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1. 发明申请

WO2009050683A3 POLYCARBONATE RESINS METHOD OF MANUFACTURE, AND ARTICLES FORMED THEREFROM 审中-公开
标题翻译：聚碳酸酯树脂制造方法和由其制成的制品
公开(公告)号：WO2009050683A3
公开(公告)日：2009-08-06
申请号：PCT/IB2008054287
申请日：2008-10-17
申请人： SABIC INNOVATIVE PLASTICS I P , BRACK HANS-PETER , LOOIJ HANS , WILLEMSE DENNIS JAMES PATRICK , VERMEULEN HAN , KAMPS JAN HENK , JANSEN BERNARDUS JOHANNES PAUL
发明人： BRACK HANS-PETER , LOOIJ HANS , WILLEMSE DENNIS JAMES PATRICK MARIA , VERMEULEN HAN , KAMPS JAN HENK , JANSEN BERNARDUS JOHANNES PAULUS
IPC分类号： C08G64/02 , C08G64/04 , C08G64/16
CPC分类号： C08G64/0291 , C08G63/64 , C08G64/045 , C08G64/1691
摘要： Disclosed herein is a polycarbonate comprising a terminal olefin group of the formula (I) wherein R 1 is a C 1 -C 40 hydrocarbon that can be unsubstituted or substituted with a halogen, olefin, ether, ketone, or C 4 -C 30 polyoxyalkylene functionality in which the alkylene groups contain 2 to 6 carbon atoms, R 2 to R 4 are each independently a hydrogen or a C 1 -C 40 hydrocarbon that can be unsubstituted or substituted with a halogen, olefin, ether, ketone, or a C 4 -C 30 polyoxyalkylene functionality in which the alkylene groups contain 2 to 6 carbon atoms, and optionally wherein any two of R 1 to R 4 together form a monocyclic, bicyclic, or tricyclic ring system optionally substituted with a heteroatom in each ring.
摘要翻译：本文公开的是包含式（I）的端烯烃基团的聚碳酸酯，其中R 1是可以未被取代或被卤素，烯烃，醚，酮或C 4 -C 30聚氧化烯取代的C 1 -C 40烃其中亚烷基含有2至6个碳原子的官能度，R 2至R 4各自独立地为氢或可以未被取代或被卤素，烯烃，醚，酮或C取代的C 1 -C 40烃其中亚烷基含有2至6个碳原子的4至30个聚氧化亚烷基官能团，并且任选地其中任何两个R 1至R 4一起形成任选地在每个环中被杂原子取代的单环，二环或三环环系。

2. 发明申请

WO2008051849B1 TERT-BUTYLHYDROQUINONE POLYCARBONATES 审中-公开
标题翻译：叔丁基二氢呋喃聚碳酸酯
公开(公告)号：WO2008051849B1
公开(公告)日：2008-06-26
申请号：PCT/US2007081958
申请日：2007-10-19
申请人： SABIC INNOVATIVE PLASTICS IP , KAMPS JAN HENK , KUNG EDWARD , MULLEN BRIAN
发明人： KAMPS JAN HENK , KUNG EDWARD , MULLEN BRIAN
IPC分类号： C08G64/04 , C08G64/30
CPC分类号： C08G64/307 , C08G64/04
摘要： The present invention relates to polycarbonate having repeat units derived from tert-butylhydroquinone (TBHQ). It has herein been found that polycarbonate having repeat units derived from TBHQ has superior properties as compared to polycarbonate having repeat units derived from other dihydroxy (hydroquinone-type) compounds. In one embodiment the present invention provides a polycarbonate having repeat units derived from tert-butylhydroquinone. The polycarbonate has a Mw (PC) of at least 9,000 g/mol.
摘要翻译：本发明涉及具有衍生自叔丁基氢醌（TBHQ）的重复单元的聚碳酸酯。本发明已经发现，与具有衍生自其它二羟基（氢醌型）化合物的重复单元的聚碳酸酯相比，具有衍生自TBHQ的重复单元的聚碳酸酯具有优异的性能。在一个实施方案中，本发明提供了具有衍生自叔丁基氢醌的重复单元的聚碳酸酯。聚碳酸酯具有至少9,000g / mol的Mw（PC）。

