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1. 发明申请

WO2005056727A1 A PROCESS FOR THE ACID EXTRACTION OF HYDROCARBON FEED 审中-公开
标题翻译：酸性提取油料进料的方法
公开(公告)号：WO2005056727A1
公开(公告)日：2005-06-23
申请号：PCT/US2004/040087
申请日：2004-12-01
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , MINHAS, Bhupender, S. , PEIFFER, Dennis, G. , BECK, Jeffrey, S. , STERN, David, L. , MELLI, Tomas, R.
发明人： MINHAS, Bhupender, S. , PEIFFER, Dennis, G. , BECK, Jeffrey, S. , STERN, David, L. , MELLI, Tomas, R.
IPC分类号： C10G17/10
CPC分类号： C10G21/28 , C10G17/10 , C10G2300/202 , C10G2300/4081
摘要： This invention relates to a process for recycling acid used to remove nitrogen contaminants from hydrocarbons using polymeric membranes to separate spent acid from the acid extraction of hydrocarbons into acid for recycle and acid for regeneration.
摘要翻译：本发明涉及一种使用聚合物膜从碳氢化合物中除去氮污染物的方法，以将废酸从碳酸的酸萃取中分离出来，再循环酸和用于再生。

2. 发明申请

WO2008124190A1 BACK FLUSHABLE STRAINER DEVICE 审中-公开
标题翻译：背面可冲洗设备
公开(公告)号：WO2008124190A1
公开(公告)日：2008-10-16
申请号：PCT/US2008/004662
申请日：2008-04-10
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , WANNI, Amar, S. , RUDY, Thomas, M. , LAFLEUR, Claude, A. , HAY, Clifford, A. , MELLI, Tomas, R.
发明人： WANNI, Amar, S. , RUDY, Thomas, M. , LAFLEUR, Claude, A. , HAY, Clifford, A. , MELLI, Tomas, R.
IPC分类号： B01D50/00 , B01D29/66 , B01D36/04
CPC分类号： B01D50/00 , B01D29/01 , B01D29/58 , B01D29/66 , B01D35/02
摘要： A strainer device (16) for a fluid flow circuit (10) removes debris and solid particles from the fluid flow to prevent plugging and reduce fouling of the system. The assembly includes a chamber (22) that can be hydrocyclonic, a collection area (32), a screen assembly (50) and a distributor (36) that allows selective connection to a flushing fluid. The fluid flows through the chamber past the strainer device, with large particles collecting in the collection area under the influence of gravity and smaller solid particles being collected in the screen assembly. Particles can be flushed from the system- by selectively activating the distributor to back flush the screen assembly and sweep the collection area free of solid particles without disassembling the system.
摘要翻译：用于流体流动回路（10）的过滤器装置（16）从流体流中去除碎屑和固体颗粒以防止堵塞并减少系统的结垢。组件包括可以是水力旋流的腔室（22），收集区域（32），筛网组件（50）和允许选择性地连接到冲洗流体的分配器（36）。流体经过过滤器装置流过腔室，大量颗粒在重力作用下收集在收集区域，较小的固体颗粒被收集在筛网组件中。可以从系统中冲洗颗粒 - 通过选择性地启动分配器以使刷洗组件反冲洗，并且在不拆卸系统的情况下扫掠没有固体颗粒的收集区域。

3. 发明申请

WO2008016635A3 REJUVENATION PROCESS FOR OLEFIN POLYMERIZATION AND ALKYLATION CATALYST 审中-公开
标题翻译：烯烃聚合和烷基化催化剂的再生工艺
公开(公告)号：WO2008016635A3
公开(公告)日：2008-04-10
申请号：PCT/US2007017172
申请日：2007-08-01
申请人： EXXONMOBIL RES & ENG CO , UMANSKY BENJAMIN S , DANDEKAR AJIT B , MELLI TOMAS R , MILLER AMANDA K , MCGIHON RONALD D
发明人： UMANSKY BENJAMIN S , DANDEKAR AJIT B , MELLI TOMAS R , MILLER AMANDA K , MCGIHON RONALD D
IPC分类号： B01J29/90 , C07C2/12 , C07C2/66
CPC分类号： B01J29/90 , B01J29/7038 , C10G29/205 , C10G50/00
摘要： A method of rejuvenating a deactivated molecular sieve catalyst, deactivated by use in an olefin oligomerization or aromatics alkylation process, which method comprises contacting the deactivated catalyst with a stream of rejuvenation gas comprising a hydrocarbon product fraction from the process at an elevated temperature and pressure for a time sufficient to effect an increase in catalytic activity of the deactivated catalyst.
摘要翻译：一种使用在烯烃低聚或芳烃烷基化方法中失活的失活分子筛催化剂的再生方法，该方法包括使失活催化剂与包含来自该方法的烃产物馏分的再生气体流在升高的温度和压力下足以实现失活催化剂的催化活性增加的时间。

