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    • 6. 发明授权
    • Styrene resin composition and method of producing molding thereof
    • 苯乙烯树脂组合物及其成型方法
    • US5408003A
    • 1995-04-18
    • US54978
    • 1993-04-30
    • Satoshi HondaKazuhiro YokooHideaki Matsuura
    • Satoshi HondaKazuhiro YokooHideaki Matsuura
    • C08F257/02C08F265/04C08L25/14C08L33/06C08L25/06C08L35/06
    • C08F257/02C08F265/04C08L25/14C08L2205/22
    • A styrene resin composition comprising a crosslinked styrene resin and uniformly dispersed therein an uncrosslinked resin capable of being extracted with an organic solvent, the amount of the uncrosslinked resin being from 3 to 50% by weight based on the total amount of the composition; and a method of producing a molding of a styrene resin composition, which method comprises the step of subjecting to cast polymerization a liquid mixture comprising: (a) a styrene monomer in an amount of 30% by weight or more based on the total amount of the ingredients (a), (b), and (c); (b) a monofunctional monomer having one radical-polymerizable double bond in the molecule, in an amount less than 70% by weight based on the total amount of the ingredients (a), (b), and (c); (c) a polyfunctional monomer having at least two radical-polymerizable double bonds in the molecule, in an amount of from 0.01 to 40% by weight based on the total amount of the ingredients (a), (b), and (c); (d) a resin component soluble in a mixture of the ingredients (a), (b), and (c), in an amount of from 3 to 100 parts by weight per 100 parts by weight of the total amount of the ingredients (a), (b), and (c); and (e) a free-radical polymerization initiator in an amount of from 0.001 to 5 parts by weight per 100 parts by weight of the total amount of the ingredients (a), (b), (c), and (d).
    • 一种苯乙烯树脂组合物,其包含交联苯乙烯树脂并均匀分散有能够用有机溶剂萃取的未交联树脂,未交联树脂的量为组合物总量的3至50重量%; 以及制造苯乙烯树脂组合物的成型体的方法,该方法包括以下步骤:将液体混合物进行浇注聚合,所述液体混合物包含:(a)苯乙烯单体的量为30重量%以上 成分(a),(b)和(c); (b)基于成分(a),(b)和(c)的总量,分子中具有一个可自由基聚合的双键的单官能单体的量小于70重量%。 (c)基于成分(a),(b)和(c)的总量,分子中具有至少两个可自由基聚合的双键的多官能单体的量为0.01至40重量% ; (d)可溶于成分(a),(b)和(c)的混合物中的树脂组分的量为每100重量份组分总量3至100重量份( a),(b)和(c); 和(e)每100重量份组分(a),(b),(c)和(d)的总量为0.001-5重量份的自由基聚合引发剂。