3. 发明申请

WO2010058343A1 STABILIZATION OF ISOSORBIDE-BASED POLYCARBONATE 审中-公开
标题翻译：基于异硫脲的聚碳酸酯的稳定性
公开(公告)号：WO2010058343A1
公开(公告)日：2010-05-27
申请号：PCT/IB2009/055124
申请日：2009-11-17
申请人： SABIC INNOVATIVE PLASTICS IP B.V. , ASSINK, Roland , DE BROUWER, Hans , JANSEN, Bernd , KAMPS, Jan Henk , STEENDAM, Wilhelmus, Johannes, Daniel , GOEDMAKERS, Jan-Willem
发明人： ASSINK, Roland , DE BROUWER, Hans , JANSEN, Bernd , KAMPS, Jan Henk , STEENDAM, Wilhelmus, Johannes, Daniel , GOEDMAKERS, Jan-Willem
IPC分类号： C08L69/00 , C08G64/42
CPC分类号： C08J3/02 , C08G64/0208 , C08J2369/00
摘要： An isosorbide-containing polycarbonate composition is provided. The composition contains a polycarbonate having repeat units derived from isosorbide, a polycarbonate- property-modifying additive, and a pH stabilizer. When a solution containing 10 wt.% of the composition dissolved in dichloromethane is prepared the solution has a non-aqueous pH in a range of equal to or between 0.8 below and 0.5 above the pH of the dichloromethane.
摘要翻译：提供含有异山梨醇的聚碳酸酯组合物。该组合物含有具有衍生自异山梨醇，聚碳酸酯性质改性添加剂和pH稳定剂的重复单元的聚碳酸酯。当制备含有10重量％组合物溶解在二氯甲烷中的溶液时，该溶液的非水性pH值在二氯甲烷的pH值之下等于或低于0.8或低于0.5的范围内。

4. 发明申请

WO2008070214A1 LIGHT TRANSMISSIVE ARTICLES AND METHODS THEREOF 审中-公开
标题翻译：光传输文章及其方法
公开(公告)号：WO2008070214A1
公开(公告)日：2008-06-12
申请号：PCT/US2007/073423
申请日：2007-07-13
申请人： GENERAL ELECTRIC COMPANY , BODEN, Eugene, Pauling , LAWRENCE, Brian, Lee , MONTGOMERY, Steven, James , CHAKRAVARTI, Shreyas , VOLLENBERG, Peter, Hendrikus , KUNG, Edward , KAMPS, Jan, Henk , PRADA, Lina , MCDERMOTT, John, Brian , TAKEMORI, Michael, Teruki
发明人： BODEN, Eugene, Pauling , LAWRENCE, Brian, Lee , MONTGOMERY, Steven, James , CHAKRAVARTI, Shreyas , VOLLENBERG, Peter, Hendrikus , KUNG, Edward , KAMPS, Jan, Henk , PRADA, Lina , MCDERMOTT, John, Brian , TAKEMORI, Michael, Teruki
IPC分类号： G02B5/22
CPC分类号： G02B5/223 , G02B5/208
摘要： The present invention provides methods for controlling the optical properties of a light transmissive article. The method includes identifying a target window in an Abbe diagram comprising reference polymeric materials. The method further includes selecting a first polymeric material from the reference polymeric materials and compounding the first polymeric material with a stable UV chromophore to provide a first polymer composition. The method further includes transforming the first polymer composition to provide the light transmissive article, wherein the light transmissive article has an Abbe number and a refractive index which falls within the target window. Light transmissive articles prepared using the above methods are also provided.
摘要翻译：本发明提供了控制透光性物品的光学特性的方法。该方法包括在包含参考聚合材料的阿贝图中识别目标窗口。该方法还包括从参考聚合物材料中选择第一聚合物材料并将第一聚合物材料与稳定的紫外发色团混合以提供第一聚合物组合物。该方法还包括转化第一聚合物组合物以提供透光制品，其中透光制品具有落在目标窗口内的阿贝数和折射率。还提供了使用上述方法制备的透光性物品。

