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1. 发明专利

JP2006272491A Treatment method for carbon nano-wall, carbon nano-wall and carbon nano-wall device 有权
标题翻译：碳纳米管，碳纳米管和碳纳米管装置的处理方法
公开(公告)号：JP2006272491A
公开(公告)日：2006-10-12
申请号：JP2005093283
申请日：2005-03-28
申请人： Mineo Hiramatsu , Masaru Hori , Toyota Motor Corp , トヨタ自動車株式会社 , 勝堀 , 美根男平松
发明人： HORI MASARU , HIRAMATSU MINEO , KANO HIROYUKI , SUGIYAMA TORU
IPC分类号： B82B1/00 , C01B31/02 , H01J1/304 , H01L21/8242 , H01L27/108 , H01L29/06 , H01L29/786 , H01L29/80
摘要： PROBLEM TO BE SOLVED: To provide a treatment method for carbon nano-wall, which is a new carbon structure having a nanometer scale, a carbon nano-wall and a carbon nano-wall device. SOLUTION: The shape treatment is conducted for the carbon nano-wall (CNW). As the shape treatment, dry etching such as plasma etching is adopted. In a graphene sheet constituting the carbon nano-wall, at least the tip part thereof is more decreased in thickness than the root part. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种具有纳米尺度的新的碳结构的碳纳米管的处理方法，碳纳米壁和碳纳米壁装置。解决方案：对碳纳米壁（CNW）进行形状处理。作为形状处理，采用诸如等离子体蚀刻之类的干蚀刻。在构成碳纳米壁的石墨烯片中，至少其末端部分的厚度比根部更薄。版权所有（C）2007，JPO＆INPIT

2. 发明专利

JP2005097113A Method and device for producing carbon nanowall 审中-公开
标题翻译：用于生产碳纳米管的方法和装置
公开(公告)号：JP2005097113A
公开(公告)日：2005-04-14
申请号：JP2004343214
申请日：2004-11-26
申请人： Mineo Hiramatsu , Masaru Hori , 勝堀 , 美根男平松
发明人： HIRAMATSU MINEO , HORI MASARU
IPC分类号： C01B31/02
摘要： PROBLEM TO BE SOLVED: To provide a new method for producing carbon nanowalls, and to provide a device suitable for performing the method.
SOLUTION: A gaseous starting material 32 at least comprising carbon as a constitutive element is introduced into a reaction chamber 10. The reaction chamber 10 is provided with a diode parallel plate capacitive coupling plasma (CCP)-generating mechanism 20 including a first electrode 22 and a second electrode 24. In this way, electromagnetic waves such as RF (Radio Frequency) waves are applied to form a plasma atmosphere 34 in which the gaseous starting material 32 is converted into plasma. On the other hand, in a radical generation chamber 41 provided at the outside of the reaction chamber 10, a radical source gas 36 at least comprising hydrogen is cracked by RF waves, or the like, to generate a hydrogen radical 38. The hydrogen radical 38 is injected inside the plasma atmosphere 34, and carbon nanowalls are formed on the surface of a substrate 5 arranged on the second electrode 24.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种生产碳纳米壁的新方法，并提供适合于执行该方法的装置。解决方案：将至少包含碳作为组成元素的气态原料32引入反应室10.反应室10设置有二极管平行板电容耦合等离子体（CCP）生成机构20，其包括第一电极22和第二电极24.以这种方式，施加诸如RF（射频）波的电磁波以形成其中气态原料32被转换成等离子体的等离子体气氛34。另一方面，在设置在反应室10的外侧的自由基生成室41中，至少含有氢的自由基源气体36被RF波等破裂，生成氢基38.氢原子 38被注入到等离子体气氛34内，并且在布置在第二电极24上的基板5的表面上形成碳纳米壁。（C）2005年，JPO和NCIPI