4. 发明申请

WO2007092317A2 GASOLINE PRODUCTION BY OLEFIN POLYMERIZATION 审中-公开
标题翻译：汽油生产由烯烃聚合
公开(公告)号：WO2007092317A2
公开(公告)日：2007-08-16
申请号：PCT/US2007/002909
申请日：2007-02-01
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , UMANSKY, Benjamin, S. , WERNER, Arthur, P. , MILLER, Amanda, K. , MELLI, Tomas, R. , DEAN, Christopher, M. , ISMAIL, Niveen, S. , BRIGNAC, Garland, B.
发明人： UMANSKY, Benjamin, S. , WERNER, Arthur, P. , MILLER, Amanda, K. , MELLI, Tomas, R. , DEAN, Christopher, M. , ISMAIL, Niveen, S. , BRIGNAC, Garland, B.
IPC分类号： C10G50/00 , C10G57/02 , B01J23/00
CPC分类号： B01J29/7038 , B01J29/70 , C10G50/00 , C10G57/02 , C10G2400/02
摘要： A process unit for the zeolite-catalyzed conversion of light refinery olefins from an FCC unit such as ethylene, propylene, and butylene to gasoline boiling range motor fuels comprises at least two sequential, serially connected reactors connected in parallel to a fractionation section with at one or two fractionators for separating the reactor effluents into product fraction with an optional recycle stream or streams. The configurations according to this scheme allow the adjustment of reactor temperature and/or pressure and/or space velocity to be based on the reactivities of the olefin compounds present in the LPG streams so that the gasoline produced in each reactor will be separated immediately, to reduce over-polymerization of the gasoline in the low severity reactor and to ensure that gasoline formed in the low severity reactor will not be sent to the higher severity reactor e.g. with a higher reactor temperature, where excessive polymerization to undesirable higher molecular with products may take place.
摘要翻译：沸石催化的轻质炼油烯烃从FCC装置如乙烯，丙烯和丁烯转化成汽油沸程的发动机燃料的处理单元包括至少两个连续的串联连接的反应器，其与一个分离部分并联连接或两个分离器，用于将反应器流出物与任选的再循环流或物流分离成产物级分。根据该方案的配置允许基于LPG流中存在的烯烃化合物的反应性来调节反应器温度和/或压力和/或空间速度，使得在每个反应器中产生的汽油将立即分离，减少低严重性反应器中汽油的过度聚合，并确保低浓度反应器中形成的汽油不会送到较高级别的反应器，如具有较高的反应器温度，其中可能发生过度聚合成不期望的较高分子与产物。

5. 发明申请

WO2005105957A1 METHOD FOR REVAMPING FIXED-BED CATALYTIC REFORMERS 审中-公开
标题翻译：固定床催化改性剂的方法
公开(公告)号：WO2005105957A1
公开(公告)日：2005-11-10
申请号：PCT/US2005/013458
申请日：2005-04-19
申请人： EXXONMOBIL RESEARCH ENGINEERING COMPANY , GRAZIANI, Kenneth, R. , IACCINO, Larry, Lee , MELLI, Tomas, R. , MARSHALL, Greg, A , THURTELL, John, Harland , FOJTASEK, Brian, D , FIUTOWSKA, Bozena , VIETS, John, Werner , GOLDSTEIN, Stuart, S.
发明人： GRAZIANI, Kenneth, R. , IACCINO, Larry, Lee , MELLI, Tomas, R. , MARSHALL, Greg, A , THURTELL, John, Harland , FOJTASEK, Brian, D , FIUTOWSKA, Bozena , VIETS, John, Werner , GOLDSTEIN, Stuart, S.
IPC分类号： C10G35/12
CPC分类号： C10G35/12 , B01J8/12 , C10G49/002 , C10G59/02
摘要： A fixed-bed catalytic reformer unit is converted to moving bed reactor/cyclic regenerator operation by re-using the fixed bed reactors of the original unit as regenerator vessels operated in cyclic regeneration mode in a new catalyst regeneration section. A flow connection, suitably a liftpipe, is provided to convey spent catalyst from the spent catalyst outlet of a new moving bed reactor section to the converted regenerator section, together with a flow connection for regenerated catalyst from the regenerator section to the regenerated catalyst inlet of the new moving bed reactor section. A flow control distributor directs spent catalyst sequentially to each of the regenerator vessels to carry out the regeneration with regeneration gas. Each regenerator vessel is cycled through a fill, regeneration, discharge sequence to maintain a continuous flow of catalyst to and from the reactor section.
摘要翻译：固定床催化重整单元通过在新的催化剂再生段中重新使用原始单元的固定床反应器作为在循环再生模式下操作的再生器容器而转化为移动床反应器/循环再生器操作。提供流动连接，适当地是提升管，用于将废催化剂从新的移动床反应器部分的废催化剂出口输送到转化的再生器部分，以及用于再生催化剂从再生器部分到再生催化剂入口的再生催化剂入口的流动连接新移动床反应器段。流量控制分配器将废催化剂顺序地引导到每个再生器容器，以用再生气体进行再生。每个再生器容器循环通过填充，再生，排放顺序，以保持催化剂连续流过反应器部分。

