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    • 4. 发明授权
    • Use of exfoliated clay nanoplatelets and method for encapsulating cations
    • 使用剥离粘土纳米片和封装阳离子的方法
    • US08513519B2
    • 2013-08-20
    • US12800866
    • 2010-05-24
    • King-Fu LinChia-Hsin LeeKeng-Jen LinKen-Yen Liu
    • King-Fu LinChia-Hsin LeeKeng-Jen LinKen-Yen Liu
    • H01L31/04
    • H01G9/2004H01G9/2031Y02E10/542Y02P70/521
    • This invention relates to a method for making an electrolyte composition of a dye-sensitized solar cell comprising utilizing exfoliated clay nanoplatelets and the method for rapidly encapsulating cations. The electrolyte composition mainly includes exfoliated clay nanoplatelets, an ionic liquid and iodine. The method for rapidly encapsulating cation comprises adding the exfoliated clay nanoplatelets into a cationic solution, wherein the exfoliated clay nanoplatelets encapsulates cations and recovers into a layered structure such that phase separation of the solution occurs; and filtrating the solution to separate the clay nanoplatelets encapsulating the cations. The exfoliated clay nanoplatelets have a unique property of encapsulation for the cations, is suitable for use in an electrolyte composition for dye-sensitized solar cells, cationic drug encapsulation and environmental protection.
    • 本发明涉及一种制造染料敏化太阳能电池的电解质组合物的方法,其包括利用剥离粘土纳米片和快速包封阳离子的方法。 电解质组合物主要包括剥离粘土纳米片,离子液体和碘。 用于快速包封阳离子的方法包括将剥离的粘土纳米片加入阳离子溶液中,其中剥离的粘土纳米片包封阳离子并回收成层状结构,使得溶液发生相分离; 并过滤该溶液以分离封装阳离子的粘土纳米片。 剥离粘土纳米片具有独特的阳离子封装性能,适用于染料敏化太阳能电池的电解质组合物,阳离子药物包封和环境保护。
    • 6. 发明申请
    • Use of exfoliated clay nanoplatelets and method for encapsulating cations
    • 使用剥离粘土纳米片和封装阳离子的方法
    • US20110031429A1
    • 2011-02-10
    • US12800866
    • 2010-05-24
    • King-Fu LinChia-Hsin LeeKeng-Jen LinKen-Yen Liu
    • King-Fu LinChia-Hsin LeeKeng-Jen LinKen-Yen Liu
    • H01G9/022
    • H01G9/2004H01G9/2031Y02E10/542Y02P70/521
    • This invention relates to a method for making an electrolyte composition of a dye-sensitized solar cell comprising utilizing exfoliated clay nanoplatelets and the method for rapidly encapsulating cations. The electrolyte composition mainly includes exfoliated clay nanoplatelets, an ionic liquid and iodine. The method for rapidly encapsulating cation comprises adding the exfoliated clay nanoplatelets into a cationic solution, wherein the exfoliated clay nanoplatelets encapsulates cations and recovers into a layered structure such that phase separation of the solution occurs; and filtrating the solution to separate the clay nanoplatelets encapsulating the cations. The exfoliated clay nanoplatelets have a unique property of encapsulation for the cations, is suitable for use in an electrolyte composition for dye-sensitized solar cells, cationic drug encapsulation and environmental protection.
    • 本发明涉及一种制造染料敏化太阳能电池的电解质组合物的方法,其包括利用剥离粘土纳米片和快速包封阳离子的方法。 电解质组合物主要包括剥离粘土纳米片,离子液体和碘。 用于快速包封阳离子的方法包括将剥离的粘土纳米片加入阳离子溶液中,其中剥离的粘土纳米片包封阳离子并回收成层状结构,使得溶液发生相分离; 并过滤该溶液以分离封装阳离子的粘土纳米片。 剥离粘土纳米片具有独特的阳离子封装性能,适用于染料敏化太阳能电池的电解质组合物,阳离子药物包封和环境保护。
    • 7. 发明申请
    • Method for forming polymer-clay nanocomposite latex and its application on sealing and semi-conductive materials
    • 形成聚合物 - 粘土纳米复合胶乳的方法及其在密封和半导体材料上的应用
    • US20080287587A1
    • 2008-11-20
    • US11840972
    • 2007-08-19
    • King-Fu LinAn-Ting ChienMing-Huei YenChia-Hsin LeeTing-Hsiang WengChuan-Cheng Chou
    • King-Fu LinAn-Ting ChienMing-Huei YenChia-Hsin LeeTing-Hsiang WengChuan-Cheng Chou
    • C08K3/36
    • C08F2/22C08F2/44C08F218/04C08F220/18C08F220/56
    • The present invention discloses a method to prepare the polymer-clay nanocomposite latex. At first, a clay and a water-soluble initiator are mixed in water to form an intermediate solution, in which the initiator is absorbed or intercalated into the clay. Then, at least one monomer from vinyl ester, acrylic and acrylamide derivatives is added into the intermediate solution for soap-free emulsion polymerization, which may also be added with some other monomers such as acrylic acid, maleic anhydride, vinyl chloride, acrylonitrile ethylene, et al. for copolymerization. During soap-free emulsion polymerization, the radicals from the dissociated initiators will react with the monomers to form the monomer radicals, which tend to diffuse into the interlayer region of clays for further polymerization and eventually exfoliate the clays. The prepared exfoliated polymer-clay nanocomposite latex can be cast into a vapor-impermeable film so that it can be used as a sealing material or coating. The exfoliated clay in nanoplatelet form is a two-dimensional electrolyte nanomaterial and its aqueous solution is conductive. The exfoliated clay aqueous solutions can be prepared by removing the polymer matrix from the nanocomposite latex with solvent. As the exfoliated clay solution is cast into a film with the clay content is more than or equal to 80 wt %, the film is semi-conductive. Thus, the exfoliated clay aqueous solutions can be applied to the electronic materials and organic/inorganic multilayer composite films.
