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1. 发明授权

US5132345A Ion-selective electrodes 失效
标题翻译：离子选择电极
公开(公告)号：US5132345A
公开(公告)日：1992-07-21
申请号：US624623
申请日：1990-12-10
申请人： Stephen J. Harris , Michael A. McKervey , Gyula Svehla , Dermot Diamond
发明人： Stephen J. Harris , Michael A. McKervey , Gyula Svehla , Dermot Diamond
IPC分类号： G01N27/333
CPC分类号： G01N27/333
摘要： An ion-selective polymeric membrane for an electrochemical sensor for use in analytical chemistry, comprisinga) a supporting matrix e.g. of PVC, andb) an ionophore selected from calixarene or oxacalixarene derivatives of the formula IV ##STR1## wherein n+m=3-8;m=0-8;n=0-8;a, which may be the same or different on each aryl group, is 0 or 1;R.sup.2 is alkyl, aryl, alkaryl, alkoxy, alkoxyalkoxy, aryloxy, alkaryloxy, alicyclic, alkylthio, arylthio, alkarylthio, or a substituted derivative thereof;R.sup.3 is --H, alkyl or alkenyl;X is --OH or a group containing an acrylate or methacrylate functional group;provided that when X is --OH, n is at least 1/2(n+m);and provided that when m=0, n=4, a=0 and R.sup.3 is alkyl or allyl, R.sup.2 is not alkoxy having 4 or more carbon atoms in the alkyl group;and provided that when m=0, n=4, a=0 and R.sup.3 is t-butyl, R.sup.2 is not methoxy or ethoxy;or of the formula V ##STR2## wherein R.sup.4 is alkyl; or polymers of those compounds of the formula IV in which X is a group containing an acrylate or methacrylate group.New compounds in which R.sup.2 is --SCH.sub.2 CH.sub.3 are described.Selectivity coefficients and slope measurements are given for the ionophores in PVC electrodes which are selective for sodium, potassium and caesium.
摘要翻译：一种用于分析化学中的用于电化学传感器的离子选择性聚合物膜，包括：a）的PVC，和b）选自式IV的杯芳烃或氧杂七环芳烃衍生物的离子载体，其中n + m = 3-8; m = 0-8; n = 0-8; a在每个芳基上可以相同或不同，为0或1; R2是烷基，芳基，烷芳基，烷氧基，烷氧基烷氧基，芳氧基，烷氧基，脂环族，烷硫基，芳硫基，烷芳硫基或其取代衍生物。 R3是-H，烷基或烯基; X是-OH或含有丙烯酸酯或甲基丙烯酸酯官能团的基团; 条件是当X为-OH时，n为至少1/2（n + m）; 并且条件是当m = 0时，n = 4，a = 0和R3是烷基或烯丙基，R2不是烷基中具有4个或更多个碳原子的烷氧基; 并且条件是当m = 0时，n = 4，a = 0和R3是叔丁基，R 2不是甲氧基或乙氧基; 或其中R 4是烷基的式V V 或其中X为含丙烯酸酯或甲基丙烯酸酯基团的式Ⅳ化合物的聚合物。描述了其中R2是-SCH2CH3的新化合物。对于对钠，钾和铯有选择性的PVC电极中的离子载体，给出了选择性系数和斜率测量。

2. 发明授权

US5599913A Chromoionophores, optical sensors containing them and a method for determining the presence of alkali metal cations or of a base 失效
标题翻译：含铬荧光体，含有它们的光学传感器和用于测定碱金属阳离子或碱的存在的方法
公开(公告)号：US5599913A
公开(公告)日：1997-02-04
申请号：US381912
申请日：1995-03-28
申请人： Stephen J. Harris , Dermot Diamond , Michael A. McKervey
发明人： Stephen J. Harris , Dermot Diamond , Michael A. McKervey
IPC分类号： C07C205/42 , C07C205/43 , C07C205/45 , C07C245/08 , G01N31/22
CPC分类号： C07C205/43 , C07C205/42 , C07C205/45 , C07C245/08 , C07C2103/92 , Y10S435/808 , Y10T436/11 , Y10T436/173845 , Y10T436/174614
摘要： New chromoionophores of the formula IV ##STR1## wherein a=0-3, b=0 or 1, c =0 or 1, x=0 or 1, y=0 or 1, z=0 or 1,R', which may be the same or different in each aryl group, is H, halogen, hydrocarbyl, aryl, hydrocarbylaryl or a substituted derivative thereof;R, which may be the same or different, is hydrocarbyl, aryl, hydrocarbylaryl, or a substituted derivative thereofare useful in optical sensors or colourmetric reagents for clinical use particularly for lithium, When complexed with lithium, the chromoionophores of the invention and other calixarene derivatives can be used for detecting amines, particularly trimethylamine, as an indicator of fish spoilage.
摘要翻译： PCT No.PCT / IE93 / 00046 Sec。 371日期：1995年3月28日 102（e）1995年3月28日PCT PCT 1993年8月6日PCT公布。公开号WO94 / 04483 日期1994年3月3日公式IV的新的铬离子荧光素其中a = 0-3，b = 0或1，c = 0或1，x = 0或1，y = 0或1，z = 0或1，R'在每个芳基中可以相同或不同，为H，卤素，烃基，芳基，烃基芳基或其取代的衍生物; R可以相同或不同，是烃基，芳基，烃基芳基或其取代的衍生物，可用于特别用于锂的临床用光学传感器或色度试剂中。当与锂络合时，本发明的染色体和其他杯芳烃衍生物可用于检测胺，特别是三甲胺，作为鱼类腐败的指标。

