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    • 4. 发明授权
    • Photomask blank, photomask, and method for manufacturing photomask blank
    • 光掩模坯料,光掩模以及制造光掩模坯料的方法
    • US08304147B2
    • 2012-11-06
    • US12935517
    • 2009-03-31
    • Hiroyuki IwashitaHiroaki ShishidoAtsushi KominatoMasahiro Hashimoto
    • Hiroyuki IwashitaHiroaki ShishidoAtsushi KominatoMasahiro Hashimoto
    • G03F1/20
    • G03F1/22G03F1/46G03F1/54G03F1/80H01L21/0274
    • The present invention provides a photomask blank used for producing a photomask to which an ArF excimer laser light is applied, wherein: a light-shielding film is provided on a light transmissive substrate; the light-shielding film has a laminated structure in which a back-surface antireflection layer, a light-shielding layer and a front-surface antireflection layer are laminated in this order from the side close to the light transmissive substrate; the thickness of the entire light-shielding film is 60 nm or less; the back-surface antireflection layer is made of a film containing a metal and has a first etching rate; the front-surface antireflection layer is made of a film containing a metal and has a third etching rate; the light-shielding layer is made of a film containing the same metal as that contained in the back-surface antireflection layer or the front-surface antireflection layer and has a second etching rate that is lower than the first etching rate and the third etching rate; and the thickness of the light-shielding layer is 30% or less of the thickness of the entire light-shielding film.
    • 本发明提供一种用于制造施加了ArF准分子激光的光掩模的光掩模坯料,其中:在透光基板上设置有遮光膜; 遮光膜具有层叠结构,其中背面防反射层,遮光层和前表面抗反射层从靠近透光基板的一侧依次层叠; 整个遮光膜的厚度为60nm以下; 背面抗反射层由含有金属的膜制成,具有第一蚀刻速率; 前表面抗反射层由含有金属的膜制成,具有第三蚀刻速率; 遮光层由含有与背面防反射层或前表面防反射层中所含的金属相同的金属的膜制成,并且具有比第一蚀刻速率和第三蚀刻速率低的第二蚀刻速率 ; 遮光层的厚度为整个遮光膜的厚度的30%以下。
    • 6. 发明申请
    • MASK BLANK, TRANSFER MASK, AND METHOD OF MANUFACTURING A TRANSFER MASK
    • 掩蔽层,转移掩模和制造转移掩模的方法
    • US20120100470A1
    • 2012-04-26
    • US13378739
    • 2010-06-17
    • Osamu NozawaHiroyuki IwashitaMasahiro HashimotoAtsushi Kominato
    • Osamu NozawaHiroyuki IwashitaMasahiro HashimotoAtsushi Kominato
    • G03F1/48G03F1/72G03F1/50B82Y30/00
    • G03F1/50G03F1/58G03F1/80
    • Provided is a mask blank which enables EB defect correction to be suitably applied and which further enables a reduction in the thickness of a light-shielding film. A mask blank 10 is used for producing a transfer mask adapted to be applied with ArF exposure light and has a light-shielding film 2 on a transparent substrate 1. The light-shielding film 2 has an at least two-layer structure comprising a lower layer composed mainly of a material containing a transition metal, silicon, and at least one or more elements selected from oxygen and nitrogen and an upper layer composed mainly of a material containing a transition metal, silicon, and at least one or more elements selected from oxygen and nitrogen. The ratio of the etching rate of the lower layer to that of the upper layer is 1.0 or more and 20.0 or less in etching which is carried out by supplying a fluorine-containing substance to a target portion and irradiating charged particles to the target portion.
    • 提供了能够适当地应用EB缺陷校正的掩模坯料,并且还能够减少遮光膜的厚度。 掩模坯料10用于制造适于施加ArF曝光光的转印掩模,并且在透明基板1上具有遮光膜2.遮光膜2具有至少两层结构,包括下层 主要由含有过渡金属,硅和至少一种或多种选自氧和氮的元素的材料构成的层,以及主要由含有过渡金属,硅以及至少一种或多种元素的材料组成的上层 氧气和氮气。 在通过向目标部分供给含氟物质并将带电粒子照射到目标部分进行的蚀刻中,下层的蚀刻速率与上层的蚀刻速率的比例为1.0以上且20.0以下。
    • 9. 发明申请
    • PHOTOMASK BLANK, PHOTOMASK, AND METHOD FOR MANUFACTURING PHOTOMASK BLANK
    • PHOTOMASK BLANK,PHOTOMASK和制造光电隔离层的方法
    • US20110104592A1
    • 2011-05-05
    • US12935517
    • 2009-03-31
    • Hiroyuki IwashitaHiroaki ShishidoAtsushi KominatoMasahiro Hashimoto
    • Hiroyuki IwashitaHiroaki ShishidoAtsushi KominatoMasahiro Hashimoto
    • G03F1/00
    • G03F1/22G03F1/46G03F1/54G03F1/80H01L21/0274
    • The present invention provides a photomask blank used for producing a photomask to which an ArF excimer laser light is applied, wherein: a light-shielding film is provided on a light transmissive substrate; the light-shielding film has a laminated structure in which a back-surface antireflection layer, a light-shielding layer and a front-surface antireflection layer are laminated in this order from the side close to the light transmissive substrate; the thickness of the entire light-shielding film is 60 nm or less; the back-surface antireflection layer is made of a film containing a metal and has a first etching rate; the front-surface antireflection layer is made of a film containing a metal and has a third etching rate; the light-shielding layer is made of a film containing the same metal as that contained in the back-surface antireflection layer or the front-surface antireflection layer and has a second etching rate that is lower than the first etching rate and the third etching rate; and the thickness of the light-shielding layer is 30% or less of the thickness of the entire light-shielding film.
    • 本发明提供一种用于制造施加了ArF准分子激光的光掩模的光掩模坯料,其中:在透光基板上设置有遮光膜; 遮光膜具有层叠结构,其中背面防反射层,遮光层和前表面抗反射层从靠近透光基板的一侧依次层叠; 整个遮光膜的厚度为60nm以下; 背面抗反射层由含有金属的膜制成,具有第一蚀刻速率; 前表面抗反射层由含有金属的膜制成,具有第三蚀刻速率; 遮光层由含有与背面防反射层或前表面防反射层中所含的金属相同的金属的膜制成,并且具有比第一蚀刻速率和第三蚀刻速率低的第二蚀刻速率 ; 遮光层的厚度为整个遮光膜的厚度的30%以下。