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    • 3. 发明授权
    • Energy storage device and methods of manufacture
    • 储能装置及制造方法
    • US5800857A
    • 1998-09-01
    • US718569
    • 1996-09-30
    • Nazir AhmadKeh-Chi Tsai
    • Nazir AhmadKeh-Chi Tsai
    • H01G9/00H01G9/155H01M2/02H01M2/08H01M2/16H01M2/36H01M4/00H01M4/04H01M4/58H01M6/48H01M10/04B05D5/12
    • H01G9/155H01M10/0418H01M2/0212H01M2/08H01M2/1673H01M4/00H01M4/04H01M4/58H01M6/48H01M2/36H01M4/0438Y02E60/13Y10T29/41Y10T29/417
    • A dry preunit (10), includes a plurality of cells (110, 112, 114) in a true bipolar configuration, which are stacked and bonded together, to impart to the device an integral and unitary construction. Each cell (114) includes two electrically conductive electrodes (111A, 111B) that are spaced apart by a predetermined distance. The cell (114) also includes two identical dielectric gaskets (121, 123) that are interposed, in registration with each other, between the electrodes (111A, 111B), for separating and electrically insulating these electrodes. When the electrodes (111A, 111B), and the gaskets (121, 123) are bonded together, at least one fill gap (130) is formed for each cell. Each cell (114) also includes a porous and conductive coating layer (119, 120) that is formed on one surface of each electrode. The coating layer (119) includes a set of closely spaced-apart peripheral microprotrusions (125), and a set of distally spaced-apart central microprotrusions (127). These microprotrusions (125, 127) impart structural support to the cells, and provide additional insulation between the electrodes. An energy storage device (10A) such as a capacitor, is created with the addition of an electrolyte to the gap (130) of the dry preunit (10) and subsequent sealing of the fill ports. Organic polymers in organic solvents are used to seal the edges of electrodes of porous metal oxides, metal nitrides, or metal carbides to reduce or eliminate leakage current. The preparation of metal nitrides and metal carbides are claimed for electrode use.
    • PCT No.PCT / US95 / 03985第 371日期1996年9月30日 102(e)1996年9月30日PCT 1995年3月30日PCT PCT。 公开号WO95 / 26833 日期1995年10月12日干燥单元(10)包括多个单元(110,112,114),其具有真正的双极结构,它们堆叠并结合在一起,以赋予器件整体和整体结构。 每个单元(114)包括间隔开预定距离的两个导电电极(111A,111B)。 电池(114)还包括在电极(111A,111B)之间插入彼此对准的两个相同的电介质垫圈(121,123),用于分离和电绝缘这些电极。 当电极(111A,111B)和垫圈(121,123)结合在一起时,为每个电池形成至少一个填充间隙(130)。 每个电池(114)还包括形成在每个电极的一个表面上的多孔和导电涂层(119,120)。 涂层(119)包括一组紧密间隔开的周边微突起(125)和一组远离间隔开的中心微突起(127)。 这些微突起(125,127)赋予细胞结构支撑,并在电极之间提供额外的绝缘。 通过向干燥预浸料(10)的间隙(130)添加电解液并随后密封填充口而产生诸如电容器的能量存储装置(10A)。 有机溶剂中的有机聚合物用于密封多孔金属氧化物,金属氮化物或金属碳化物电极的边缘,以减少或消除漏电流。 要求用于电极使用的金属氮化物和金属碳化物的制备。
    • 4. 发明申请
    • ENERGY STORAGE DEVICE FABRICATION METHOD
    • 能源储存装置制造方法
    • US20140027043A1
    • 2014-01-30
    • US13606429
    • 2012-09-07
    • Keh-Chi TsaiYueh-Hsun Lee
    • Keh-Chi TsaiYueh-Hsun Lee
    • B32B37/12
    • H01G11/84H01G11/12H01G11/14H01G11/54H01G11/82Y02E60/13
    • An energy storage device fabrication method includes the steps of: mounting a frame shell at the top wall of a first plate electrode, mounting a glue frame at the top wall of the first plate electrode around the frame shell to have the top wall of the glue frame be disposed above the elevation of top wall of the frame shell, filling an electrolyte solution in the accommodation chamber defined by the glue frame, the frame shell and the top wall of the first plate member under a vacuum environment to form a first unit, mounting a second unit with a second plate electrode at the top wall of the glue frame, and bonding the second unit to the glue frame of the first unit under a vacuum environment to seal the electrolyte solution in between the first plate electrode and the second plate electrode.
