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1. 发明申请

US20050256256A1 Solid polymer electrolyte 失效
标题翻译：固体聚合物电解质
公开(公告)号：US20050256256A1
公开(公告)日：2005-11-17
申请号：US10523085
申请日：2003-07-23
申请人： Hiroo Muramoto , Takeshi Niitani
发明人： Hiroo Muramoto , Takeshi Niitani
IPC分类号： C08F293/00 , C08F290/06 , C08F297/00 , H01B1/06 , H01B1/12 , H01M10/0525 , H01M10/0565 , H01M10/36 , C08F118/02
CPC分类号： C08F290/062 , C08F293/005 , C08F2438/01 , H01B1/122 , H01M10/0525 , H01M10/0565 , H01M2300/0082
摘要： An object of the present invention is to provide a practical solid polymer electrolyte that exhibits excellent thermal characteristics, physical characteristics, and ionic conductivity, and in particular, to provide a completely solid electrolyte and a copolymer composition that functions as the substrate for producing such an electrolyte. A solid polymer electrolyte comprising an electrolyte salt, and a copolymer in which a block chain A containing a repeating unit represented by a formula (I) shown below, a block chain B containing a repeating unit represented by a formula (II) shown below: (wherein, R9 represents an aryl group), and a block chain C containing a repeating unit represented by a formula (III) shown below: (wherein, R13 represents an aryl group or a heteroaryl group) are arranged in the sequence B, A, C.
摘要翻译：本发明的目的是提供一种表现出优异的热特性，物理特性和离子导电性的实用固体聚合物电解质，特别是提供完全固体电解质和共同组合物，其用作制备这种电解液包含电解质盐的固体高分子电解质和含有下述式（I）表示的重复单元的嵌段链A，含有下述式（II）所示的重复单元的嵌段链B的共聚物，（其中R 9表示芳基）和含有如下所示的式（III）表示的重复单元的嵌段链C（式中，R 13表示芳基或杂芳基）以序列B，A，C排列。

2. 发明授权

US5639903A Sulfonium salt compounds and initiators of polymerization 失效
标题翻译：锍盐化合物和聚合引发剂
公开(公告)号：US5639903A
公开(公告)日：1997-06-17
申请号：US569217
申请日：1995-12-11
申请人： Eiji Takahashi , Hiroo Muramoto
发明人： Eiji Takahashi , Hiroo Muramoto
IPC分类号： C07C381/12 , C08F4/00 , C08G59/68 , C07C321/00
CPC分类号： C08F4/00 , C07C381/12 , C08G59/687
摘要： The present invention is related to sulfonium salt compounds useful as an initiator of cationic polymerization and represented by a following general formula (I): ##STR1## wherein R.sub.1 is benzyl, phenyl, etc., R.sub.2, R.sub.3 and R.sub.4 are each independently hydrogen, alkyl, etc., R.sub.5 is hydrogen, alkyl, phenyl, etc., R.sub.6 is a group represented by a formula, --(CH.sub.2).sub.m --R.sub.11 wherein R.sub.11 is COR.sub.12, COOR.sub.13, OR,.sub.14, nitrile, OCOR.sub.15 or SOR.sub.16, wherein R.sub.12, R.sub.13, R.sub.14, R.sub.15 and R.sub.16 are each independently hydrogen, alkyl or phenyl, m is 0 or 1, and X represents SbF.sub.6, AsF.sub.6, PF.sub.6 or BF.sub.4.
摘要翻译： PCT No.PCT / JP94 / 00953 Sec。 371 1995年12月11日第 102（e）日期1995年12月11日PCT提交1994年6月14日PCT公布。公开号WO94 / 29271 日期：1994年12月22日本发明涉及可用作阳离子聚合引发剂的锍盐化合物，由以下通式（I）表示：其中R 1为苄基，苯基等，R 2， R 3和R 4各自独立地为氢，烷基等，R 5为氢，烷基，苯基等，R 6为下列基团： - （CH 2）m -R 11，其中R 11为COR 12，COOR 13，OR 14 腈，OCOR15或SOR16，其中R12，R13，R14，R15和R16各自独立地为氢，烷基或苯基，m为0或1，X表示SbF6，AsF6，PF6或BF4。