3. 发明授权

US5216185A Polymerizable calixarene and oxacalixarene derivatives, polymers thereof and use of such derivatives and polymers for sequestration of metals 失效
标题翻译：可聚合的氯仿和氧化二烯衍生物，其聚合物和这些衍生物和聚合物用于金属排序的用途
公开(公告)号：US5216185A
公开(公告)日：1993-06-01
申请号：US625575
申请日：1990-12-10
申请人： Stephen J. Harris , John Guthrie , Maureen MacManus , Michael A. McKervey
发明人： Stephen J. Harris , John Guthrie , Maureen MacManus , Michael A. McKervey
IPC分类号： C07C69/712 , C07C217/18 , C07C323/12 , C07D323/00 , C08F20/26 , C08F20/30 , C08F220/30 , C09K3/00
CPC分类号： C07C69/712 , C07D323/00 , C08F20/30
摘要： Polymerizable calixarene and oxacalixarene derivates wherein at least one aryl group of the macrocyclic ring has a phenolic side chain of the formula VII: ##STR1## wherein Z is a group containing an acrylate or methacrylate functional group. Linear polymers may be formed from these compounds by free radical polymerization at the (meth)acrylate group. Such compounds and their polymers are capable of sequestering metals.

4. 发明授权

US5210216A Calixarene and oxacalixarene derivatives and use thereof of sequestration metals 失效
标题翻译：杯芳烃和恶唑烷衍生物及其螯合金属的用途
公开(公告)号：US5210216A
公开(公告)日：1993-05-11
申请号：US625573
申请日：1990-12-10
申请人： Stephen J. Harris , John Guthrie , Maureen MacManus , Ciaran McArdle , Michael A. McKervey
发明人： Stephen J. Harris , John Guthrie , Maureen MacManus , Ciaran McArdle , Michael A. McKervey
IPC分类号： C02F1/26 , C02F1/68 , C07C59/70 , C07C205/25 , C07C205/37 , C07C217/24 , C07C235/20 , C07C245/08 , C07C251/38 , C07C251/76 , C07C323/12 , C07C327/44 , C07D213/30 , C07D235/12 , C07D295/185 , C07D313/00 , C07D321/00 , C07D323/00 , C07F7/18 , C08F8/00 , C08G18/32 , C08G18/54 , C08G75/02 , C08G77/38 , C08G85/00 , C08K5/15 , C09J4/00
CPC分类号： C07D213/30 , C02F1/26 , C02F1/683 , C07C205/25 , C07C205/37 , C07C217/24 , C07C235/20 , C07C245/08 , C07C251/38 , C07C251/76 , C07C323/12 , C07C327/44 , C07C59/70 , C07D235/12 , C07D295/185 , C07D313/00 , C07D321/00 , C07D323/00 , C07F7/1836 , C08F8/00 , C08G18/3215 , C08G18/542 , C08G75/02 , C08G77/38 , C08G85/00 , C08K5/15 , C09J4/00 , C07C2103/92
摘要： Calixarene and oxacalixarene derivatives of the formula IV: ##STR1## wherein m'+m"=0-8n=0-8m'.gtoreq.1/2(m'+m")3.ltoreq.m'+m"+n.ltoreq.8if n=0, m'+m".gtoreq.4R.sup.3 is H, halogen, or hydrocarbyl, aryl, hydrocarbylaryl or a substituted derivative thereof and R.sup.3 may be the same or different on each aryl group;R.sup.15 is H or hydrocarbyl, aryl, hydrocarbylaryl or a substituted derivative thereof;X is selected from ##STR2## wherein R.sup.7 and R.sup.8 which may be the same or different are H or hydrocarbyl (including a cycloaliphatic ring formed by R.sup.7 and R.sup.8 together), aryl, hydrocarbylaryl or a substituted derivative thereof; R.sup.9 is --OH, --NH.sub.2, --NHC(O)NH.sub.2 or --NHAr, wherein Ar is aryl or a substituted derivative thereof,n' is 0 or 1.Use of the compounds for sequestration of metals is also described.
摘要翻译：式IV的杯芳烃和恶唑烷衍生物：其中m'+ m“= 0-8 n = 0-8 m'/ = 1/2（m'+ m”）3 = 如果n = 0，m + + m + n，则n'= n，R 3是H，卤素或烃基，芳基，烃基芳基或其取代的衍生物，并且R 3可以相同或每个芳基不同; R 15为H或烃基，芳基，烃基芳基或其取代衍生物; （A）（CH2）n'SR7（B）其中可以相同或不同的R 7和R 8是H或烃基（包括环脂族基）由R 7和R 8一起形成的环），芳基，烃基芳基或其取代的衍生物; R9是-OH，-NH2，-NHC（O）NH2或-NHAr，其中Ar是芳基或其取代衍生物，n'是0或1.还描述了化合物螯合金属的用途。

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