6. 发明申请

WO2008063325A3 PROCESS FOR BENZENE REDUCTION AND SULFUR REMOVAL FROM FCC NAPHTHAS 审中-公开
标题翻译：苯并呋喃降解和硫化氢去除方法
公开(公告)号：WO2008063325A3
公开(公告)日：2008-07-17
申请号：PCT/US2007022030
申请日：2007-10-16
申请人： EXXONMOBIL RES & ENG CO , UMANSKY BENJAMIN S , STANLEY JAMES F , MELLI TOMAS R , SMYTH SEAN C , ROUNDTREE EUGENE M
发明人： UMANSKY BENJAMIN S , STANLEY JAMES F , MELLI TOMAS R , SMYTH SEAN C , ROUNDTREE EUGENE M
IPC分类号： C10G61/00
CPC分类号： C10G29/205 , B01J29/40 , B01J29/70 , B01J29/90 , B01J2229/42 , C10G21/00 , C10G27/00 , C10G45/12 , C10G61/10 , Y02P20/52
摘要： A process for the removal of sulfur compounds and benzene of a catalytically cracked petroleum naphtha comprising benzene, organic sulfur compounds and olefins, by fractionating the cracked naphtha into a relatively low boiling range, olefinic, light catalytic naphtha (LCN) and an olefinic heavy catalytic naphtha (HCN) which boils above the range of the LCN the boiling ranges of the LCN and the HCN being defined by a cut point selected to maintain most of the benzene in the cracked naphtha in the LCN together with olefins in the boiling range of the LCN. The LCN is subjected to an optional non-hydrogenative desulfurization step followed by a fixed bed alkylation step in which the benzene in the LCN is alkylated with the olefins contained in this fraction. The HCN is treated by a similar an alkylation step using the olefins contained in this fraction to alkylate the sulfur compounds, forming alkylated products which boil above the gasoline boiling range. The LCN and HCN are then fractionated to remove light ends and higher boiling sulfur reaction products (disulfides, alkylated thiophenes) boiling above the gasoline boiling range.
摘要翻译：烯烃，轻质催化石脑油（LCN）和烯烃重催化作用，通过将裂解石脑油分馏成相对低沸点的方法，除去含有苯，有机硫化合物和烯烃的催化裂化石脑油的硫化合物和苯的方法石脑油（HCN）沸点高于LCN的范围，LCN和HCN的沸点范围由选择为将LCN中的裂解石脑油中的大部分苯保持在沸点范围内的烯烃所限定的切割点 LCN。对LCN进行任选的非氢化脱硫步骤，然后进行固定床烷基化步骤，其中LCN中的苯用该馏分中所含的烯烃烷基化。通过类似的烷基化步骤处理HCN，使用该级分中所含的烯烃烷基化硫化合物，形成沸点高于汽油沸程的烷基化产物。然后将LCN和HCN分馏以除去沸点高于汽油沸程的轻馏分和较高沸点硫反应产物（二硫化物，烷基化噻吩）。

