CPC分类号： C08L29/04 , C08F2/20 , C08F8/12 , C08F2800/10 , C08J5/18 , C08F218/08 , C08F2216/1433 , C08F222/10 , C08F220/58 , C08F228/04 , C08F222/02 , C08F228/02 , C08F226/06
摘要： An aqueous solution of partially hydrolyzed vinyl ester resin having an excellent stability and useful particularly as a secondary agent for suspension polymerization of vinyl compounds, wherein the partially hydrolyzed vinyl ester resin has a degree of hydrolysis of at most 70% by mole, it is contained in a concentration of at most 50% by weight, and it satisfies the equation: 1n y>0.042x+1.0, in which y is the cloud point (° C.) of a 30% by weight aqueous solution of the partially hydrolyzed vinyl ester resin, and x is the degree of hydrolysis (% by mole) of the partially hydrolyzed vinyl ester resin.
摘要翻译：包含部分水解的乙烯基酯树脂的水溶液具有优异的稳定性并且特别用作乙烯基化合物的悬浮聚合的二次试剂，其中部分水解的乙烯基酯树脂的水解度至多为70摩尔％，其含有浓度为50重量％以下，满足下式：1n y> 0.042×1.0，其中y为部分水解乙烯基的30重量％水溶液的浊点（℃）酯树脂，x是部分水解的乙烯基酯树脂的水解度（摩尔％）。

9. 发明授权

US08772400B2 Polyvinyl alcohol-based film for optical use, polarizing film, and polarizing plate 失效
标题翻译：用于光学用的聚乙烯醇基膜，偏振膜和偏振片
公开(公告)号：US08772400B2
公开(公告)日：2014-07-08
申请号：US12309657
申请日：2006-07-27
申请人： Shuichi Kitamura , Katsuhiko Katsuma , Mitsuo Shibutani , Toshihiro Shimizu
发明人： Shuichi Kitamura , Katsuhiko Katsuma , Mitsuo Shibutani , Toshihiro Shimizu
IPC分类号： C08L29/04
CPC分类号： G02B5/3033 , C08J5/18 , C08J2329/04 , C08L29/04 , C08L2205/02 , C08L2666/04
摘要： The present invention provides a polyvinyl alcohol-based film for optical uses, which is excellent in stretching property and is used for producing a polarizing film excellent in polarization performance throughout the visible light wavelength range, particularly in the vicinity of the wavelength of 460 nm. The invention relates to a polyvinyl alcohol-based film for optical uses comprising a polyvinyl alcohol-based resin, wherein the polyvinyl alcohol-based resin is composed of only a polyvinyl alcohol-based resin (A) containing a 1,2-glycol bond at a side chain and the amount of the 1,2-glycol bond at a side chain is from 0.01 to 6% by mol, or a polyvinyl alcohol-based film for optical uses comprising a polyvinyl alcohol-based resin, wherein the polyvinyl alcohol-based resin includes a polyvinyl alcohol-based resin (A) containing a 1,2-glycol bond at a side chain and a polyvinyl alcohol-based resin (B) other than the polyvinyl alcohol-based resin (A) and satisfies the following expression (1): 0.01≦A×G/(A+B)≦6 (1) wherein A represents a content ratio (weight ratio) of the polyvinyl alcohol-based resin (A) based on a total amount of the polyvinyl alcohol-based resin (A) and the polyvinyl alcohol-based resin (B), B represents a content ratio (weight ratio) of the polyvinyl alcohol-based resin (B) based on the above total amount, and G represents an amount (% by mol) of the 1,2-glycol bond at a side chain.
摘要翻译：本发明提供一种拉伸性优异的聚乙烯醇系的光学用薄膜，特别是在波长460nm附近，可用于制造偏光性能优异的偏光性能优异的偏光膜。本发明涉及包含聚乙烯醇类树脂的光学用聚乙烯醇系膜，其中，聚乙烯醇类树脂仅由含有1,2-二醇键的聚乙烯醇系树脂（A）构成，侧链，侧链上的1,2-二醇键的量为0.01〜6摩尔％，或者是含有聚乙烯醇类树脂的光学用聚乙烯醇类膜，其中，聚乙烯醇 - 基于树脂的树脂包括侧链上含有1,2-二醇键的聚乙烯醇系树脂（A）和聚乙烯醇系树脂（A）以外的聚乙烯醇系树脂（B），满足下式（1）：0.01＆nlE; A×G /（A + B）＆nlE; 6（1）其中A表示聚乙烯醇类树脂（A）的含量比（重量比）醇系树脂（A）和聚乙烯醇系树脂（B），B表示聚乙烯醇的含量比（重量比）基于上述总量的苯乙烯类树脂（B），G表示侧链上的1,2-二醇键的量（摩尔％）。

10. 发明授权

US08691892B2 Chaff molding and production method thereof 有权
标题翻译：其成型及其制造方法
公开(公告)号：US08691892B2
公开(公告)日：2014-04-08
申请号：US12150150
申请日：2008-04-25
申请人： Kenji Kikuchi , Mitsuo Shibutani , Shusaku Mandai
发明人： Kenji Kikuchi , Mitsuo Shibutani , Shusaku Mandai
IPC分类号： B32B5/16 , C08K3/30 , C08K5/00 , C08L29/04
CPC分类号： C08L97/02 , Y10T428/258 , C08K3/24 , C08L29/04
摘要： This invention provides a chaff molding which is excellent in a compressive strength. Said chaff molding comprises a chaff and a polyvinyl alcohol-based resin having a 1,2-diol structure as a side chain.
摘要翻译：本发明提供一种压缩强度优异的谷壳成型体。所述糠模具包括具有作为侧链的1,2-二醇结构的谷壳和聚乙烯醇系树脂。

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