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    • 8. 发明授权
    • Transparent thermoplastic resin compositions and process for preparing the same
    • 透明热塑性树脂组合物及其制备方法
    • US07579406B2
    • 2009-08-25
    • US11206581
    • 2005-08-18
    • Jeong-su ChoiMi-young LeeHyong-min BahnKeun-hoon YooWon-seok Lee
    • Jeong-su ChoiMi-young LeeHyong-min BahnKeun-hoon YooWon-seok Lee
    • C08L47/00
    • C08F285/00C08L33/04C08L51/04Y10S525/902C08F220/00C08L2666/04
    • The present invention relates to a transparent thermoplastic resin composition which characteristically contains A) 20-80 weight % of graft copolymer composed of a) conjugated diene rubber latex; b) intermediate layer prepared by copolymerization of acrylic acid alkylester derivative and aromatic vinyl derivative with the above a); and c) graft layer prepared by copolymerization of methacrylic acid alkylester derivative or acrylic acid alkylester derivative, a romatic vinyl derivative and vinyl cyan derivative with the above b) and B) 20-80 weight % of MSAN copolymer prepared by copolymerization of methacrylic acid alkylester derivative or acrylic acid alkylester derivative, aromatic vinyl derivative and vinyl cyan derivative. The transparent thermoplastic resin composition of the present invention has enhanced transparency, impact strength, surface gloss, weather resistance and color by being prepared by the method of the invention which is characterized by the steps of forming an intermediate layer by adding acrylic rubber to polybutadiene rubber, grafting, and regulating refractive indices of each monomers of a copolymer.
    • 本发明涉及一种透明热塑性树脂组合物,其特征在于包含A)20-80重量%的由共轭二烯橡胶胶乳组成的接枝共聚物; b)通过丙烯酸烷基酯衍生物和芳族乙烯基衍生物与上述a)的共聚制备的中间层; 和c)通过甲基丙烯酸烷基酯衍生物或丙烯酸烷基酯衍生物,芳香族乙烯基衍生物和乙烯基氰基衍生物与上述b)和B)共聚制备的接枝层,其为通过甲基丙烯酸烷基酯共聚制备的20-80重量%的MSAN共聚物 衍生物或丙烯酸烷基酯衍生物,芳族乙烯基衍生物和乙烯基氰基衍生物。 本发明的透明热塑性树脂组合物通过本发明的方法制备透明性,冲击强度,表面光泽,耐候性和颜色,其特征在于以下步骤:通过向聚丁二烯橡胶中加入丙烯酸橡胶形成中间层 ,接枝和调节共聚物各单体的折射率。
    • 9. 发明申请
    • Method for preparing rubber-reinforced thermoplastic resin, and rubber-reinforced thermoplastic resin composition using the same
    • 制备橡胶增强热塑性树脂的方法和使用其的橡胶增强热塑性树脂组合物
    • US20070123648A1
    • 2007-05-31
    • US10563695
    • 2005-03-25
    • Jun-tae LeeKeun-hoon YooChan-hong LeeHyun-do KimChang-mook Kim
    • Jun-tae LeeKeun-hoon YooChan-hong LeeHyun-do KimChang-mook Kim
    • C08L51/00
    • C08F279/02C08F279/04C08F285/00C08F291/02C08L51/04C08L55/02C08F212/10C08L2666/02C08L2666/04
    • The present invention relates to a method for preparing a rubber-reinforced thermoplastic resin, a rubber-reinforced thermoplastic resin prepared by the same method, and a rubber-reinforced thermoplastic resin composition using the same, wherein the rubber-reinforced thermoplastic resin has excellent heat-sealability and thermal stability maintaining good mechanical properties. More specifically, the present invention relates to a method for preparing a rubber-reinforced thermoplastic resin, a rubber-reinforced thermoplastic resin prepared by the same method, and a rubber-reinforced thermoplastic resin composition using the same characterized by, on the basis of 100 weight parts of total monomer used to prepare graft copolymer, using the mixture comprising 10 to 30 weight parts of a rubber latex having average particle diameter of 0.08 to 0.16 μm and gel content of 65 to 95 weight % and 15 to 45 weight parts of a rubber latex having average particle diameter of 0.26 to 0.34 μm and gel content of 55 to 85 weight %, keeping the weight ratio of vinyl cyanide compound including acrylonitrile to aromatic vinyl compound including styrene from 16/84 to 24/76 as a monomer composition grafted on rubber latex, and adjusting the graft ratio of graft copolymer, i.e. rubber-reinforced thermoplastic resin, from 25 to 65.
    • 本发明涉及一种制备橡胶增强热塑性树脂的方法,通过相同方法制备的橡胶增强热塑性树脂和使用其的橡胶增强热塑性树脂组合物,其中橡胶增强热塑性树脂具有优异的热 - 密封性和热稳定性保持良好的机械性能。 更具体地,本发明涉及一种制备橡胶增强热塑性树脂的方法,通过相同方法制备的橡胶增强热塑性树脂和使用其的橡胶增强热塑性树脂组合物,其特征在于,基于100 用于制备接枝共聚物的总单体的重量份,使用包含10〜30重量份平均粒径为0.08〜0.16μm,凝胶含量为65〜95重量%,15〜45重量份的橡胶胶乳的混合物 橡胶胶乳的平均粒径为0.26〜0.34μm,凝胶含量为55〜85wt%,将包含丙烯腈的乙烯基氰化合物与包括苯乙烯的芳族乙烯基化合物的重量比从16/84至24/76保持为接枝的单体组合物 并将接枝共聚物(即橡胶增强热塑性树脂)的接枝率调节为25至65。