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    • 1. 发明申请
    • Process for making an optical film
    • 制造光学膜的方法
    • US20070228586A1
    • 2007-10-04
    • US11394479
    • 2006-03-31
    • William MerrillAndrew OuderkirkMatthew JohnsonTimothy HebrinkMartin DenkerMark O'Neill
    • William MerrillAndrew OuderkirkMatthew JohnsonTimothy HebrinkMartin DenkerMark O'Neill
    • B29D11/00
    • G02B5/3008B29C55/023B29C55/146B29C55/165B29K2067/00B29K2995/0032G02B5/3083
    • Exemplary methods include includes providing a film comprising at least one polymeric material; widening the film under a first set of processing conditions in a first draw step along the crossweb direction such that in-plane birefringence, if any, created in the film is low; and drawing the film in a second draw step along a downweb direction under a second set of processing conditions, wherein the second set of processing conditions creates in-plane birefringence in at least one polymeric material. Exemplary roll of film includes an oriented optical film characterized by an effective orientation axis. The oriented optical film comprises only one birefringent polymeric material, at least one birefringent material and at least one isotropic material, or a first birefringent material and a second birefringent material, the birefringent materials characterized by effective orientation axes along the MD. The optical film has a width of greater than 0.3 m and a length a length greater than 10 m.
    • 示例性的方法包括提供包含至少一种聚合物材料的膜; 在沿着横向横向方向的第一拉伸步骤中的第一组处理条件下使膜变宽,使得在膜中产生的面内双折射(如果有的话)低; 以及在第二组处理条件下沿下游方向在第二牵引步骤中拉伸所述膜,其中所述第二组加工条件在至少一种聚合材料中产生平面内双折射。 示例性的薄膜包括以有效取向轴为特征的定向光学薄膜。 取向光学膜仅包含一种双折射聚合物材料,至少一种双折射材料和至少一种各向同性材料,或第一双折射材料和第二双折射材料,双折射材料的特征在于沿着MD的有效取向轴。 光学膜的宽度大于0.3μm,长度大于10μm。
    • 6. 发明授权
    • Passive collimating tubular skylight
    • 被动准直管状天窗
    • US06363667B2
    • 2002-04-02
    • US09740797
    • 2000-12-21
    • Mark O'Neill
    • Mark O'Neill
    • E04B718
    • E04B9/32E04D13/03E04D2013/0345
    • A passive collimating tubular skylight consisting of a radiant energy-collecting aperture, a radiant energy-delivering aperture, and a radiant energy passageway between these two apertures, the passageway having a specularly reflective interior surface and a configuration to improve the collimation of the radiant energy passing therethrough. The skylight can be configured with the radiant energy-collecting aperture located above the roof of a building, oriented to collect sunlight; and equipped with a sealed weatherproof glazing, with the radiant energy-delivering aperture, or luminaire, located at ceiling level within the building, and equipped with a diffusing glazing; and with the reflective tubular light passageway constructed with a larger cross sectional area near the radiant energy-delivering aperture than near the radiant energy-collecting aperture. In complete accord with the second law of thermodynamics, and as proven by experimental results, the new passive collimating tubular skylight provides significant advantages over the prior art, including better solar energy collection, higher throughput optical efficiency, improved radiant energy collimation, enhanced interior illumination levels, and more precise positional control of the interior illumination.