3. 发明专利

JP2007230863A Carbon nanowall 有权
标题翻译：碳纳米线
公开(公告)号：JP2007230863A
公开(公告)日：2007-09-13
申请号：JP2007080332
申请日：2007-03-26
申请人： Mineo Hiramatsu , Masaru Hori , Nu Eco Engineering Kk , Nuエコ・エンジニアリング株式会社 , 勝堀 , 美根男平松
发明人： HIRAMATSU MINEO , HORI MASARU
IPC分类号： C01B31/02 , B82B1/00 , H01M4/96
CPC分类号： Y02E60/50
摘要： PROBLEM TO BE SOLVED: To provide a novel method for producing carbon nanowalls and an apparatus suitable for carrying out the method. SOLUTION: A source gas 32 containing at least carbon as a constituent element is introduced into a reaction chamber 10. The reaction chamber 10 includes a parallel plate-type capacitively coupled plasma (CCP) generator 20 including a first electrode 22 and a second electrode 24. The irradiation of an electromagnetic wave such as an RF wave plasmatizes the source material 32 to form a plasma atmosphere 34. In a radical-generating chamber 41 disposed outside the reaction chamber 10, hydrogen radicals 38 are generated by decomposing a radical source gas 36 containing hydrogen using an RF wave and the like. The hydrogen radicals 38 are introduced into the plasma atmosphere 34, whereby the carbon nanowalls are formed on a substrate 5 disposed on the second electrode 24. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种生产碳纳米管的新方法和适用于实施该方法的装置。解决方案：将至少含有碳作为组成元素的源气体32引入反应室10.反应室10包括平行板式电容耦合等离子体（CCP）发生器20，其包括第一电极22和第二电极24.诸如RF波之类的电磁波的照射等离子体化源材料32以形成等离子体气氛34.在设置在反应室10外部的自由基产生室41中，氢自由基38通过分解自由基使用RF波等含有氢的源气体36。将氢自由基38引入等离子体气氛34中，由此在设置在第二电极24上的基板5上形成碳纳米壁。（C）2007，JPO＆INPIT

4. 发明专利

JP2006120621A Fuel cell separator, electrode structure for fuel cell, manufacturing method thereof, and polymer electrolyte fuel cell comprising the same 有权
标题翻译：燃料电池分离器，用于燃料电池的电极结构，其制造方法和包含其的聚合物电解质燃料电池
公开(公告)号：JP2006120621A
公开(公告)日：2006-05-11
申请号：JP2005253451
申请日：2005-09-01
申请人： Mineo Hiramatsu , Masaru Hori , Toyota Motor Corp , トヨタ自動車株式会社 , 勝堀 , 美根男平松
发明人： HORI MASARU , HIRAMATSU MINEO , KANO HIROYUKI , KATAYAMA YUKIHISA , SUGIYAMA TORU , YOSHIDA SATOSHI
IPC分类号： H01M8/02 , H01M8/10
CPC分类号： H01M8/0245 , H01M8/0228 , H01M8/0234 , H01M8/0252 , H01M8/0258 , H01M8/0263 , H01M8/1007 , Y02P70/56 , Y10S977/948
摘要： PROBLEM TO BE SOLVED: To increase the degree of freedom in the shape of channels in a separator to enable an optimum gas channel to be designed, to enable a sufficient supply of gas below gas channel ribs, and to improve cell performance through the reduction in diffusion polarization; to improve a drainage property and to prevent flooding, thereby reducing diffusion polarization and improving cell performance; and to improve cell performance through the reduction of contact resistance.
SOLUTION: This fuel cell separator is characterized by comprising a separator substrate on which gas channel ribs are formed through vapor-phase growth of a carbon-based porous material with a nanosize structure. This application also provides an electrode structure for a fuel cell, methods of manufacturing the separator and the fuel cell, and a polymer electrolyte fuel cell comprising the electrode structure.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：为了增加分离器中通道形状的自由度以使得能够设计最佳气体通道，以便能够充分地供应气体通道肋下方的气体，并且通过扩散极化的减小; 提高排水性能，防止淹水，从而减少扩散极化，提高电池性能; 并通过降低接触电阻来提高电池性能。解决方案：该燃料电池隔板的特征在于包括隔板基板，气体通道肋通过具有纳米尺寸结构的碳基多孔材料的气相生长形成在其上。本申请还提供了一种用于燃料电池的电极结构，制造隔膜和燃料电池的方法，以及包括电极结构的聚合物电解质燃料电池。版权所有（C）2006，JPO＆NCIPI