    • 一种储能装置的制造方法,其特征在于,包括以下步骤:将框架壳体安装在第一板状电极的顶壁,将框架安装在第一板状电极的顶壁周围框架壳体上,使胶水的顶壁 框架设置在框架壳体的顶壁的高度上方,在真空环境下在由胶框架,框架壳体和第一板构件的顶壁限定的容纳室中填充电解质溶液以形成第一单元, 将第二单元与第二平板电极安装在胶框架的顶壁处,并且在真空环境下将第二单元与第一单元的胶合框架结合,以密封第一板电极和第二板之间的电解质溶液 电极。
    • 7. 发明申请
    • PORTABLE ELECTRICAL LIQUID DISPENSING APPARATUS
    • 便携式电液分配装置
    • US20100294800A1
    • 2010-11-25
    • US12468059
    • 2009-05-19
    • Keh-Chi TsaiWen-Hua Lin
    • Keh-Chi TsaiWen-Hua Lin
    • F15C4/00
    • B67D7/005B67D7/425B67D7/58
    • A portable electrical liquid dispensing apparatus includes a housing, a power supply detachably connected with the housing, a driving unit accommodated in the housing and electrically connected with the power supply, a liquid dispensing unit accommodated in the housing and coupled to the driving unit, a first dispensing pipe having a first entry end and a first exhaust end connected with the liquid dispensing unit, and a second dispensing pipe having a second entry end connected with the liquid dispensing unit and a second exhaust end. When the electrical liquid dispensing apparatus is used, the liquid dispensing unit can be driven by the driving unit to dispense the fuel from a fuel tank into an agricultural machine through the first dispensing pipe and the second dispensing pipe, thereby enhancing the efficiency and convenience of refueling operation.
    • 便携式电液分配装置包括壳体,与壳体可拆卸地连接的电源,容纳在壳体中并与电源电连接的驱动单元,容纳在壳体中并联接到驱动单元的液体分配单元, 第一分配管具有第一入口端和与液体分配单元连接的第一排气端,以及具有与液体分配单元连接的第二入口端和第二排气端的第二分配管。 当使用电液体分配装置时,液体分配单元可以由驱动单元驱动,以通过第一分配管和第二分配管将燃料从燃料箱分配到农业机器中,从而提高了效率和便利性 加油操作
    • 8. 发明授权
    • Method of producing high surface area metal oxynitrides as substrates in
electrical energy storage
    • 在电能存储中生产高表面积金属氮氧化物作为基底的方法
    • US5980977A
    • 1999-11-09
    • US761837
    • 1996-12-09
    • Charles Z. DengKeh Chi TsaiDania Ghantous
    • Charles Z. DengKeh Chi TsaiDania Ghantous
    • H01G9/058B82B1/00H01G9/00H01G9/04H01G9/042H01G9/155H01M2/36H01M4/00H01M4/04H01M4/58H01M4/66H01M6/48H01M10/04B05D5/12
    • H01M10/0418H01G11/26H01G11/46H01G11/86H01G9/0032H01G9/042H01M4/0402H01M4/58H01M4/66H01M6/48H01M2/36H01M4/0438Y02E60/13
    • The present invention concerns a process to produce a high surface area niobium oxynitride, tantalum oxynitride, vanadium oxynitride, zirconium oxynitride, titanium oxynitride or molybdenum oxynitride coated substrate for use as an electrical energy storage component in a capacitor or a battery configuration. The process relates to:(a) coating one or both flat etched surfaces of a solid substrate, in the form of a thin sheet, with a solution or a slurry of a metal halide in a liquid volatile carrier to produce a thin surface film;(b) contacting the metal halide surface film-carrier coated substrate of step (a) with oxygen, air, or combinations thereof at a temperature to convert the metal halide to metal oxide, respectively, as a thin film and to remove the liquid volatile carrier;(c) repeating steps (a) and (b) to obtain a desired thickness;(d) heating the metal oxide film coated substrate of step (c) in oxygen, air or combinations thereof to convert at least about 95% of the metal chloride to metal oxide;(e) increasing the temperature of the metal oxide coated substrate to elevated temperatures;(f) contacting the oxide coated substrate produced in step (e) with a nitrogen source selected from excess flowing gaseous ammonia, a mixture of ammonia gas and hydrogen gas, or a mixture of hydrogen gas and nitrogen gas at elevated temperatures to convert about 95% or greater of the oxide coating to the corresponding metal oxynitride on the substrate, which metal oxynitride layer has a high surface area and is electrically conductive; and(g) cooling to ambient temperature and recovering the high surface area metal oxynitride coated substrate produced in step (f).
