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1. 发明授权

US4233061A Novel benzenesulfonamide derivatives 失效
标题翻译：新型苯磺酰胺衍生物
公开(公告)号：US4233061A
公开(公告)日：1980-11-11
申请号：US974517
申请日：1978-12-29
申请人： Tetsuo Takematsu , Makoto Konnai , Hiroyoshi Omokawa
发明人： Tetsuo Takematsu , Makoto Konnai , Hiroyoshi Omokawa
IPC分类号： A01N41/06 , C07C311/15 , A01N9/14
CPC分类号： C07C255/00 , A01N41/06
摘要： A compound of the general formula ##STR1## wherein R.sub.0 represents an alkyl group optionally having a substituent selected from the class consisting of a cyano group, lower alkoxy groups and di-(lower alkyl)amino groups, a lower alkenyl group, or a lower alkynyl group; R.sub.1, R.sub.2 and R.sub.3, independently from each other, represent a hydrogen atom, a halogen atom, a lower alkyl group, or a lower alkoxy group; R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8, independently from each other, represent a hydrogen atom, a halogen atom, a lower alkyl group, or a lower alkoxy group; Y represents a group of the formula ##STR2## or a group of the formula ##STR3## in which one of R.sub.9 and R.sub.10 is a lower alkyl group and the other is a hydrogen atom or a lower alkyl group; with the proviso that when Y is the group ##STR4## and R.sub.0 represents an unsubstituted alkyl group, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 do not represent hydrogen atoms at the same time. The compounds of formula (I) are produced by the reaction of the corresponding benzenesulfonamide derivatives with the corresponding benzyl or benzoyl halides; the reaction of the corresponding benzenesulfonyl halides with the corresponding benzylamines or benzoyl amides; or by the alkylation, alkenylation or alkynylation of the corresponding compounds of formula (I) in which R.sub.0 is hydrogen. The compounds of formula (I) have superior selective herbicidal effects, and are useful as active ingredients of herbicides, especially those for application to aquatic rice paddies.
摘要翻译：通式（I）的化合物，其中R 0表示任选具有选自氰基，低级烷氧基和二 - （低级烷基）氨基的取代基的烷基，低级烯基，或低级炔基; R 1，R 2和R 3彼此独立地表示氢原子，卤素原子，低级烷基或低级烷氧基; R4，R5，R6，R7和R8彼此独立地表示氢原子，卤素原子，低级烷基或低级烷氧基; Y表示式为“IMAGE”的基团或其中R9和R10中的一个为低级烷基且另一个为氢原子或低级烷基的式“IMAGE”的基团; 条件是当Y为基团时，R 0表示未取代的烷基，R 4，R 5，R 6，R 7和R 8不同时表示氢原子。式（I）化合物通过相应的苯磺酰胺衍生物与相应的苄基或苯甲酰基卤化物的反应产生; 相应的苯磺酰卤与相应的苄胺或苯甲酰胺的反应; 或通过其中R 0是氢的相应的式（I）化合物的烷基化，烯基化或炔基化。式（I）的化合物具有优异的选择性除草效果，并且可用作除草剂的活性成分，特别是用于水稻的施用。