5. 发明专利

JP2007095580A Field emitter using carbon nanotube 审中-公开
标题翻译：使用碳纳米管的场发射体
公开(公告)号：JP2007095580A
公开(公告)日：2007-04-12
申请号：JP2005285524
申请日：2005-09-29
申请人： Mineo Hiramatsu , Masaru Hori , Nu Eco Engineering Kk , Nuエコ・エンジニアリング株式会社 , 勝堀 , 美根男平松
发明人： HORI MASARU , HIRAMATSU MINEO , KANO HIROYUKI
IPC分类号： H01J1/304 , H01J9/02
摘要： PROBLEM TO BE SOLVED: To decrease threshold value of an electron emission field of a field emitter. SOLUTION: A silicon substrate (Sub) formed with carbon nanotube is mounted on a susceptor 110 having a micro heater in a reaction tank 100 and the reaction tank 100 is filled with supercritical CO 2 of 100°C. Next, trimethyl (methyl-cyclo-pentadienyl) platinum dissolved in hexane is added in a mixing vessel 200 which can be cut off and connected to the reaction tank 200 by a valve 210, and dissolved into the supercritical CO 2 . Then, after making the pressure in the mixing vessel 200 larger than that of inside the reaction tank 100, the valve 210 is opened and the supercritical CO 2 dissolved with a platinum compound in the mixing vessel 200 is introduced to the reaction tank 100 and the silicon substrate (Sub) is heated for a prescribed time up to 150°C, and platinum is deposited. Thereby, a carbon nanotube field emitter carrying platinum can be constructed. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：降低场致发射体的电子发射场的阈值。解决方案：将形成有碳纳米管的硅衬底（Sub）安装在具有微加热器的基座110上，并在反应罐100中填充超临界CO 2 SB C。接下来，将溶解在己烷中的三甲基（甲基 - 环戊二烯基）铂加入到混合容器200中，混合容器200可以通过阀210切断并连接到反应罐200，并溶解到超临界CO 2， SB>。然后，在使混合容器200中的压力大于反应槽100内部的压力之后，打开阀210，并且在混合容器200中引入用铂化合物溶解的超临界CO 2 SB 2 在反应槽100和硅基板（Sub））中加热至150℃的规定时间，并沉积铂。由此，可以构成携带铂的碳纳米管场发射体。版权所有（C）2007，JPO＆INPIT

6. 发明专利

JP2006278586A Device, carbon nano wall, and its manufacturing method 有权
标题翻译：装置，碳纳米墙及其制造方法
公开(公告)号：JP2006278586A
公开(公告)日：2006-10-12
申请号：JP2005093311
申请日：2005-03-28
申请人： Mineo Hiramatsu , Masaru Hori , Toyota Motor Corp , トヨタ自動車株式会社 , 勝堀 , 美根男平松
发明人： HORI MASARU , HIRAMATSU MINEO , KANO HIROYUKI , SUGIYAMA TORU
IPC分类号： H01L29/06 , B82B1/00 , B82B3/00 , C01B31/02 , H01L21/205 , H01L21/8242 , H01L27/108 , H01L29/66 , H01L29/78 , H01L29/786 , H01L29/80
摘要： PROBLEM TO BE SOLVED: To provide a new device using a new carbon structure having a nano scale, and to provide a carbon nano wall and a manufacturing method of the carbon nano wall. SOLUTION: In the device, a conductive region is formed with the carbon nano wall as a substrate. The carbon nano wall can comprise a hetero atom or does not comprise the hetero atom. In the carbon nano wall comprising the hetero atom, material gas comprising the hetero atom and a carbon source can be manufactured by a plasma CVD method. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种使用具有纳米级的新碳结构的新器件，并提供碳纳米壁和碳纳米壁的制造方法。解决方案：在器件中，以碳纳米壁为基底形成导电区域。碳纳米壁可以包含杂原子或不包含杂原子。在包含杂原子的碳纳米壁中，可以通过等离子体CVD法制造包含杂原子和碳源的原料气体。版权所有（C）2007，JPO＆INPIT