    • 本发明涉及一种制造用作电容器或电池结构中的电能存储部件的高表面积铌氧氮化物,氮氧化钽,氮氧化钒,氮氧化锆,氮氧化钛或氮氧化钼涂覆的基板的方法。 该方法涉及:(a)以液体挥发性载体中的金属卤化物的溶液或浆料将薄片形式的固体基材的一个或两个平坦蚀刻表面涂覆以产生薄的表面膜; (b)将金属卤化物表面的载体涂覆的步骤(a)的基材与氧气,空气或其组合在一起的温度下分别将金属卤化物分解成金属氧化物作为薄膜,并除去液体挥发性 载体 (c)重复步骤(a)和(b)以获得所需的厚度; (d)在氧气,空气或其组合中将步骤(c)的金属氧化物膜涂覆的基材加热以将至少约95%的金属氯化物转化为金属氧化物; (e)将金属氧化物涂覆的基底的温度升高到升高的温度; (f)使步骤(e)中生产的氧化物涂覆的基材与选自过量流动的气态氨,氨气和氢气的混合物或氢气和氮气的混合物的氮源在升高的温度下接触,以转化约95 对基板上相应的金属氮氧化物的氧化物涂层的%或更多,该金属氮氧化物层具有高的表面积并具有导电性; 和(g)冷却至环境温度并回收在步骤(f)中制备的高表面积金属氧氮化物涂覆的基材。
    • 10. 发明授权
    • Cell comprising an alkali metal and aqueous electrolyte
    • 包含碱金属和水性电解质的电池
    • US4007057A
    • 1977-02-08
    • US645199
    • 1975-12-29
    • Ernest Lucius LittauerRoger Paul HollandsworthKeh Chi Tsai
    • Ernest Lucius LittauerRoger Paul HollandsworthKeh Chi Tsai
    • H01M6/04H01M6/26H01M6/32H01M12/04
    • H01M6/26H01M12/04
    • In a reactive metal-water electrochemical cell, an alkaline electrolyte containing soluble inorganic ions which are reduced preferentially to water at the cathode. More particularly, the additives substantially reduce or eliminate reduction of water and evolution of hydrogen at the cathode resulting in significant improvement in current efficiency, gravimetric energy density and cell potential at a given current. Additionally, suppression of hydrogen evolution makes possible a sealed system with venting of gases from the cell no longer necessary. The inorganic ions of the invention are nitrite, hypochlorite, chlorate, bromate, dinitrogen trioxide and sulfite ions which are formed when soluble salts of nitrite, sulfite, hypochlorate, bromate, chlorate, soluble gases such as dinitrogen trioxide and sulfur dioxide and other soluble inorganic compounds are dissolved in the alkaline electrolyte.
    • 在反应性金属 - 水电化学电池中,含有可溶性无机离子的碱性电解质在阴极优先被还原成水。 更具体地,添加剂基本上减少或消除了水的还原和阴极的析出,导致在给定电流下电流效率,重量分析能量密度和电池电位显着提高。 另外,抑制析氢使得密封系统成为可能,不再需要从电池排出气体。 本发明的无机离子是亚硝酸盐,次氯酸盐,氯酸盐,溴酸盐,二氧化氮和亚硫酸盐离子,当亚硝酸盐,亚硫酸盐,次氯酸盐,溴酸盐,氯酸盐,可溶性气体如三氧化二氮和二氧化硫和其他可溶性无机物 化合物溶解在碱性电解质中。