2. 发明授权

US4157257A Benzenesulfonamide derivatives 失效
标题翻译：苯磺酰胺衍生物
公开(公告)号：US4157257A
公开(公告)日：1979-06-05
申请号：US837911
申请日：1977-09-29
申请人： Tetsuo Takematsu , Makoto Konnai , Hiroyoshi Omokawa
发明人： Tetsuo Takematsu , Makoto Konnai , Hiroyoshi Omokawa
IPC分类号： A01N41/06 , C07C311/15 , A01N9/14 , C07C143/79 , C07C143/82
CPC分类号： C07C255/00 , A01N41/06
摘要： A compound of the general formula ##STR1## wherein R.sub.0 represents an alkyl group optionally having a substituent selected from the class consisting of a cyano group, lower alkoxy groups and di-(lower alkyl)amino groups, a lower alkenyl group, or a lower alkynyl group; R.sub.1, R.sub.2 and R.sub.3, independently from each other, represent a hydrogen atom, a halogen atom, a lower alkyl group, or a lower alkoxy group; R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8, independently from each other, represent a hydrogen atom, a halogen atom, a lower alkyl group, or a lower alkoxy group; Y represents a group of the formula ##STR2## or a group of the formula ##STR3## in which one of R.sub.9 and R.sub.10 is a lower alkyl group and the other is a hydrogen atom or a lower alkyl group; with the proviso that when Y is the group ##STR4## and R.sub.0 represents an unsubstituted alkyl group, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 do not represent hydrogen atoms at the same time. The compounds of formula (I) are produced by the reaction of the corresponding benzenesulfonamide derivatives with the corresponding benzyl or benzoyl halides; the reaction of the corresponding benzenesulfonyl halides with the corresponding benzylamines or benzoyl amides; or by the alkylation, alkenylation or alkynylation of the corresponding compounds of formula (I) in which R.sub.0 is hydrogen. The compounds of formula (I) have superior selective herbicidal effects, and are useful as active ingredients of herbicides, especially those for application to aquatic rice paddies.
摘要翻译：通式（I）的化合物，其中R 0表示任选具有选自氰基，低级烷氧基和二 - （低级烷基）氨基的取代基的烷基，低级烯基，或低级炔基; R 1，R 2和R 3彼此独立地表示氢原子，卤素原子，低级烷基或低级烷氧基; R4，R5，R6，R7和R8彼此独立地表示氢原子，卤素原子，低级烷基或低级烷氧基; Y表示式为“IMAGE”的基团或其中R9和R10中的一个为低级烷基且另一个为氢原子或低级烷基的式“IMAGE”的基团; 条件是当Y为基团时，R 0表示未取代的烷基，R 4，R 5，R 6，R 7和R 8不同时表示氢原子。式（I）化合物通过相应的苯磺酰胺衍生物与相应的苄基或苯甲酰基卤化物的反应产生; 相应的苯磺酰卤与相应的苄胺或苯甲酰胺的反应; 或通过其中R 0是氢的相应的式（I）化合物的烷基化，烯基化或炔基化。式（I）的化合物具有优异的选择性除草效果，并且可用作除草剂的活性成分，特别是用于水稻的施用。

3. 发明授权

US4468245A N-(2,3-Epoxypropylene)-n-aralkylsulfonamide and herbicidal compositions containing the same 失效
标题翻译： N-（2,3-环氧丙烯）-n-芳烷基磺酰胺和含有它们的除草组合物
公开(公告)号：US4468245A
公开(公告)日：1984-08-28
申请号：US449989
申请日：1982-12-15
申请人： Tetsuo Takematsu , Makoto Konnai , Hiroyoshi Omokawa , Koichi Yoneyama , Kazuyuki Ushinohama , Seiichi Suzuki
发明人： Tetsuo Takematsu , Makoto Konnai , Hiroyoshi Omokawa , Koichi Yoneyama , Kazuyuki Ushinohama , Seiichi Suzuki
IPC分类号： A01N43/20 , A01N43/40 , A01N47/06 , A01N47/20 , A01N47/22 , A01N47/30 , C07D303/36 , C07D405/12 , A01N43/36
CPC分类号： C07D405/12 , A01N43/20 , A01N43/40 , A01N47/06 , A01N47/20 , A01N47/22 , A01N47/30 , C07D303/36
摘要： An N-(2,3-epoxypropylene)-N-aralkylsulfonamide of formula (I): ##STR1## wherein R.sup.1 is an alkyl group, a haloalkyl group, an aralkyl group or an aryl group which may be substituted, R.sup.2 and R.sup.3, independently of each other, are a hydrogen atom or an alkyl group, R.sup.4 and R.sup.4', independently of each other, are a hydrogen atom, an alkyl group, an alkoxy group or a halogen atom, R.sup.5, R.sup.6 and R.sup.7, independently of each other, are a hydrogen atom, an alkyl group, a haloalkyl group or an aryl group, and n is 0 or 1.The novel compounds have excellent herbicidal effect based on the physiological selectivity between rice plant and weeds, and have low phytotoxicity against rice plant.
摘要翻译：式（I）的N-（2,3-环氧丙烯）-N-芳烷基磺酰胺：其中R1是烷基，卤代烷基，芳烷基或可被取代的芳基，R2 R 3和R 3彼此独立地为氢原子或烷基，R 4和R 4'彼此独立地为氢原子，烷基，烷氧基或卤素原子，R 5，R 6和R 7，独立地为氢原子，烷基，卤代烷基或芳基，n为0或1.该化合物基于水稻和杂草之间的生理选择性具有优异的除草效果，并且具有低的对水稻的植物毒性。

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