7. 发明专利

JP2006108649A Metallic mold for nano-imprint, forming method of nano-pattern, and resin molding 审中-公开
标题翻译：用于纳米印刷的金属模具，纳米图案的形成方法和树脂模塑
公开(公告)号：JP2006108649A
公开(公告)日：2006-04-20
申请号：JP2005253441
申请日：2005-09-01
申请人： Mineo Hiramatsu , Masaru Hori , Toyota Motor Corp , トヨタ自動車株式会社 , 勝堀 , 美根男平松
发明人： HORI MASARU , HIRAMATSU MINEO , KANO HIROYUKI , SUGIYAMA TORU , KATAYAMA YUKIHISA , YOSHIDA SATOSHI
IPC分类号： H01L21/027 , C01B31/02 , C23C16/26 , C23C16/452 , C23C16/509
CPC分类号： B81C99/0085 , B82Y10/00 , B82Y30/00 , B82Y40/00 , G03F7/0002 , Y10T428/24612
摘要： PROBLEM TO BE SOLVED: To raise mold-releasability of a metal mold and a resin layer in a nano-imprint, and to raise a durability of the metal mold. SOLUTION: This invention relates to the metal mold for the nano-imprint characterized by providing a carbon nano-wall layer on a front surface of a metallic mold for molding a resin, a method of forming a nano-pattern using this metallic mold, and a resin molding which can be obtained. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提高纳米压印中金属模和树脂层的脱模性，并提高金属模的耐久性。解决方案：本发明涉及用于纳米压印的金属模具，其特征在于在用于模制树脂的金属模具的前表面上提供碳纳米壁层，使用该金属形成纳米图案的方法模具和可以获得的树脂模制品。版权所有（C）2006，JPO＆NCIPI

8. 发明专利

JP2007095579A Field emitter using carbon nano wall 审中-公开
标题翻译：使用碳纳米管的场发射体
公开(公告)号：JP2007095579A
公开(公告)日：2007-04-12
申请号：JP2005285503
申请日：2005-09-29
申请人： Mineo Hiramatsu , Masaru Hori , Nu Eco Engineering Kk , Nuエコ・エンジニアリング株式会社 , 勝堀 , 美根男平松
发明人： HORI MASARU , HIRAMATSU MINEO , KANO HIROYUKI
IPC分类号： H01J1/304
摘要： PROBLEM TO BE SOLVED: To decrease threshold value of an electron emission field of a field emitter. SOLUTION: A silicon substrate (Sub) formed with carbon nano wall is mounted on a susceptor 110 having a micro heater in a reaction tank 100 and the reaction tank 100 is filled with supercritical CO 2 of 100°C. Next, trimethyl (methyl-cyclo-pentadienyl) platinum dissolved in hexane is added in a mixing vessel 200 which can be cut off and connected to the reaction tank 100 by a valve 210, and dissolved into the supercritical CO 2 . Then, after making the pressure in the mixing vessel 200 larger than that of inside the reaction tank 100, the valve 210 is opened and the supercritical CO 2 dissolved with a platinum compound in the mixing vessel 200 is introduced to the reaction tank 100 and the silicon substrate (Sub) is heated for a prescribed time up to 150°C, and platinum is deposited. Therefore, a carbon nano wall field emitter carrying platinum can be constructed. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：降低场致发射体的电子发射场的阈值。解决方案：将形成有碳纳米壁的硅衬底（Sub）安装在具有微加热器的基座110上，并在反应槽100中填充超临界CO 2 SB 100℃。接下来，将溶解在己烷中的三甲基（甲基 - 环戊二烯基）铂加入到混合容器200中，混合容器200可以通过阀210切断并连接到反应罐100，并溶解到超临界CO 2， SB>。然后，在使混合容器200中的压力大于反应槽100内部的压力之后，打开阀210，并且在混合容器200中引入用铂化合物溶解的超临界CO 2 SB 2 在反应槽100和硅基板（Sub））中加热至150℃的规定时间，并沉积铂。因此，可以构建携带铂的碳纳米壁场发射体。版权所有（C）2007，JPO＆INPIT