7. 发明申请

WO2007103314A3 MEMBRANE AND PROCESS FOR RECOVERY OF ACID 审中-公开
标题翻译：醋酸回收膜和方法
公开(公告)号：WO2007103314A3
公开(公告)日：2007-11-01
申请号：PCT/US2007005599
申请日：2007-03-06
申请人： EXXONMOBIL RES & ENG CO , STRAUSS RAMON A , MELLI TOMAS R , HOLLENBACH JOHN H , MINHAS BHUPENDER S
发明人： STRAUSS RAMON A , MELLI TOMAS R , HOLLENBACH JOHN H , MINHAS BHUPENDER S
IPC分类号： B01D61/02 , B01D61/36 , B01D71/36 , B01D71/38 , C01B17/92
CPC分类号： B01D71/28 , B01D61/025 , B01D61/027 , B01D61/362 , B01D61/58 , B01D71/38 , B01D2317/022 , B01D2325/30 , C01B17/88
摘要： A crosslinked polymeric polyvinyl sulfate membrane or crosslinked copolymer polyvinyl sulfate and polyvinyl alcohol membrane, or Nafion® or polytetrafluoroethylene suitable for use in an acid environment, and its use for recovering or reconstituting acid from a feed mixture comprising predominantly acid and water, the method comprising: processing said mixture using a first polymeric membrane such as Nafion® or polytetrafluoroethylene ("PTFE") for example, to form a first retentate containing a substantially greater concentration of acid than said feed mixture and a first permeate containing a substantially greater concentration of water than said mixture, said first polymeric membrane selectively excluding permeance of the acid over the water found in the mixture, and recovering the first retentate; said first retentate can be processed further using a second water reduction membrane system mean to form a retentate stream containing a substantially greater concentration of acid than the first retentate and a second stream containing a substantially greater concentration of water than said first retentate; and recovering the acid retentate.
摘要翻译：交联聚合物聚乙烯硫酸盐膜或交联共聚物聚乙烯硫酸盐和聚乙烯醇膜，或适用于酸性环境的Nafion或聚四氟乙烯及其用于从主要含有酸和水的进料混合物中回收或重构酸的用途，所述方法包括：使用例如Nafion或聚四氟乙烯（“PTFE”）的第一聚合物膜来处理所述混合物，以形成含有比所述进料混合物大得多的酸浓度的第一渗余物和含有基本上更大浓度的水的第一渗透物所述第一聚合物膜选择性地排除所述混合物中存在的水的渗透性，并回收所述第一渗余物; 可以使用第二减水膜系统进一步处理所述第一渗余物，所述第二减水膜系统形成含有比所述第一滞留物大得多的酸浓度的滞留物流，以及含有比所述第一渗余物大得多的水的第二流; 并回收酸滞留物。

8. 发明申请

WO2006094007A3 PROCESS FOR MAKING HIGH OCTANE GASOLINE WITH REDUCED BENZENE CONTENT 审中-公开
公开(公告)号：WO2006094007A3
公开(公告)日：2006-09-08
申请号：PCT/US2006/007169
申请日：2006-02-28
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , UMANSKY, Benjamin, Santiago , CLARK, Michael, christopher , LOPEZ, Carlos, N. , VIETS, John, Werner , SMITH, C., Morris , THURTELL, John, Harland , MELLI, Tomas, R. , SMYTH, Sean, C.
发明人： UMANSKY, Benjamin, Santiago , CLARK, Michael, christopher , LOPEZ, Carlos, N. , VIETS, John, Werner , SMITH, C., Morris , THURTELL, John, Harland , MELLI, Tomas, R. , SMYTH, Sean, C.
IPC分类号： C07C2/68
摘要： Solid phosphoric acid (SPA) olefin oligomerization process units may be converted to operation with a more environmentally favorable solid catalyst. The SPA units in which a light olefin feed is oligomerized to form gasoline boiling range hydrocarbon product, is converted unit to operation -with a molecular sieve based olefin oligomerization catalyst comprising an MWW zeolite material. Besides being more environmentally favorable in use, the MWW based zeolites offer advantages in catalyst cycle life, selectivity. After loading of the catalyst, the converted unit is operated as a fixed-bed unit by passing a C 2 - C 4 olefinic feed and a light aromatic co-feed containing benzene to a fixed bed of the MWW zeolite catalyst to effect alkylation of the benzene with the aromatic co-feed, typically at a temperature from 150 to 350°C, a pressure not greater than 7000 kpa, usually less than 4000 kPa and an olefin space velocity up to 10 WHSV.