5. 发明申请

WO2008008599A2 GLOSSY COLORED INJECTION MOLDED ARTICLE 审中-公开
标题翻译： GLOSSY彩色注塑成型品
公开(公告)号：WO2008008599A2
公开(公告)日：2008-01-17
申请号：PCT/US2007/071557
申请日：2007-06-19
申请人： GENERAL ELECTRIC COMPANY , KAMPS, Jan, Henk , KUNG, Edward , LENS, Jan- Pleun , TAKEMORI, Michael, Teruki , VAN DE GRAMPEL, Hendrik, Theodorus
发明人： KAMPS, Jan, Henk , KUNG, Edward , LENS, Jan- Pleun , TAKEMORI, Michael, Teruki , VAN DE GRAMPEL, Hendrik, Theodorus
CPC分类号： C08G63/64 , C08G64/06 , C08K5/523 , C08L25/12 , C08L27/18 , C08L55/02 , C08L69/00 , C08L83/10 , C08L2666/02
摘要： An injection molded article comprising a polycarbonate composition. The polycarbonate composition is scratch resistant, flame retardant, has a low chlorine and bromine content and is dark colored.
摘要翻译：一种包含聚碳酸酯组合物的注塑制品。聚碳酸酯组合物具有耐划伤性，阻燃性，氯和溴含量低，呈深色。

6. 发明申请

WO2008136842A1 POLY( CARBONATE-CO-UREA) COPOLYMERS 审中-公开
标题翻译：聚（碳酸酯 - 共聚物）共聚物
公开(公告)号：WO2008136842A1
公开(公告)日：2008-11-13
申请号：PCT/US2007/074062
申请日：2007-07-23
申请人： GENERAL ELECTRIC COMPANY , KAMPS, Jan Henk , KUNG, Edward , LENS, Jan Pleun
发明人： KAMPS, Jan Henk , KUNG, Edward , LENS, Jan Pleun
IPC分类号： C08G64/12 , C08G64/02 , C08G64/16
CPC分类号： C08G64/0241 , C08G64/12 , C08G64/1641
摘要： Disclosed herein is a poly(carbonate-co-urea-co-ester) copolymer comprising incorporated urea compound, dihydroxy compound and diacid compound residues. Also disclosed herein is a poly(carbonate-co-urea) copolymer comprising incorporated urea compound and dihydroxy compound residues.
摘要翻译：本文公开了包含掺入的脲化合物，二羟基化合物和二酸化合物残基的聚（碳酸酯 - 共 - 脲 - 共 - 酯）共聚物。本文还公开了包含掺入的脲化合物和二羟基化合物残基的聚（碳酸酯 - 共 - 尿素）共聚物。