    • 由辐射能量收集孔,辐射能量输送孔和这两个孔之间的辐射能通道组成的被动准直管状天窗,该通道具有镜面反射内表面和用于改善辐射能准直的构造 通过 天窗可以配置有位于建筑物屋顶上方的辐射能量收集孔,定向收集阳光; 并配有密封的防风雨玻璃,配有辐射能量输送孔或照明设备,位于建筑物内的天花板上,并配有扩散玻璃; 并且反射管状光通道构造成具有靠近辐射能量收集孔附近的辐射能量输送孔附近的较大横截面积。 完全符合热力学第二定律,并且通过实验结果证明,新的被动准直管状天窗比现有技术提供了显着的优点,包括更好的太阳能收集,更高的通量光学效率,改进的辐射能准直,增强的室内照明 水平和更精确的内部照明的位置控制。
    • 7. 发明授权
    • Reflective article with concealed retroreflective pattern
    • 具有隐蔽反光图案的反光制品
    • US6024455A
    • 2000-02-15
    • US6292
    • 1998-01-13
    • Mark O'NeillMichael F. WeberOlester Benson, Jr.John A. WheatleyJames M. JonzaGary B. Hanson
    • Mark O'NeillMichael F. WeberOlester Benson, Jr.John A. WheatleyJames M. JonzaGary B. Hanson
    • G02B5/124G02B5/128G02B5/26
    • G02B5/124
    • A reflective article has a multilayer film covering a patterned retroreflective layer. In one embodiment the patterned retroreflective layer includes a separate indicia layer covering a retroreflective substrate. The indicia are substantially hidden under normal viewing conditions but easily detectable under retroreflective lighting conditions. Various types of retroreflective layers are disclosed. The article can also include microstructured relief patterns which produce holographic images under ambient lighting but which disappear under retroreflective conditions. The multilayer film includes alternating layers of at least a first and second polymer, and has a relatively high reflectivity for normally incident light within a first spectral range which is approximately coextensive with the visible spectrum, and a relatively low reflectance for normally incident light within a second spectral range. The second spectral range can include a transmission window of 15% or less fractional bandwidth located at least partially in the visible spectrum. Film constructions are disclosed which achieve sharper spectral transitions than previously attainable. Film constructions are also disclosed which preserve such sharp transitions even at high entrance (tilt) angles.
    • 反射制品具有覆盖图案化的反光层的多层膜。 在一个实施例中,图案化的反光层包括覆盖回射衬底的单独标记层。 标记在正常观察条件下基本隐藏,但在回射照明条件下容易检测。 公开了各种类型的回射层。 该文章还可以包括在环境照明下产生全息图像但在回射条件下消失的微结构化浮雕图案。 多层膜包括至少第一和第二聚合物的交替层,并且对于在与可见光谱近似共同的第一光谱范围内的正常入射光具有相对较高的反射率,以及在可见光谱内的正常入射光的相对较低的反射率 第二光谱范围。 第二光谱范围可以包括至少部分地位于可见光谱中的15%或更小的分数带宽的透射窗口。 公开了薄膜结构,其实现比先前可获得的更清晰的光谱转变。 还公开了即使在高入口(倾斜)角度下保持这种尖锐转变的膜结构。
    • 8. 发明授权
    • Refrigerator interior liner
    • 冰箱内衬
    • US08785545B2
    • 2014-07-22
    • US13203886
    • 2010-03-09
    • Michel DucJan NeelenMark O'Neill
    • Michel DucJan NeelenMark O'Neill
    • C08J3/22C08L9/00
    • C08L25/06C08F2/38C08F12/08C08F279/02C08L51/04F25D23/066F25D23/08
    • A refrigerator interior liner can be made of a composition including a monovinylaromatic polymer matrix having an average molecular weight in weight Mw above 150,000 g/mol; rubber particles; and low- Mw plasticizers. The rubber particles can have an RPS volume of about 8.5 μm, a monomodal distribution, a swell index above 13.8, and an RPVF of at least 39%. The composition can be prepared by forming a polymerizable mixture including a monovinylaromatic monomer, and dissolving a viscous rubber in the polymerizable mixture. A free radical initiator and a chain transfer agent can be contacted with the polymerizable mixture at conditions whereby phase inversion subsequently occurs. The chain transfer agent can produce an increase of the rubber to PS phase viscosity ratio within the inversion reactor. Polymerization can be continued until a monovinylaromatic polymer matrix having rubber particles dispersed therein is obtained.
    • 冰箱内衬可以由包含平均分子量Mw大于150,000g / mol的单乙烯基芳族聚合物基质的组合物制成; 橡胶颗粒; 和低Mw增塑剂。 橡胶颗粒可以具有约8.5μm的RPS体积,单峰分布,高于13.8的溶胀指数和至少39%的RPVF。 可以通过形成包含单乙烯基芳族单体的可聚合混合物,并将粘性橡胶溶解在可聚合混合物中来制备组合物。 在随后发生相转化的条件下,可以使自由基引发剂和链转移剂与可聚合混合物接触。 链转移剂可以在反应器内产生橡胶与PS相粘度比的增加。 可以继续聚合,直到获得具有分散有橡胶颗粒的单乙烯基芳族聚合物基质。