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    • 6. 发明授权
    • Surfactant clathrates and agricultural chemical formulations thereof
    • 表面活性剂包合物及其农药组合物
    • US6051730A
    • 2000-04-18
    • US850455
    • 1997-05-05
    • Norman R. PallasJames L. Hazen
    • Norman R. PallasJames L. Hazen
    • C07F7/08C08G77/46C08K5/21C07F7/10
    • C08G77/46C07F7/0854C08K5/21Y10S424/08Y10S424/10
    • A solid, water-soluble complex comprising:a) a water-miscible polysiloxane of the formula: ##STR1## wherein n is from 2 to 6; a is from 8 to 25; and b is from 0 to 25; and the oxyalkylene groups may be random or block mixtures; y is from 0 to 5; x is from 1 to 5; and R is selected from the group consisting of hydrogen, C.sub.1- C.sub.4 alkyl, and a C.sub.1- C.sub.4, alkyl ester; or ##STR2## wherein A is a linear or branched alkyl having 6 to 30 carbon atoms; G is a glycol moiety of the formula --R' (OCH.sub.2 CH.sub.2) .sub.m OR" wherein R' is a divalent alkylene group having 2 to 6 carbon atoms; R" is selected from the group consisting of hydrogen, C.sub.1- C.sub.4 alkyl, and a C.sub.1- C.sub.4 alkyl ester; m is 8 to 100; y is 0 to 5; X is 0.1 to 2.5; and z is 0.1 to 5.0; andb) a complex-forming agent of the formula: ##STR3## wherein X is O, S, Sc, or Te. These complexes are useful useful as adjuvants for dry agricultural chemicals such as pesticides and/or fertilizers.
    • 一种固体水溶性络合物,其包含:a)下式的水混溶性聚硅氧烷:其中n为2-6; a是8到25; b为0〜25; 氧化烯基可以是无规或嵌段混合物; y为0〜5; x为1〜5; 并且R选自氢,C 1 -C 4烷基和C 1 -C 4烷基酯; 或其中A是具有6至30个碳原子的直链或支链烷基; G是式-R'(OCH 2 CH 2)m OR“的二醇部分,其中R'是具有2至6个碳原子的二价亚烷基; R“选自氢,C 1 -C 4烷基和C 1 -C 4烷基酯; m为8〜100; y为0〜5; X为0.1〜2.5; z为0.1〜5.0; 和b)下式的络合物形成剂:其中X是O,S,Sc或Te。 这些配合物可用作干农药如农药和/或肥料的佐剂。