3. 发明授权

US07579401B2 Solid polymer electrolyte 失效
标题翻译：固体聚合物电解质
公开(公告)号：US07579401B2
公开(公告)日：2009-08-25
申请号：US10523085
申请日：2003-07-23
申请人： Hiroo Muramoto , Takeshi Niitani
发明人： Hiroo Muramoto , Takeshi Niitani
IPC分类号： C08F118/02
CPC分类号： C08F290/062 , C08F293/005 , C08F2438/01 , H01B1/122 , H01M10/0525 , H01M10/0565 , H01M2300/0082
摘要： An object of the present invention is to provide a practical solid polymer electrolyte that exhibits excellent thermal characteristics, physical characteristics, and ionic conductivity, and in particular, to provide a completely solid electrolyte and a copolymer composition that functions as the substrate for producing such an electrolyte. A solid polymer electrolyte comprising an electrolyte salt, and a copolymer in which a block chain A containing a repeating unit represented by a formula (I) shown below, a block chain B containing a repeating unit represented by a formula (II) shown below: (wherein, R9 represents an aryl group), and a block chain C containing a repeating unit represented by a formula (III) shown below: (wherein, R13 represents an aryl group or a heteroaryl group) are arranged in the sequence B, A, C.
摘要翻译：本发明的目的是提供一种表现出优异的热特性，物理特性和离子导电性的实用固体聚合物电解质，特别是提供完全固体电解质和共同组合物，其用作制备这种电解液包含电解质盐的固体高分子电解质和含有下述式（I）表示的重复单元的嵌段链A，含有下述式（II）所示的重复单元的嵌段链B的共聚物，（其中，R9表示芳基）和含有下述式（III）表示的重复单元的嵌段链C（其中，R 13表示芳基或杂芳基）按顺序B，A ， C。

4. 发明申请

US20070040145A1 Composition for polymer solid electrolyte, polmer solid electrolyte, polymer, polymer solid electrolyte battery, ionconductive membrane, copolymer and process for producing the copolymer 有权
标题翻译：用于聚合物固体电解质，聚合物固体电解质，聚合物，聚合物固体电解质电池，离子导电膜，共聚物和用于制备共聚物的方法的组合物
公开(公告)号：US20070040145A1
公开(公告)日：2007-02-22
申请号：US10571998
申请日：2004-01-23
申请人： Hiroo Muramoto , Takeshi Nitani , Koichiro Aoyagi
发明人： Hiroo Muramoto , Takeshi Nitani , Koichiro Aoyagi
IPC分类号： H01G9/02 , H01M10/40 , C08J5/22
CPC分类号： C08J5/2231 , C08F290/062 , C08J2325/08 , H01B1/122 , H01M6/181 , H01M10/052 , H01M10/0565 , H01M2300/0082
摘要： The present invention provides a polymer solid electrolyte excellent in thermal properties, physical properties and ion conductivity and being close to practical level; especially, a totally solid electrolyte and a composition for producing the same. A composition for polymer solid electrolyte includes a copolymer having repeating units represented by Formula (I): (wherein each of R1 to R3 independently represents a hydrogen atom or a C1-C10 hydrocarbon group; R4a and R4b independently represents a hydrogen atom or a methyl group; R5 represents a hydrogen atom, a hydrocarbon group, an acyl group or a silyl group; and m is an integer of 1 to 100), and repeating units represented by Formula (II): (wherein each of R6 and R8 independently represents a hydrogen atom or a C1-C10 hydrocarbon group; R9 represents an organic group having at lease one functional group selected from the group consisting of hydroxyl group, carboxyl group, epoxy group, acid anhydride group and amino group); and an electrolyte salt.
摘要翻译：本发明提供了热性能，物理性质和离子传导性优异且接近实用水平的聚合物固体电解质; 特别是完全固体电解质及其制造用组合物。用于聚合物固体电解质的组合物包括具有由式（I）表示的重复单元的共聚物：其中R 1至R 3各自独立地表示氢原子或C 1 -C 10烃基; R 4a和R 4b独立地表示氢原子或甲基; R 5表示氢原子，烃基团，酰基或甲硅烷基; m为1至100的整数）和由式（II）表示的重复单元：其中R 6和R 8中的每一个独立地表示氢原子或C1-C10烃基; R 9表示具有至少一个选自羟基，羧基，环氧基的官能团的有机基团，酸酐基和氨基）; 和电解质盐。