9. 发明专利

JP2006069816A Method for producing carbon nanowall, carbon nanowall and apparatus for producing the same 有权
标题翻译：生产碳纳米管的方法，用于生产碳纳米管的装置及其制造方法
公开(公告)号：JP2006069816A
公开(公告)日：2006-03-16
申请号：JP2004252698
申请日：2004-08-31
申请人： Mineo Hiramatsu , Masaru Hori , 勝堀 , 美根男平松
发明人： HIRAMATSU MINEO , HORI MASARU
IPC分类号： C01B31/02 , B82B3/00 , H05H1/00 , H05H1/46
摘要： PROBLEM TO BE SOLVED: To provide a new method for producing carbon nanowalls, and an apparatus suitable for practicing the method. SOLUTION: The method for producing the carbon nanowalls comprises following steps. A raw material gas 32 comprising at least carbon as a constituting element is introduced into a reaction chamber 10 provided with a parallel plate-type capacitively-coupled plasma (CCP) generation mechanism 20 comprising a first electrode 22 and a second electrode 24, from which an electromagnetic wave such as an RF wave is irradiated to form a plasma atmosphere 34 where the raw material gas 32 is converted into plasma. On the other hand, in a radical generating chamber 41 installed outside of the reaction chamber 10, a radical source gas 36 containing at least hydrogen is decomposed by an RF wave or the like to generate a hydrogen radical 38. The hydrogen radical 38 is injected into the plasma atmosphere 34 to form carbon nanowalls on the surface of a substrate 5 arranged on the second electrode 24. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种生产碳纳米壁的新方法，以及适用于该方法的设备。解决方案：制备碳纳米管的方法包括以下步骤。将包含至少碳作为构成元素的原料气体32引入到具有平行板型电容耦合等离子体（CCP）产生机构20的反应室10中，该平行板型电容耦合等离子体（CCP）产生机构20包括第一电极22和第二电极24，照射诸如RF波之类的电磁波，以形成原料气体32转换为等离子体的等离子体气氛34。另一方面，在安装在反应室10外部的自由基产生室41中，至少含有氢的自由基源气体36被RF波等分解，生成氢基38.注入氢根38 进入等离子体气氛34以在布置在第二电极24上的基板5的表面上形成碳纳米壁。（C）2006年，JPO和NCIPI

10. 发明申请

US20080274392A1 Method and Apparatus for Producing Catalyst Layer for Fuel Cell 审中-公开
标题翻译：燃料电池催化剂层生产方法与装置
公开(公告)号：US20080274392A1
公开(公告)日：2008-11-06
申请号：US11884233
申请日：2006-02-14
申请人： Masaru Hori , Mineo Hiramatsu , Hiroyuki Kano , Satoshi Yoshida , Yukihisa Katayama , Toru Sugiyama
发明人： Masaru Hori , Mineo Hiramatsu , Hiroyuki Kano , Satoshi Yoshida , Yukihisa Katayama , Toru Sugiyama
IPC分类号： H01M4/88 , H01M4/00 , C23C16/00
CPC分类号： H01M4/8605 , B82Y30/00 , C23C14/18 , C23C14/28 , C23C14/325 , C23C14/34 , C23C16/26 , C23C16/505 , H01M4/8817 , H01M4/8867 , H01M4/9083 , H01M8/0234 , Y02P70/56
摘要： A method for manufacturing a catalyst layer for a fuel cell support for a catalyst layer comprises the steps of vapor-growing a carbonaceous porous material having a nano-size structure, such as carbon nanowalls (CNWs), and supporting and dispersing a catalyst component and/or an electrolyte component on the support for a catalyst layer. The method simplifies the process for manufacturing an electrode layer for fuel cells and improves the dispersibility of the catalyst component and the electrolyte, whereby the generation efficiency of a fuel cell can be improved.
摘要翻译：用于催化剂层的燃料电池用载体催化剂层的制造方法包括：对碳纳米管（CNW）等纳米尺寸结构的碳质多孔体进行气相生长，并且对催化剂成分进行负载和分散， /或用于催化剂层的载体上的电解质组分。该方法简化了燃料电池用电极层的制造工序，提高了催化剂成分和电解质的分散性，能够提高燃料电池的发电效率。

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