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    • 3. 发明授权
    • Stable photographic color developing composition and method of use
    • 稳定的照相色彩显影组合物和使用方法
    • US06623915B1
    • 2003-09-23
    • US10216994
    • 2002-08-12
    • Shirleyanne E. HayeJanet M. Huston
    • Shirleyanne E. HayeJanet M. Huston
    • G03C7413
    • G03C7/413G03C5/266
    • Concentrated and working strength photographic color developing compositions are stabilized with the inclusion of a sulfur compound as a preservative for a color developing agent. The preservative can be represented by one of the following Structures I, II, III, and IV: M1S—R—CH(NH2)—COOM2   (I) M1S—R1—COOM2   (II) R2—S—S—R2   (III) R3HN—R4—SM1   (IV) wherein R is a divalent aliphatic linking group having at least 1 carbon atom in the chain, R1 is phenylene or an unsubstituted alkylene having 1 or 2 carbon atoms, R2 is a monovalent aliphatic group having at least 2 carbon atoms and comprising a —CH(NHR3)—COOM2 or —(C1-C3)alkylene-CH(NHR3)—COOM2 group, R3 is hydrogen, an alkyl group having 1 to 3 carbon atoms or phenyl, R4 is an alkylene group, a cyclohexylene group, or a phenylene group, and M1 and M2 are independently hydrogen, an alkali metal or ammonium ion or methyl group. These compositions can be used to process color photographic materials.
    • 浓缩和加工强度的照相彩色显影组合物通过包含作为彩色显影剂的防腐剂的硫化合物而被稳定。 防腐剂可以由以下结构I,II,III和IV之一表示:其中R是在链中具有至少1个碳原子的二价脂族连接基团,R 1是亚苯基或具有1或2个碳的未取代的亚烷基 原子,R2是具有至少2个碳原子并且包含-CH(NHR 3)-COOM 2或 - (C 1 -C 3)亚烷基-CH(NHR 3)-COOM 2基团的一价脂族基团,R 3是氢,具有1个 3个碳原子或苯基,R4是亚烷基,亚环己基或亚苯基,M1和M2独立地是氢,碱金属或铵离子或甲基。 这些组合物可用于处理彩色照相材料。
    • 5. 发明授权
    • Three-part concentrated photographic color developing kit and methods of use
    • 三部分集中照相彩色显影套件及其使用方法
    • US06518003B1
    • 2003-02-11
    • US09931315
    • 2001-08-16
    • Shirleyanne E. HayeJanet M. Huston
    • Shirleyanne E. HayeJanet M. Huston
    • G03E7413
    • G03C7/413G03C5/266G03C7/407
    • A three-part color developing kit includes (I) a first concentrated aqueous solution having a pH of from about 11 to about 13.5 and comprising at least 0.25 mol/l of sulfite ions, at least 2.5×10−5 mol/l of iodide ions, at least 0.05 mol/l of bromide ions, and at least 0.5 mol/l of a buffer having a pKa of from about 11 to about 13.5, (II) a second concentrated aqueous solution having a pH of from about 3 to about 6 and comprising at least 1 g/l of a vinyl pyrrolidone polymer, and at least 0.05 mol/l of an organic antioxidant, and a third concentrated aqueous solution having a pH of from about 1 to about 3 and comprising at least 0.05 mol/l of a color developing agent, and at least 0.005 mol/l of sulfite ions.
    • 三部分彩色显影试剂盒包括(I)pH为约11至约13.5并且包含至少0.25mol / l亚硫酸根离子,至少2.5×10 -5 mol / l碘离子的第一浓缩水溶液 ,至少0.05mol / l的溴离子和至少0.5mol / l的pKa为约11至约13.5的缓冲液,(II)pH为约3至约6的第二浓缩水溶液 并且包含至少1g / l的乙烯基吡咯烷酮聚合物和至少0.05mol / l的有机抗氧化剂,以及pH为约1至约3并且包含至少0.05mol / l的第三浓缩水溶液 的彩色显影剂,以及至少0.005mol / l的亚硫酸根离子。