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    • 1. 发明申请
    • Method for producing water absorbent resin
    • 吸水树脂的制造方法
    • US20110319518A1
    • 2011-12-29
    • US13254573
    • 2010-03-04
    • Kenji KadonagaKenji TadaMasazumi SasabeSeiji Kato
    • Kenji KadonagaKenji TadaMasazumi SasabeSeiji Kato
    • C08F301/00C08F2/46
    • C08J3/245B01F7/00466B01F7/169C08F20/06C08F220/06C08J2333/02
    • The present invention is a method for producing a water absorbent resin which method is a method for producing surface cross-linked water absorbent resin particles, the method including the successive steps of: (a) adding a surface cross-linking agent and water to a particulate water absorbent resin in a mixer; and (b) reacting the resulting water absorbent resin mixture taken out from the mixer with the surface cross-linking agent in a reactor by heating or active energy ray irradiation, water vapor being used as part or all of the water added in the mixer. This makes it possible to provide a method for producing a water absorbent resin in which method a surface cross-linked water absorbent resin that has excellent properties can be obtained efficiently at low cost with high productivity.
    • 本发明是一种吸水性树脂的制造方法,其为表面交联型吸水性树脂粒子的制造方法,该方法包括以下连续步骤:(a)将表面交联剂和水加入到 混合器中的颗粒状吸水性树脂; 和(b)通过加热或活性能量射线照射将从混合器中取出的所得吸水性树脂混合物与表面交联剂反应在反应器中,使用水蒸气作为混合器中加入的部分或全部水。 这使得可以提供一种制造吸水性树脂的方法,其中可以以低成本有效地以高生产率获得具有优异性能的表面交联吸水性树脂的方法。
    • 3. 发明申请
    • Binding method of water absorbent resin
    • 吸水树脂的结合方法
    • US20110237739A1
    • 2011-09-29
    • US12673425
    • 2008-09-04
    • Kenji TadaKenji KadonagaMasazumi Sasabe
    • Kenji TadaKenji KadonagaMasazumi Sasabe
    • C08L33/08C08F220/26
    • C08J3/245A61L15/60B01D53/02B01D2253/202B01D2257/80C08J3/12C08J2333/02
    • Aqueous liquid and moisture vapor are added to water absorbent resin powder so that particles of the water absorbent resin powder are bound. In forming bound particles by supplying aqueous liquid and moisture vapor to the water absorbent resin powder, the foregoing arrangement makes it possible to supply moisture to whole the powder so that a less amount of particles remains unbound (ungranulated) and increase of a concentration of the water absorbent resin bound particles allows for further improvement of a drying efficiency and makes it possible to obtain particulate water absorbent resin having excellent properties even when the bound particles are highly concentrated. The present invention provides (i) a method for binding water absorbent resin and (ii) a method for producing particulate water absorbent resin which method includes the step of binding particles of water absorbent resin powder. The foregoing effect can be obtained by these methods.
    • 向吸水性树脂粉末中加入水性和水蒸汽,使吸水性树脂粉末的粒子结合。 在通过向吸水性树脂粉末供给水性液体和水蒸汽来形成结合粒子的情况下,通过上述结构,能够使整体粉末供给水分,使得少量的粒子保持未结合(未成粒),并且增加浓度 吸水性树脂结合颗粒允许进一步提高干燥效率,并且使得即使当结合颗粒高度浓缩时也可获得具有优异性能的颗粒状吸水性树脂。 本发明提供(i)粘合吸水性树脂的方法和(ii)颗粒状吸水性树脂的制造方法,其特征在于,包括粘合吸水性树脂粉末的粒子的工序。 通过这些方法可以获得上述效果。
    • 5. 发明授权
    • Method for manufacture of porous product from molded high internal phase emulsion
    • 从成型的高内相乳液制造多孔产品的方法
    • US07001548B2
    • 2006-02-21
    • US10466345
    • 2002-05-24
    • Katsuhiko SakamotoMasazumi Sasabe
    • Katsuhiko SakamotoMasazumi Sasabe
    • B29C44/02
    • B29C39/06B29C33/0022B29C44/388B29C67/202B29K2105/0064B29K2105/045
    • A method directed to manufacturing porous products by supplying a water-in-oil type high internal phase emulsion into mold elements, shaping and polymerizing the emulsion. It is characterized by a moving shaping unit provided with a lower mold element on one side having a smooth mold face furnished with a depressed part and an upper mold element on the other side having a smooth mold face furnished with a corresponding depressed part forming a cavity of a stereoscopic shape together with the depressed part of the lower mold element. Prior to the union of the two mold elements continuously supplying the emulsion into the two mold elements, transferring the shaping unit into a polymerizing device subsequent to the union of the mold elements, and shaping and polymerizing the emulsion therein.
    • 一种通过将油包水型高内相乳液提供到模具元件中来制造多孔产品的方法,使乳液成形和聚合。 其特征在于,移动成型单元在一侧具有下模具元件,该下模具元件具有设置有凹陷部分的光滑模具表面,而在另一侧具有上模具元件,该模具元件具有光滑的模具表面,该模具表面设置有形成腔 与下模具元件的凹陷部分一起形成立体形状。 在将乳液连续地供应到两个模具元件中的两个模具元件的联合之前,在模具元件的结合之后将成形单元转移到聚合装置中,以及在其中成形和聚合乳液。
    • 7. 发明授权
    • Method for production of porous cross-linked polymer
    • 生产多孔交联聚合物的方法
    • US06750263B2
    • 2004-06-15
    • US10148308
    • 2002-05-29
    • Masazumi SasabeKatsuhiko SakamotoKozo Nogi
    • Masazumi SasabeKatsuhiko SakamotoKozo Nogi
    • C08J928
    • B29C44/308B29C44/30C08J9/283
    • This invention provides a method of producing a porous cross-linked polymer by horizontal continuous polymerization of a water-in-oil higher internal phase emulsion (HIPE), which includes using a weir at the opposite end parts in the width direction of an emulsion supporting member for use in the polymerization. This invention also provides a method of producing a porous cross-linked polymer by horizontal continuous polymerization of an HIPE, which includes using a supporting member of the lower side of the emulsion and a sheet material on the upper side of the emulsion, and performing the polymerization by exerting a tensile force in the width direction and/or the travel direction of the sheet material. This invention further provides a method of producing a porous cross-linked polymer by horizontal continuous polymerization of an HIPE, which includes regulating the thickness of the HIPE by passing the HIPE between a movable supporting member and an object disposed so as to retain a prescribed gap from the movable supporting member.
    • 本发明提供了一种通过水包油高级内相乳液(HIPE)的水平连续聚合制备多孔交联聚合物的方法,该方法包括在乳液支撑的宽度方向的相对端部使用堰 本发明还提供了一种通过HIPE的水平连续聚合制备多孔交联聚合物的方法,其包括使用乳液下侧的支撑构件和在上侧的片材 的乳液,并通过在片材的宽度方向和/或行进方向上施加张力进行聚合。本发明还提供了通过HIPE的水平连续聚合制备多孔交联聚合物的方法, 其包括通过将HIPE通过可移动支撑构件和被设置为保持预先设置的物体之间的HIPE的厚度来调节HIPE的厚度 与可移动支撑构件的划痕间隙。