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    • 2. 发明申请
    • POLYCARBONATES CONTAINING LOW LEVELS OF METHYL SALICYLATE PREPARED BY A MELT POLYMERIZATION IN A REACTIVE EXTRUDER
    • 含有反应性挤出机中熔融聚合制备的低水平甲基磺酸酯的聚碳酸酯
    • WO2007075351A3
    • 2007-09-13
    • PCT/US2006047776
    • 2006-12-14
    • GEN ELECTRICDAVIS PETERLOOIJ HANS
    • DAVIS PETERLOOIJ HANS
    • C08G64/30B29C47/60B29C47/76
    • C08G64/205B29C47/0004B29C47/0009B29C47/0021B29C47/0871B29C47/38B29C47/6025B29C47/6031B29C47/6056B29C47/76B29C47/767B29K2069/00C08G64/307
    • Polycarbonate is prepared by reactive extrusion on a reactive extruder. A method incorporates the steps of introducing a polycarbonate oligomer, an activated carbonate, and a transesterification catalyst to the extruder through a feed section. The extruder has a feed section, a polycarbonate exit section, and a reaction section between the feed section and the polycarbonate exit section. The reaction section has one or more devolatilization units, wherein each devolatilization unit incorporates an array of vent-conveying sections and conveying sections arranged in a configuration of: ( C V C )x ( V )n , and/or ( V C V )x ( C )n. (V) is a vent-conveying section, (C) is a conveying section, x is 1 or more, and n is 1 or 0. The extruder screw in the vent- conveying sections and the conveying sections in each devolatilization unit have conveying elements or conveying elements and mixing elements and no elements that create a melt seal in the devolatilization unit. The method further includes the step of extruding the reaction components at a temperature in a range between 100 °C and 500 °C, wherein during the extrusion of the reaction components, activated carbonate residue is removed through the vent-conveying sections.
    • 聚碳酸酯通过在反应性挤出机上的反应性挤出制备。 一种方法包括通过进料段将聚碳酸酯低聚物,活性碳酸酯和酯交换催化剂引入挤出机的步骤。 挤出机具有进料部分,聚碳酸酯出口部分和进料部分和聚碳酸酯出口部分之间的反应部分。 反应部分具有一个或多个脱挥发单元,其中每个脱挥发单元结合排气输送段和排列成以下结构的输送段:(CVC)x(V)n和/或(VCV)x(C) ñ。 (V)是排气输送部,(C)是输送部,x为1以上,n为1或0.排气输送部中的挤出机螺杆和各脱挥发分部的输送部具有输送 元件或输送元件和混合元件,并且没有在脱挥发单元中产生熔体密封的元件。 该方法还包括在100℃至500℃的温度范围内挤出反应组分的步骤,其中在反应组分的挤出期间,通过排气输送段除去活性碳酸盐残余物。