5. 发明授权

US06218485B1 Process for producing narrow polydispersity alkenylphenol polymer 有权
标题翻译：制备窄多分散烯基酚聚合物的方法
公开(公告)号：US06218485B1
公开(公告)日：2001-04-17
申请号：US09556985
申请日：2000-04-24
申请人： Hiroo Muramoto , Yukikazu Nobuhara , Eiichiro Kobayashi
发明人： Hiroo Muramoto , Yukikazu Nobuhara , Eiichiro Kobayashi
IPC分类号： C08F446
CPC分类号： C08F297/02 , C08F4/48 , C08F12/04 , C08F20/18 , C08F36/04 , C08F2/001
摘要： A process for producing a monodisperse polymer which has a number-average molecular weight from 1,000 to 100,000 and a molecular weight distribution Mw (weight-average molecular weight)/Mn (number-average molecular weight)=1.00 through 1.50 is disclosed. This process comprises: homopolymerizing or random copolymerizing an anionic polymerizable compound by living anionic polymerization using an organic alkali metal and/or an alkali metal as a polymerization initiator, wherein a target molecular weight is obtained by adding the compound divided into multiple steps.
摘要翻译：公开了数均分子量为1,000〜100,000，分子量分布Mw（重均分子量）/ Mn（数均分子量）= 1.00〜1.50的单分散聚合物的制造方法。该方法包括：使用有机碱金属和/或碱金属作为聚合引发剂，通过活性阴离子聚合均匀或无规共聚阴离子聚合性化合物，其中通过加入分成多个步骤的化合物获得目标分子量。

6. 发明授权

US07678860B2 Composition for polymer solid electrolyte, polymer solid electrolyte, polymer, polymer solid electrolyte battery, ionconductive membrane, copolymer and process for producing the copolymer 有权
标题翻译：用于聚合物固体电解质，聚合物固体电解质，聚合物，聚合物固体电解质电池，离子导电膜，共聚物和用于制备共聚物的方法的组合物
公开(公告)号：US07678860B2
公开(公告)日：2010-03-16
申请号：US10571998
申请日：2004-01-23
申请人： Hiroo Muramoto , Takeshi Niitani , Koichiro Aoyagi
发明人： Hiroo Muramoto , Takeshi Niitani , Koichiro Aoyagi
IPC分类号： C08F118/02 , H01G9/02
CPC分类号： C08J5/2231 , C08F290/062 , C08J2325/08 , H01B1/122 , H01M6/181 , H01M10/052 , H01M10/0565 , H01M2300/0082
摘要： The present invention provides a polymer solid electrolyte excellent in thermal properties, physical properties and ion conductivity and being close to practical level; especially, a totally solid electrolyte and a composition for producing the same. A composition for polymer solid electrolyte includes a copolymer having repeating units represented by Formula (I): (wherein each of R1 to R3 independently represents a hydrogen atom or a C1-C10 hydrocarbon group; R4a and R4b independently represents a hydrogen atom or a methyl group; R5 represents a hydrogen atom, a hydrocarbon group, an acyl group or a silyl group; and m is an integer of 1 to 100), and repeating units represented by Formula (II): (wherein each of R6 and R8 independently represents a hydrogen atom or a C1-C10 hydrocarbon group; R9 represents an organic group having at lease one functional group selected from the group consisting of hydroxyl group, carboxyl group, epoxy group, acid anhydride group and amino group); and an electrolyte salt.
摘要翻译：本发明提供了热性能，物理性质和离子传导性优异且接近实用水平的聚合物固体电解质; 特别是完全固体电解质及其制造用组合物。用于聚合物固体电解质的组合物包括具有由式（I）表示的重复单元的共聚物：其中R 1至R 3各自独立地表示氢原子或C 1 -C 10烃基; R 4a和R 4b独立地表示氢原子或甲基基团; R 5表示氢原子，烃基，酰基或甲硅烷基; m为1〜100的整数），以及由式（II）表示的重复单元：（式中，R 6和R 8各自独立地表示氢原子或C1-C10烃基; R9表示具有至少一个选自羟基，羧基，环氧基，酸酐基和氨基的官能团的有机基团）; 和电解质盐。

