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    • 2. 发明授权
    • Tantalum carbide nitride materials by vapor deposition processes
    • 通过气相沉积工艺生产氮化钽材料
    • US07678298B2
    • 2010-03-16
    • US11860952
    • 2007-09-25
    • Kavita ShahHaichun YangSchubert S. Chu
    • Kavita ShahHaichun YangSchubert S. Chu
    • C23C16/00
    • C23C16/36C04B35/58007C04B35/6325H01L21/28202H01L21/28556H01L21/28562H01L21/76843H01L29/518H01L29/78
    • Embodiments of the invention generally provide compositions of tantalum carbide nitride materials. In one embodiment, a composition of a tantalum carbide nitride material is provided which includes the chemical formula of TaCxNy, wherein x is within a range from about 0.20 to about 0.50 and y is within a range from about 0.20 to about 0.55, an interstitial/elemental carbon atomic ratio of about 2 or greater, and a crystalline structure. In some examples, the composition provides that x is within a range from about 0.25 to about 0.40, preferably, from about 0.30 to about 0.40, and y is within a range from about 0.30 to about 0.50, preferably, from about 0.35 to about 0.50. The interstitial/elemental carbon atomic ratio may be about 3, about 4, or greater. The composition further may have a sheet resistance within a range from about 1×104 Ω/sq to about 1×106 Ω/sq.
    • 本发明的实施方案通常提供碳化钽氮化物材料的组合物。 在一个实施方案中,提供了包含化学式TaC x N y的化合物碳氮化物材料的组合物,其中x在约0.20至约0.50的范围内,y在约0.20至约0.55的范围内,间隙/ 元素碳原子比为约2或更大,以及晶体结构。 在一些实例中,组合物提供x在约0.25至约0.40,优选约0.30至约0.40的范围内,y在约0.30至约0.50,优选约0.35至约0.50的范围内 。 间隙/元素碳原子比可以是约3,约4或更大。 该组合物还可以具有在约1×10 4Ω·cm-1至约1×10 6Ω·cm·cm 2的范围内的薄层电阻。
    • 3. 发明授权
    • Vapor deposition processes for tantalum carbide nitride materials
    • 碳化钽氮化物材料的气相沉积工艺
    • US07585762B2
    • 2009-09-08
    • US11860945
    • 2007-09-25
    • Kavita ShahHaichun YangSchubert S. Chu
    • Kavita ShahHaichun YangSchubert S. Chu
    • H01L21/4763
    • H01L21/76843C23C16/36C23C16/45525C23C16/45542H01L21/28556H01L21/28562
    • Embodiments of the invention generally provide methods for depositing and compositions of tantalum carbide nitride materials. The methods include deposition processes that form predetermined compositions of the tantalum carbide nitride material by controlling the deposition temperature and the flow rate of a nitrogen-containing gas during a vapor deposition process, including thermal decomposition, CVD, pulsed-CVD, or ALD. In one embodiment, a method for forming a tantalum-containing material on a substrate is provided which includes heating the substrate to a temperature within a process chamber, and exposing the substrate to a nitrogen-containing gas and a process gas containing a tantalum precursor gas while depositing a tantalum carbide nitride material on the substrate. The method further provides that the tantalum carbide nitride material is crystalline and contains interstitial carbon and elemental carbon having an interstitial/elemental carbon atomic ratio of greater than 1, such as about 2, 3, 4, or greater.
    • 本发明的实施方案通常提供了用于沉积碳化钽和氮化钽材料的组合物的方法。 这些方法包括通过控制包括热分解,CVD,脉冲CVD或ALD在内的气相沉积工艺中的含氮气体的沉积温度和流速来形成碳化钽氮化物材料的预定组成的沉积工艺。 在一个实施例中,提供了一种在衬底上形成含钽材料的方法,其包括将衬底加热到​​处理室内的温度,并将衬底暴露于含氮气体和含有钽前体气体的工艺气体 同时在衬底上沉积碳化钽氮化物材料。 该方法进一步提供了碳化钽氮化物材料是结晶的并且含有间隙碳和元素间碳/元素碳原子比大于1,例如约2,3,4或更大的元素碳。
    • 8. 发明申请
    • TANTALUM CARBIDE NITRIDE MATERIALS BY VAPOR DEPOSITION PROCESSES
    • 通过蒸发沉积工艺制备碳化钨纳米材料
    • US20090078916A1
    • 2009-03-26
    • US11860952
    • 2007-09-25
    • KAVITA SHAHHaichun YangSchubert S. Chu
    • KAVITA SHAHHaichun YangSchubert S. Chu
    • H01B1/04
    • C23C16/36C04B35/58007C04B35/6325H01L21/28202H01L21/28556H01L21/28562H01L21/76843H01L29/518H01L29/78
    • Embodiments of the invention generally provide compositions of tantalum carbide nitride materials. In one embodiment, a composition of a tantalum carbide nitride material is provided which includes the chemical formula of TaCxNy, wherein x is within a range from about 0.20 to about 0.50 and y is within a range from about 0.20 to about 0.55, an interstitial/elemental carbon atomic ratio of about 2 or greater, and a crystalline structure. In some examples, the composition provides that x is within a range from about 0.25 to about 0.40, preferably, from about 0.30 to about 0.40, and y is within a range from about 0.30 to about 0.50, preferably, from about 0.35 to about 0.50. The interstitial/elemental carbon atomic ratio may be about 3, about 4, or greater. The composition further may have a sheet resistance within a range from about 1×104 Ω/sq to about 1×106 Ω/sq.
    • 本发明的实施方案通常提供碳化钽氮化物材料的组合物。 在一个实施方案中,提供了包含化学式TaC x N y的化合物碳氮化物材料的组合物,其中x在约0.20至约0.50的范围内,y在约0.20至约0.55的范围内,间隙/ 元素碳原子比为约2或更大,以及晶体结构。 在一些实例中,组合物提供x在约0.25至约0.40,优选约0.30至约0.40的范围内,y在约0.30至约0.50,优选约0.35至约0.50的范围内 。 间隙/元素碳原子比可以是约3,约4或更大。 组合物还可以具有在约1×10 4Ω/ sq至约1×10 6Ω/ sq的范围内的薄层电阻。