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    • 1. 发明授权
    • Polyvinyl alcohol-based film for optical use, polarizing film, and polarizing plate
    • 用于光学用的聚乙烯醇基膜,偏振膜和偏振片
    • US08772400B2
    • 2014-07-08
    • US12309657
    • 2006-07-27
    • Shuichi KitamuraKatsuhiko KatsumaMitsuo ShibutaniToshihiro Shimizu
    • Shuichi KitamuraKatsuhiko KatsumaMitsuo ShibutaniToshihiro Shimizu
    • C08L29/04
    • G02B5/3033C08J5/18C08J2329/04C08L29/04C08L2205/02C08L2666/04
    • The present invention provides a polyvinyl alcohol-based film for optical uses, which is excellent in stretching property and is used for producing a polarizing film excellent in polarization performance throughout the visible light wavelength range, particularly in the vicinity of the wavelength of 460 nm. The invention relates to a polyvinyl alcohol-based film for optical uses comprising a polyvinyl alcohol-based resin, wherein the polyvinyl alcohol-based resin is composed of only a polyvinyl alcohol-based resin (A) containing a 1,2-glycol bond at a side chain and the amount of the 1,2-glycol bond at a side chain is from 0.01 to 6% by mol, or a polyvinyl alcohol-based film for optical uses comprising a polyvinyl alcohol-based resin, wherein the polyvinyl alcohol-based resin includes a polyvinyl alcohol-based resin (A) containing a 1,2-glycol bond at a side chain and a polyvinyl alcohol-based resin (B) other than the polyvinyl alcohol-based resin (A) and satisfies the following expression (1): 0.01≦A×G/(A+B)≦6  (1) wherein A represents a content ratio (weight ratio) of the polyvinyl alcohol-based resin (A) based on a total amount of the polyvinyl alcohol-based resin (A) and the polyvinyl alcohol-based resin (B), B represents a content ratio (weight ratio) of the polyvinyl alcohol-based resin (B) based on the above total amount, and G represents an amount (% by mol) of the 1,2-glycol bond at a side chain.
    • 本发明提供一种拉伸性优异的聚乙烯醇系的光学用薄膜,特别是在波长460nm附近,可用于制造偏光性能优异的偏光性能优异的偏光膜。 本发明涉及包含聚乙烯醇类树脂的光学用聚乙烯醇系膜,其中,聚乙烯醇类树脂仅由含有1,2-二醇键的聚乙烯醇系树脂(A)构成, 侧链,侧链上的1,2-二醇键的量为0.01〜6摩尔%,或者是含有聚乙烯醇类树脂的光学用聚乙烯醇类膜,其中,聚乙烯醇 - 基于树脂的树脂包括侧链上含有1,2-二醇键的聚乙烯醇系树脂(A)和聚乙烯醇系树脂(A)以外的聚乙烯醇系树脂(B),满足下式 (1):0.01≦̸ A×G /(A + B)≦̸ 6(1)其中A表示聚乙烯醇类树脂(A)的含量比(重量比) 醇系树脂(A)和聚乙烯醇系树脂(B),B表示聚乙烯醇的含量比(重量比) 基于上述总量的苯乙烯类树脂(B),G表示侧链上的1,2-二醇键的量(摩尔%)。
    • 2. 发明申请
    • POLYVINYL ALCOHOL-BASED FILM FOR OPTICAL USE, POLARIZING FILM, AND POLARIZING PLATE
    • 用于光学应用的聚乙烯醇基膜,极化膜和极化板
    • US20090316264A1
    • 2009-12-24
    • US12309657
    • 2006-07-27
    • Shuichi KitamuraKatsuhiko KatsumaMitsuo ShibutaniToshihiro Shimizu
    • Shuichi KitamuraKatsuhiko KatsumaMitsuo ShibutaniToshihiro Shimizu
    • G02B1/08B32B27/36C08G63/91
    • G02B5/3033C08J5/18C08J2329/04C08L29/04C08L2205/02C08L2666/04
    • The present invention provides a polyvinyl alcohol-based film for optical uses, which is excellent in stretching property and is used for producing a polarizing film excellent in polarization performance throughout the visible light wavelength range, particularly in the vicinity of the wavelength of 460 nm. The invention relates to a polyvinyl alcohol-based film for optical uses comprising a polyvinyl alcohol-based resin, wherein the polyvinyl alcohol-based resin is composed of only a polyvinyl alcohol-based resin (A) containing a 1,2-glycol bond at a side chain and the amount of the 1,2-glycol bond at a side chain is from 0.01 to 6% by mol, or a polyvinyl alcohol-based film for optical uses comprising a polyvinyl alcohol-based resin, wherein the polyvinyl alcohol-based resin includes a polyvinyl alcohol-based resin (A) containing a 1,2-glycol bond at a side chain and a polyvinyl alcohol-based resin (B) other than the polyvinyl alcohol-based resin (A) and satisfies the following expression (1): 0.01≦A×G/(A+B)≦6  (1) wherein A represents a content ratio (weight ratio) of the polyvinyl alcohol-based resin (A) based on a total amount of the polyvinyl alcohol-based resin (A) and the polyvinyl alcohol-based resin (B), B represents a content ratio (weight ratio) of the polyvinyl alcohol-based resin (B) based on the above total amount, and G represents an amount (% by mol) of the 1,2-glycol bond at a side chain.
    • 本发明提供一种拉伸性优异的聚乙烯醇系的光学用膜,并且用于制造在整个可见光波长范围,特别是波长460nm附近的极化性能优异的偏光膜。 本发明涉及包含聚乙烯醇类树脂的光学用聚乙烯醇系膜,其中,聚乙烯醇类树脂仅由含有1,2-二醇键的聚乙烯醇系树脂(A)构成, 侧链,侧链上的1,2-二醇键的量为0.01〜6摩尔%,或者是含有聚乙烯醇类树脂的光学用聚乙烯醇类膜,其中,聚乙烯醇 - 基于树脂的树脂包括侧链上含有1,2-二醇键的聚乙烯醇系树脂(A)和聚乙烯醇系树脂(A)以外的聚乙烯醇系树脂(B),满足下式 (1):0.01AxG /(A + B)其中A表示聚乙烯醇系树脂(A)的含量比(重量比),相对于聚乙烯醇类树脂(A)和聚乙烯醇类树脂 醇系树脂(B)中,B表示聚乙烯醇系树脂(B)的含有率(重量比) 基于上述总量,G表示侧链上的1,2-二醇键的量(摩尔%)。