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    • 6. 发明授权
    • Liquid crystal alkenyl bicyclo[2.2.2]octanes and mixtures and devices containing such compounds
    • 液晶烯基双环[2.2.2]辛烷和含有这些化合物的混合物和装置
    • US06187393B1
    • 2001-02-13
    • US09269110
    • 1999-03-19
    • Warren L. DuffyStephen M KellyJohn W Goodby
    • Warren L. DuffyStephen M KellyJohn W Goodby
    • C09K1932
    • C09K19/3469C07C43/215C07C69/533C07C2602/44C07D239/34C07D319/06C09K19/321C09K19/3402C09K19/3444C09K2019/3422Y10T428/10
    • Compounds of formula (I) are provided which are particularly useful in super twisted nematic devices, where n may be 0-5; m may be 0-5; p may be 1-9; q may be 1, 1, or 2; A1, A2 are independently chosen from 1-4, -disubstituted benzene, 2,5-disubstituted pyrimidine, or 2,5-disubstituted pyridine, trans- 1,4-disubstituted cyclohexane, trans- 2,5-disubstitued dioxane. The aromatic rings may be laterally substituted with F, Cl, Br or CN; Z1 may be O, COO, OOC; Z2, Z3 are independent chosen from a direct bond, COO, OOC, C2H4, CH2O, OCH2, or -c≡c-, provided that when Z1 is O and m is 1, 3 or 5 the carbon—carbon double bond configuration is E; provided that when Z1 is O and m is 2 or 4 the carbon—carbon double bond configuration is Z; provided that when Z1 is COO or OOC and m is 0, 2 or 4 the carbon—carbon double bond configuration is E; and provided that when Z1 is COO or OOC and m is 1, 3 or 5 the carbon—carbon double bond configuration is Z.
    • 提供式(I)化合物,其特别适用于超扭曲向列装置,其中n可为0-5; m可以是0-5; p可以是1-9; q可以是1,1或2; A1,A2独立地选自1-4, - 二取代的苯,2,5-二取代的嘧啶或2,5-二取代的吡啶,反式-1,4-二取代的环己烷,反式-2,5-二取代的二恶烷。 芳环可以被F,Cl,Br或CN横向取代; Z1可以是O,COO,OOC; Z2,Z3独立地选自直接键,COO,OOC,C2H4,CH2O,OCH2或-c = c-,条件是当Z1为O且m为1,3或5时,碳 - 碳双键构型为 E; 条件是当Z1为O且m为2或4时,碳 - 碳双键构型为Z; 条件是当Z1为COO或OOC且m为0或2时,碳 - 碳双键构型为E; 并且当Z1为COO或OOC且m为1,3或5时,碳 - 碳双键构型为Z。
    • 8. 发明授权
    • Naphthyl organic compounds
    • 萘基有机化合物
    • US5496500A
    • 1996-03-05
    • US283714
    • 1994-08-01
    • Kenneth J. ToyneJohn W. GoodbyAlexander SeedGeorge W. GrayDamien G. McDonnelEdward P. RaynesSally E. DayKenneth J. HarrisonMichael Hird
    • Kenneth J. ToyneJohn W. GoodbyAlexander SeedGeorge W. GrayDamien G. McDonnelEdward P. RaynesSally E. DayKenneth J. HarrisonMichael Hird
    • C07C255/52C07C255/54C07C323/62C07C331/28C07D239/26C07D333/20C07D333/24C09K19/32C09K19/34C09K19/54C07D333/26G02F1/13
    • C07D239/26C07C255/52C07C255/54C07C323/62C07C331/28C07D333/20C07D333/24C09K19/322C09K19/3441C09K19/3458C09K19/3461C09K19/3497C09K19/544Y10T428/10
    • Liquid crystal compounds of formula (I) are described, where formula (I) is given as R.sub.1 --A--(X.sub.m --(B).sub.n --R.sub.2 where A is selected from nathyl, flourinated naphthyl, brominated naphthyl, B is selected from phenyl, methylated phenyl, brominated phenyl, fluorinated phenyl, thiophene, pyrimidine and pyridine, R.sub.1 and R.sub.2 are independently selected from alkyl, alkoxy, alkynyl, thioalkyl, Br, CN, SCN, NCS, perfluoroalkyl, perfluoroalkoxy and hydrogen, X is selected from C.tbd.C, COO and C.tbd.C, m is 0 or 1, n is 0 or 1 where m is 1 and n is 0 where m is 0; provided that where A is naphthyl, n is 1 and m is 0 then B is selected from methylated phenyl, brominated phenyl, thiophene, pyrimidine and pyridine; and further provided that where A is naphthyl, X is C.tbd.C, m is 1 and n is 1, then B is selected from thiophene, pyrimidine and pyridine. Also described are liquid crystal compounds suitable for inclusion in devices utilizing pretransitional characteristics of liquid crystalline materials in the isotropic phase and described by formula (II): R.sub.3 --J--(Y).sub.p --(Z).sub.q --R.sub. 4, where J is selected from nathyl, fluorinated naphthyl, brominated naphthyl, Z is selected from phenyl, methylated phenyl, brominated phenyl, fluorinated phenyl, thiophene, pyrimidine and pyridine, R.sub.1 and R.sub.2 are independently selected from alkyl, alkoxy, alkynyl, thioalkyl, Br, CN, SCN, NCS, perfluoroalkyl, perfluoroalkoxy and hydrogen, Y is selected from C.dbd.C, COO and C.dbd.C, p is 0 or 1, q is 0 or 1 where p is 1 and q is 0 where p is 0.
    • 描述了式(I)的液晶化合物,其中式(I)为R1-A-(Xm-(B)n-R2,其中A选自萘基,氟化萘基,溴化萘基,B选自苯基 ,甲基化苯基,溴化苯基,氟化苯基,噻吩,嘧啶和吡啶,R1和R2独立地选自烷基,烷氧基,炔基,硫代烷基,Br,CN,SCN,NCS,全氟烷基,全氟烷氧基和氢,X选自C 3,C,COO和C 3 B C,m为0或1,n为0或1,其中m为1,n为0,其中m为0;条件是其中A为萘基,n为1,m为0,B为 选自甲基化苯基,溴化苯基,噻吩,嘧啶和吡啶;并且进一步规定,其中A为萘基,X为C 3 C 10,m为1,n为1,则B为噻吩,嘧啶和吡啶。 是适于包含在利用液晶材料的预过滤特性的器件中的液晶化合物 各向同性相并由式(II)描述:R3-J-(Y)对(Z)qR 4,其中J选自萘基,氟化萘基,溴化萘基,Z选自苯基,甲基化苯基,溴化苯基 ,氟化苯基,噻吩,嘧啶和吡啶,R1和R2独立地选自烷基,烷氧基,炔基,硫代烷基,Br,CN,SCN,NCS,全氟烷基,全氟烷氧基和氢,Y选自C = C,COO和C = C,p为0或1,q为0或1,其中p为1,q为0,其中p为0。