9. 发明申请

WO2009120350A1 REDUCED VIBRATION TUBE BUNDLE SUPPORT DEVICE 审中-公开
标题翻译：减少振动管支撑装置
公开(公告)号：WO2009120350A1
公开(公告)日：2009-10-01
申请号：PCT/US2009/001886
申请日：2009-03-27
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , WANNI, Amar, S. , RUDY, Thomas, Michael , MELLI, Tomas, R.
发明人： WANNI, Amar, S. , RUDY, Thomas, Michael , MELLI, Tomas, R.
IPC分类号： F28F9/013
CPC分类号： F28F9/0132 , F28F2265/30
摘要： A tube bundle (10) for a shell and tube type heat exchanger has a support system that allows simple fabrication and provides a secure support of the tubes (12) to mitigate vibration and problems associated with vibration. The tube bundle is composed of tubes that are supported by spaced cages (22) having support rods (26) sized to allow ample clearance with the adjacent tubes and configured in alternating positions and alternating orientations so that sets of four widely spaced cages form a complete support network. To ensure secure support to avoid vibration, sets of support stakes (30) are inserted adjacent to (or in between) the cages to bias the tubes against the support rods of the cages. By this, fabrication is simplified, but a secure support system is maintained.
摘要翻译：用于壳管式热交换器的管束（10）具有支撑系统，其允许简单的制造并且提供管（12）的安全支撑以减轻与振动相关的振动和问题。管束由具有由具有支撑杆（26）的间隔的笼（22）支撑的管组成，其具有尺寸被设计成允许与相邻管的充分间隙并且配置为交替位置和交替取向，使得四组广泛间隔开的笼形成一整套支持网络。为了确保安全的支撑以避免振动，将一组支撑桩（30）插入到笼子之间（或之间），以将管子抵靠笼子的支撑杆偏压。由此，简化了制造，但是保持了安全的支撑系统。

10. 发明申请

WO2008063325A2 PROCESS FOR BENZENE REDUCTION AND SULFUR REMOVAL FROM FCC NAPHTHAS 审中-公开
标题翻译：催化裂化萘脱氮和脱硫工艺
公开(公告)号：WO2008063325A2
公开(公告)日：2008-05-29
申请号：PCT/US2007/022030
申请日：2007-10-16
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , UMANSKY, Benjamin, S. , STANLEY, James, F. , MELLI, Tomas, R. , SMYTH, Sean, C. , ROUNDTREE, Eugene, M.
发明人： UMANSKY, Benjamin, S. , STANLEY, James, F. , MELLI, Tomas, R. , SMYTH, Sean, C. , ROUNDTREE, Eugene, M.
IPC分类号： C10G17/00
CPC分类号： C10G29/205 , B01J29/40 , B01J29/70 , B01J29/90 , B01J2229/42 , C10G21/00 , C10G27/00 , C10G45/12 , C10G61/10 , Y02P20/52
摘要： A process for the removal of sulfur compounds and benzene of a catalytically cracked petroleum naphtha comprising benzene, organic sulfur compounds and olefins, by fractionating the cracked naphtha into a relatively low boiling range, olefinic, light catalytic naphtha (LCN) and an olefinic heavy catalytic naphtha (HCN) which boils above the range of the LCN the boiling ranges of the LCN and the HCN being defined by a cut point selected to maintain most of the benzene in the cracked naphtha in the LCN together with olefins in the boiling range of the LCN. The LCN is subjected to an optional non-hydrogenative desulfurization step followed by a fixed bed alkylation step in which the benzene in the LCN is alkylated with the olefins contained in this fraction. The HCN is treated by a similar an alkylation step using the olefins contained in this fraction to alkylate the sulfur compounds, forming alkylated products which boil above the gasoline boiling range. The LCN and HCN are then fractionated to remove light ends and higher boiling sulfur reaction products (disulfides, alkylated thiophenes) boiling above the gasoline boiling range.
摘要翻译：通过将裂化石脑油分馏成相对低沸点的烯烃轻质催化石脑油来去除包含苯，有机硫化合物和烯烃的催化裂化石脑油中的硫化合物和苯的方法（LCN）和在LCN范围以上沸腾的烯烃重催化石脑油（HCN），LCN和HCN的沸程由选择用于将LCN中裂化石脑油中的大部分苯维持在一起的切点限定与烯烃在LCN的沸点范围内反应。 LCN进行任选的非氢化脱硫步骤，然后进行固定床烷基化步骤，其中LCN中的苯用该馏分中所含的烯烃进行烷基化。 HCN通过类似的烷基化步骤进行处理，使用该馏分中所含的烯烃将硫化合物烷基化，形成沸点高于汽油沸程的烷基化产物。然后将LCN和HCN分馏以除去沸点高于汽油沸程的轻馏分和高沸点硫反应产物（二硫化物，烷基化噻吩）。

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