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    • 1. 发明申请
    • SEPARATION OF GASES
    • 气体分离
    • US20120297822A1
    • 2012-11-29
    • US13575968
    • 2011-01-21
    • Michael Edward BaileyStefano ConsonniJonathan Alec ForsythManuele GattiEmanuele MartelliYasushi MoriKazumasa OguraFederico Vigano
    • Michael Edward BaileyStefano ConsonniJonathan Alec ForsythManuele GattiEmanuele MartelliYasushi MoriKazumasa OguraFederico Vigano
    • F25J1/00
    • C01B3/506C01B3/52C01B2203/0415C01B2203/046C01B2203/0475C01B2203/0485C01B2203/0805C01B2203/0883C01B2203/146F25J3/0625F25J3/0655F25J3/067F25J2205/40F25J2205/50F25J2215/04F25J2230/30F25J2240/30F25J2270/06Y02C10/12Y02P20/152
    • A process for separating sour shifted synthesis gas feedstock into liquid carbon dioxide, a gaseous hydrogen-containing gas and separated sulphur-containing components includes the steps of a. scrubbing the sour shifted gas elevated pressure with an alcohol solvent in a first scrubber and separately recovering an alcohol stream containing the sulphur-containing components and a sweet shifted gas; b. thereafter cooling the sweet shifted gas to a temperature and elevated pressure at which the carbon dioxide contained therein condenses and a two-phase gas- liquid mixture is formed; c. separating the two-phase mixture of stage (b) into separate liquid carbon dioxide and gaseous hydrogen-containing fractions in a fractionation unit; d. extracting residual carbon dioxide from the separated gaseous hydrogen-containing fraction by scrubbing the gaseous hydrogen-containing fraction at elevated pressure with an alcohol solvent in a second scrubber and recovering an alcohol stream containing carbon dioxide; e. feeding the alcohol stream containing carbon dioxide produced in step (d) to the first scrubber and f. warming and expanding the scrubber gaseous hydrogen-containing fraction using at least one heat exchanger to exchange heat with the mixture of step (b) and at least one turbo-expander capable of recovering mechanical work. The process described may be used in for example Integrated Gasification Combined Cycles (IGCC) where the source of fuel is coal or low grade carbon sources such as lignite, tar sands and shale oil.
    • 用于将酸移位的合成气原料分离成液态二氧化碳,含气态气体和分离的含硫组分的方法包括以下步骤:a。 在第一洗涤器中用醇溶剂洗涤酸转移气体升高的压力,并单独回收含有含硫成分和甜味转换气体的醇流; b。 然后将甜味转移气体冷却至其中所含的二氧化碳冷凝的温度和升高的压力,并形成两相气液混合物; C。 将分段(b)的两相混合物分离成分离液体二氧化碳和气态含氢馏分; d。 通过在第二洗涤器中用醇溶剂在升高的压力下洗涤含气态气体馏分并回收含二氧化碳的醇流,从分离的含气态氢气馏分中提取残余二氧化碳; e。 将步骤(d)中产生的含有二氧化碳的醇流送入第一洗涤器,f。 使用至少一个热交换器使洗涤器气态含氢馏分升温和膨胀,以与步骤(b)的混合物和能够回收机械功的至少一个涡轮膨胀机交换热量。 所描述的方法可用于例如集成气化组合循环(IGCC),其中燃料源为煤或低等级碳源,例如褐煤,焦油砂和页岩油。
    • 5. 发明授权
    • Separation of gases
    • 气体分离
    • US09212061B2
    • 2015-12-15
    • US13575968
    • 2011-01-21
    • Michael Edward BaileyStefano ConsonniJonathan Alec ForsythManuele GattiEmanuele MartelliYasushi MoriKazumasa OguraFederico Vigano
    • Michael Edward BaileyStefano ConsonniJonathan Alec ForsythManuele GattiEmanuele MartelliYasushi MoriKazumasa OguraFederico Vigano
    • F25J3/00C01B3/50C01B3/52F25J3/06
    • C01B3/506C01B3/52C01B2203/0415C01B2203/046C01B2203/0475C01B2203/0485C01B2203/0805C01B2203/0883C01B2203/146F25J3/0625F25J3/0655F25J3/067F25J2205/40F25J2205/50F25J2215/04F25J2230/30F25J2240/30F25J2270/06Y02C10/12Y02P20/152
    • A process for separating sour shifted synthesis gas feedstock into liquid carbon dioxide, a gaseous hydrogen-containing gas and separated sulphur-containing components includes the steps of a. scrubbing the sour shifted gas elevated pressure with an alcohol solvent in a first scrubber and separately recovering an alcohol stream containing the sulphur-containing components and a sweet shifted gas; b. thereafter cooling the sweet shifted gas to a temperature and elevated pressure at which the carbon dioxide contained therein condenses and a two-phase gas-liquid mixture is formed; c. separating the two-phase mixture of stage (b) into separate liquid carbon dioxide and gaseous hydrogen-containing fractions in a fractionation unit; d. extracting residual carbon dioxide from the separated gaseous hydrogen-containing fraction by scrubbing the gaseous hydrogen-containing fraction at elevated pressure with an alcohol solvent in a second scrubber and recovering an alcohol stream containing carbon dioxide; e. feeding the alcohol stream containing carbon dioxide produced in step (d) to the first scrubber and f. warming and expanding the scrubber gaseous hydrogen-containing fraction using at least one heat exchanger to exchange heat with the mixture of step (b) and at least one turbo-expander capable of recovering mechanical work. The process described may be used in for example Integrated Gasification Combined Cycles (IGCC) where the source of fuel is coal or low grade carbon sources such as lignite, tar sands and shale oil.
    • 用于将酸移位的合成气原料分离成液态二氧化碳,含气态气体和分离的含硫组分的方法包括以下步骤:a。 在第一洗涤器中用醇溶剂洗涤酸转移气体升高的压力,并单独回收含有含硫成分和甜味转换气体的醇流; b。 然后将甜味转移气体冷却至其中所含的二氧化碳冷凝的温度和升高的压力,并形成两相气液混合物; C。 将分段(b)的两相混合物分离成分离液体二氧化碳和气态含氢馏分; d。 通过在第二洗涤器中用醇溶剂在升高的压力下洗涤含气态气体馏分并回收含二氧化碳的醇流,从分离的含气态氢气馏分中提取残余二氧化碳; e。 将步骤(d)中产生的含有二氧化碳的醇流送入第一洗涤器,f。 使用至少一个热交换器使洗涤器气态含氢馏分升温和膨胀,以与步骤(b)的混合物和能够回收机械功的至少一个涡轮膨胀机交换热量。 所描述的方法可用于例如集成气化组合循环(IGCC),其中燃料源为煤或低等级碳源,例如褐煤,焦油砂和页岩油。