7. 发明授权

US06875821B2 Process for production of partially protected poly(hydroxystyrene)s 有权
标题翻译：制备部分保护的聚（羟基苯乙烯）的方法
公开(公告)号：US06875821B2
公开(公告)日：2005-04-05
申请号：US10466390
申请日：2002-01-25
申请人： Hiroo Muramoto , Shinichi Kimizuka
发明人： Hiroo Muramoto , Shinichi Kimizuka
IPC分类号： C08F8/00 , C08F212/14
CPC分类号： C08F212/14 , C08F8/12 , C08F2800/20 , C08F12/14 , C08F297/02
摘要： A process for making poly(hydroxystyrene)s whose phenolic hydroxyl groups are partially protected by acid-decomposable or -eliminable groups, by which the degree of deblocking of the phenolic hydroxyl groups is controlled. Namely, the production of a polymer containing, in the molecule, repeating units of the general formula (IA) and those of the general formula (IB), comprising adding an acid to polymer (B) containing in the molecule repeating units of general formula (II) in an organic solvent with the molar ratio of the acid to the OR3 group being 0.0001 equivalent or above but below 0.05 equivalent, and reacting the polymer with the acid. In the general formulae, R1 is hydrogen or methyl; R2 is C1-6 alkyl; R3 is an acid-decomposable or -eliminable group; R4 is hydrogen or a group derived from R3 by decomposition with acid; and p is 0, 1, or 2, with the proviso that the IB/IA molar ratio ranges 98/2 to 30/70.
摘要翻译：一种制备其酚羟基被酸可分解或可消除的基团部分保护的聚（羟基苯乙烯）的方法，由此控制酚羟基的解封程度。即，分子中含有通式（IA）的重复单元和通式（IB）的聚合物的聚合物的制备，包括在分子中加入酸，所述聚合物（B）在分子中含有通式（II）在酸与OR 3基团的摩尔比为0.0001当量以上但低于0.05当量的有机溶剂中，并使聚合物与酸反应。在通式中，R 1是氢或甲基; R2是C1-6烷基; R3是酸可分解或可消融的基团; R4是氢或通过用酸分解衍生自R3的基团; 且p为0,1或2，条件是IB / IA摩尔比为98/2至30/70。

8. 发明授权

US5798396A Sulfonium salt-containing compounds and initiators of polymerization 失效
标题翻译：含锍盐的化合物和聚合引发剂
公开(公告)号：US5798396A
公开(公告)日：1998-08-25
申请号：US704631
申请日：1996-09-04
申请人： Eiji Takahashi , Hiroo Muramoto
发明人： Eiji Takahashi , Hiroo Muramoto
IPC分类号： C07C381/12 , C08F2/46 , C08F2/50 , C08F4/00 , C08G59/68
CPC分类号： C08G59/687 , C07C381/12 , C08F2/50
摘要： The present invention is directed to sulfonium salt-containing compounds represented by a following general formula; ##STR1## wherein R.sub.1 is alkyl containing from 1 to 18 carbon atoms, hydroxy, alkoxy containing from 1 to 18 carbon atoms, alkylcarbonyloxy containing from 1 to 18 carbon atoms or halogen, n is any of 0, 1, 2 or 3, however, each of R.sub.1 may be different from the others when n is 2 or more, R.sub.2 is alkyl containing from 1 to 6 carbon atoms, R.sub.3 and R.sub.4 are each independently hydrogen or alkyl containing from 1 to 6 carbon atoms, R.sub.5 and R.sub.6 are each independently hydrogen, alkyl containing from 1 to 6 carbon atoms, hydroxy, alkoxy containing from 1 to 6 carbon atoms, alkylcarbonyloxy containing from 1 to 18 carbon atoms or aromatic carbonyloxy, and R.sub.7 is alkyl containing from 4 to 20 carbon atoms or a group represented by a following formula; ##STR2## wherein R.sub.8 is alkyl containing from 1 to 18 carbon atoms, hydroxy, alkoxy containing from 1 to 18 carbon atoms, alkylcarbonyloxy containing from 1 to 18 carbon atoms, aromatic carbonyloxy or halogen, m is any of 0, 1, 2 or 3, however, each of R.sub.8 may be different from the others if m is 2 or more, and X is non-nucleophilic anion residue, and hardening compositions comprising said sulfonium salt-containing compounds. In particular, a hardening composition comprising the sulfonium salt-containing compound represented by the general formula �I! shown above, a sensitizer and a cationic polymerizable compound can harden in a short time under either heating or irradiation of light or the like, and therefore, said hardening composition can be suitably used for coating materials, adhesives, photoresists, etc.
摘要翻译： PCT No.PCT / JP95 / 00364 Sec。 371日期1996年9月4日 102（e）1996年9月4日PCT PCT 1995年3月7日PCT公布。 WO95 / 24387 PCT出版物日期1995年9月14日本发明涉及由以下通式表示的含锍盐的化合物。（I）其中R1是含有1至18个碳原子的烷基，羟基，含有1至18个碳原子的烷氧基，含有1至18个碳原子的烷基羰基氧基或卤素，n是0,1,2或 3，然而，当n为2以上时，R 1为含有1〜6个碳原子的烷基，R 3和R 4各自独立地为氢或含有1〜6个碳原子的烷基，R 5和 R 6各自独立地为氢，含有1至6个碳原子的烷基，羟基，含有1至6个碳原子的烷氧基，含有1至18个碳原子的烷基羰氧基或芳族羰氧基，R7为含有4至20个碳原子的烷基或由下式表示的基团：其中R8是含有1至18个碳原子的烷基，羟基，含有1至18个碳原子的烷氧基，含有1至18个碳原子的烷基羰基氧基，芳香族羰基氧基或卤素，m是0,1,2或然而，如图3所示，然而，如果m为2以上，并且X为非亲核性阴离子残基，则R8各自可以不同，以及包含所述含锍盐化合物的硬化组合物。特别地，包含上述通式[I]表示的含锍盐化合物，敏化剂和阳离子可聚合化合物的硬化组合物可以在加热或照射等下在短时间内硬化，因此所述硬化组合物可适用于涂料，粘合剂，光致抗蚀剂等。