    • 本发明公开了一种制备聚合物 - 粘土纳米复合胶乳的方法。 首先,在水中混合粘土和水溶性引发剂,形成中间溶液,其中引发剂被吸收或嵌入粘土中。 然后,将乙烯基酯,丙烯酸和丙烯酰胺衍生物中的至少一种单体加入用于无皂乳液聚合的中间溶液中,其也可以加入一些其它单体如丙烯酸,马来酸酐,氯乙烯,丙烯腈乙烯, et al。 用于共聚。 在无皂乳液聚合过程中,来自离解的引发剂的自由基将与单体反应形成单体自由基,其倾向于扩散到粘土的中间层区域以进一步聚合并最终剥落粘土。 制备的剥离聚合物 - 粘土纳米复合胶乳可以浇铸成不透气的膜,使其可以用作密封材料或涂层。 纳米血小板形式的剥离粘土是二维电解质纳米材料,其水溶液是导电的。 剥离的粘土水溶液可以通过用溶剂从纳米复合胶乳中除去聚合物基质来制备。 当剥离粘土溶液浇铸成粘土含量大于或等于80重量%的膜时,该膜是半导体的。 因此,剥离粘土水溶液可以应用于电子材料和有机/无机多层复合膜。
    • 8. 发明申请
    • Supramolecular structures and method for forming the same
    • 超分子结构及其形成方法
    • US20070120113A1
    • 2007-05-31
    • US11287309
    • 2005-11-28
    • King-Fu LinChi-Chun Hsieh
    • King-Fu LinChi-Chun Hsieh
    • H01L51/00C07D495/02C07D409/14
    • C07C309/32
    • A primary supramolecular structure is described. The primary supramolecular structure has a shape of ring-like disk. The shape of ring-like disk has a diameter of about 10 nanometers to about 60 nanometers. The mentioned primary supramolecular structure is formed by self-assembly of amphiphilic conjugate molecules. Moreover, a secondary supramolecular structure is described. The secondary supramolecular structure has a shape of ring-like disk. The shape of ring-like disk has a diameter of about 100 nanometers to about 300 nanometers. The mentioned secondary supramolecular structure is formed by self-assembly of amphiphilic conjugate molecules hybrid with metal alkoxides or non-metal alkoxides.
    • 描述了一个主要的超分子结构。 主要的超分子结构具有环状盘的形状。 环形盘的形状具有约10纳米至约60纳米的直径。 所述的主要超分子结构通过两亲性共轭分子的自组装形成。 此外,描述了次级超分子结构。 次级超分子结构具有环状圆盘形状。 环形盘的形状具有约100纳米至约300纳米的直径。 所述的次级超分子结构通过与金属醇盐或非金属醇盐杂交的两亲性缀合物分子的自组装形成。
    • 9. 发明授权
    • Non-destructive method for determining the extent of cure of a
polymerizing material and the solidification of a thermoplastic polymer
based on wavelength shift of fluroescence
    • 用于确定聚合材料的固化程度和基于荧光波长漂移的热塑性聚合物固化的非破坏性方法
    • US5598005A
    • 1997-01-28
    • US389823
    • 1995-02-15
    • Francis W. WangRobert E. LowryKing-Fu Lin
    • Francis W. WangRobert E. LowryKing-Fu Lin
    • A61F2/46G01N21/64G01N33/44
    • G01N21/648A61B17/8836G01N21/64A61B2017/883G01N33/44
    • The change in the peak fluorescence wavelength of a small amount of a fluorescent compound, i.e., a fluorophore, which has been dissolved in a polymerizing material or a thermoplastic polymer is used to determine the extent of cure or solidification, respectively. The measured wavelength-shift can either be compared with a previously determined correlation to obtain an absolute value for the extent of cure, or can be utilized to compare or maintain an acceptable extent of cure throughout a manufacturing or a clinical process. Similarly, in the processing of a thermoplastic polymer by injection molding, the measured wavelength shift can either be compared with a previously determined correlation to obtain an absolute value for the temperature of the polymer, or can be utilized to adjust the injection molding cycle so that the mold is opened at the optimum times. The fluorophores used in the method are preferably selected from a class of fluorophores comprising alpha, omega substituted linear alkenes having an electron accepting group attached at the alpha position and an electron donating group attached at the omega position.
    • 使用溶解在聚合材料或热塑性聚合物中的少量荧光化合物即荧光团的峰值荧光波长的变化来分别确定固化或固化的程度。 测量的波长漂移可以与先前确定的相关性进行比较,以获得固化程度的绝对值,或者可以用于在整个制造或临床过程中比较或维持可接受的固化程度。 类似地,在通过注射成型处理热塑性聚合物时,将测量的波长偏移与先前确定的相关性进行比较以获得聚合物温度的绝对值,或者可用于调节注射成型周期,使得 模具在最佳时间打开。 在该方法中使用的荧光团优选选自一类荧光团,其包括在α位置附有电子接受基团的α,ω-取代的线性烯烃和连接在ω位置的给电子基团。