7. 发明申请

WO2008005633A1 METHOD FOR MAKING MOLDED POLYCARBONATE ARTICLES WITH IMPROVED COLOR 审中-公开
标题翻译：用于制造具有改进颜色的模制聚碳酸酯制品的方法
公开(公告)号：WO2008005633A1
公开(公告)日：2008-01-10
申请号：PCT/US2007/069924
申请日：2007-05-30
申请人： GENERAL ELECTRIC COMPANY , BERNDSEN, Sjef , BRACK, Hans-peter , JANSEN, Bernd , KAMPS, Jan, Henk , KUNG, Edward , LOWERY, Daniel , MCCLOSKEY, Patrick, Joseph , SMIGELSKI, Michael, Paul , WILLEMSE, Dennis
发明人： BERNDSEN, Sjef , BRACK, Hans-peter , JANSEN, Bernd , KAMPS, Jan, Henk , KUNG, Edward , LOWERY, Daniel , MCCLOSKEY, Patrick, Joseph , SMIGELSKI, Michael, Paul , WILLEMSE, Dennis
IPC分类号： C08G64/30 , C08G64/04 , C08K5/49
CPC分类号： C08G64/307 , C08G64/14
摘要： A method for preparing a molded article includes the steps of (a) obtaining a polycarbonate resin and (b) molding the polycarbonate resin. The polycarbonate resin is made by a transesterification reaction using an activated diaryl carbonate such that the polycarbonate is susceptible to the formation of internal ester linkages (IEL). The method occurs with the proviso that the polycarbonate resin, the molding conditions or both are selected to control the amount of IEL formed during the molding process to a level of less than 0.4 mol%.
摘要翻译：制备模塑制品的方法包括以下步骤：（a）获得聚碳酸酯树脂和（b）模塑聚碳酸酯树脂。聚碳酸酯树脂通过使用活化的碳酸二芳基酯的酯交换反应制备，使得聚碳酸酯容易形成内部酯键（IEL）。该方法发生，条件是选择聚碳酸酯树脂，成型条件或两者以控制在模制过程中形成的IEL的量至小于0.4mol％的水平。

8. 发明申请

WO2007053357A2 POLYMERS, POLYMER COMPOSITIONS AND METHOD OF PREPARATION 审中-公开
标题翻译：聚合物，聚合物组合物和制备方法
公开(公告)号：WO2007053357A2
公开(公告)日：2007-05-10
申请号：PCT/US2006/041351
申请日：2006-10-23
申请人： GENERAL ELECTRIC COMPANY , KAMPS, Jan, Henk , LENS, Jan-pleun , MAHOOD, James, A. , RADHAKRISHNA, A. S. , RAJ, Tilak, T. , SINGH, Ravindra, Vikram
发明人： KAMPS, Jan, Henk , LENS, Jan-pleun , MAHOOD, James, A. , RADHAKRISHNA, A. S. , RAJ, Tilak, T. , SINGH, Ravindra, Vikram
CPC分类号： C07C69/757 , C07C45/69 , C07C45/74 , C07C67/343 , C07C67/347 , C07C2601/14 , C08G64/14 , C07C49/223
摘要： A dihydroxy aromatic compound having a Formula (I) wherein R1 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic functionality having 1 to 10 carbons, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; R2 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; and each R3 and R4, at each occurrence, can be the same or different and are independently at each occurrence an aliphatic functionality having 1 to 10 carbons or a cycloaliphatic functionality having 3 to 10 carbons, "n" is an integer having a value 0 to 4 and "m" is an integer having a value 0 to 4. Also described herein are polymers made using the dihydroxy compounds of Formula (I), methods of making these polymers and compositions comprising these polymers.
摘要翻译：具有式（I）的二羟基芳族化合物其中R 1选自氰基官能团，硝基官能团，具有1至10个碳的脂族官能团，具有2个碳原子的脂族酯官能团至10个碳，具有4至10个碳的脂环族酯官能团和具有4至10个碳的芳族酯官能团; R2选自氰基官能团，硝基官能团，具有2至10个碳的脂族酯官能团，具有4至10个碳的脂环族酯官能团和具有4至10个碳的芳族酯官能团; 并且每个R 3和R 4在每次出现时可以相同或不同，并且在每次出现时独立地为具有1至10个碳的脂肪族官能团或具有3至10个碳的脂环族官能团，“n” 是值为0至4的整数，“m” 是具有值0至4的整数。本文还描述了使用式（I）的二羟基化合物制备的聚合物，制备这些聚合物的方法和包含这些聚合物的组合物。

9. 发明申请

WO2004041907A1 METHOD FOR MAKING COPOLYCARBONATES 审中-公开
标题翻译：制备共聚碳酸酯的方法
公开(公告)号：WO2004041907A1
公开(公告)日：2004-05-21
申请号：PCT/US2003/033716
申请日：2003-10-24
申请人： GENERAL ELECTRIC COMPANY , LENS, Jan, Pleun , KAMPS, Jan, Henk
发明人： LENS, Jan, Pleun , KAMPS, Jan, Henk
IPC分类号： C08G64/30
CPC分类号： C08G64/307 , C08G64/06
摘要： A melt polymerization method is presented which permits the efficient preparation of copolycarbonates in which one or more of the constituent dehydroxy aromatic compounds employed is relatively volatile, having a boiling point of less than about 340 °C. Relatively volatile dihydroxy aromatic compounds are illustrated by dihydroxybenzenes such as hydroquinone, methyl hydroquinone and resorcinol. Known methods for the preparation of members of this class of copolycarbonates, such as the melt reaction of bisphenol A and resorcinol diphenyl carbonate in the presence of sodium hydroxide and tetraalkylammonium salt catalyst systems, suffer losses in efficiency due to the resorcinol being entrained out of the polymerization mixture with by-product phenol. Catalyst systems including quaternary phosphonium salts are shown to have improved performance with respect to the amount of volatile dihydroxy aromatic compound actually incorporated into the product copolycarbonate.
摘要翻译：提出了熔融聚合方法，其可以有效地制备其中一种或多种所用的组分脱羟基芳族化合物相对挥发的共聚碳酸酯，其沸点低于约340℃。相对挥发性的二羟基芳族化合物由二羟基苯如氢醌，甲基氢醌和间苯二酚表示。用于制备这种类型的共聚碳酸酯的成员的已知方法，例如双酚A和间苯二酚碳酸二苯酯在氢氧化钠和四烷基铵盐催化剂体系的存在下的熔融反应，由于间苯二酚被夹带在聚合混合物与副产物苯酚。显示出包含季鏻盐的催化剂体系相对于实际掺入到产物共聚碳酸酯中的挥发性二羟基芳族化合物的量具有改进的性能。

10. 发明申请

WO2012037461A2 POLYCARBONATE GRAFT COPOLYMERS 审中-公开
标题翻译：聚碳酸酯共聚物
公开(公告)号：WO2012037461A2
公开(公告)日：2012-03-22
申请号：PCT/US2011/051940
申请日：2011-09-16
申请人： SABIC INNOVATIVE PLASTICS IP B.V. , HUANG, Rubin , VAN ZYL, Andre , LENS, Jan Pleun , HOEKS, Theodorus Lambertus , BRACK, Hans-Peter , KAMPS, Jan Henk
发明人： HUANG, Rubin , VAN ZYL, Andre , LENS, Jan Pleun , HOEKS, Theodorus Lambertus , BRACK, Hans-Peter , KAMPS, Jan Henk
IPC分类号： C08F283/02 , C08G64/04 , C08G64/18
CPC分类号： C08G64/18 , C08F283/02 , C08F285/00 , C08L51/08 , C08L69/00 , C08L33/12 , C08F220/18 , C08F226/10
摘要： Methods of forming polycarbonate graft copolymers are provided. In particular, a polycarbonate polymer or copolymer containing allyl groups provides the backbone for the graft copolymer, and pendant chains are attached to the copolymer through the allyl groups. The graft copolymers exhibit a combination of high transparency, good graft levels, good scratch resistance, and/or good anti-fog properties.
摘要翻译：提供了形成聚碳酸酯接枝共聚物的方法。特别地，含有烯丙基的聚碳酸酯聚合物或共聚物提供了接枝共聚物的主链，并且侧链通过烯丙基连接到共聚物上。接枝共聚物表现出高透明度，良好的接枝水平，良好的耐刮擦性和/或良好的防雾性能的组合。

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