9. 发明授权

US4031066A Flexible polybutadiene resin composition having excellent electrical properties 失效
标题翻译：具有优异电性能的柔性聚丁二烯树脂组合物
公开(公告)号：US4031066A
公开(公告)日：1977-06-21
申请号：US555143
申请日：1975-03-04
申请人： Atsushi Mori , Hiroo Muramoto
发明人： Atsushi Mori , Hiroo Muramoto
IPC分类号： C08F8/00 , C08F8/30 , C08F279/02 , C08G18/62 , C08G18/67 , C08G18/81 , C08K5/00 , C08K5/02 , C08L47/00 , C08L57/00 , C08L57/02 , C08L75/14 , C09D175/14 , H01B3/28 , H01B3/30
CPC分类号： H01B3/302 , C08F279/02 , C08G18/6208 , C08G18/671 , C08G18/81 , C08G18/8158 , C08L75/14 , H01B3/28 , H01B3/30
摘要： A flexible polybutadiene resin composition having 100 parts of (a), 5 to 120 parts of (b), and 50 to 500 parts of (c), whereA. is a thermosetting resin having a molecular weight of 500 to 100,000 and having the formula:YCH=CX--An.sub.1 --Jn.sub.2 --Gn.sub.3 --D--E--(PBd)--E--D--Gn.sub.3 ].sub.m Jn.sub.2 --An.sub.1 --CX=CHYwherein X is hydrogen, or an alkyl radical containing up to four carbon atoms; Y is selected from the group consisting of hydrogen, phenyl, and alkoxycarbonyl; A is a carboxyl, or a carbonyl group; J is an alkylene group containing less than five carbon atoms and G is selected from the group consisting of urethane, carboimino and ureylene group; E is urethare or carboimino, and can be the same or different from G; D is selected from the group consisting of alkylene, cycloalkylene, phenylene, naphthylene, pyrene, bis(phenylene)methylene and tris(phenylene)methylidyne radical in which the radical may be substituted by a lower alkyl radical); PBd is a polybutadiene or copolybutadiene or hydrogenized polybutadiene chain having a polymerization degree of from 4 to 370 and from about 50 percent to about 100 percent of 1,2-configuration; n.sub.1, n.sub.2 and n.sub.3 express 0 or 1 respectively, wherein a combination of (1) n.sub.1 is 1, n.sub.2 is 1, and n.sub.3 is 0 and (2) n.sub.1 is 1, n.sub.2 is 0 and n.sub.3 is 0 does not occur; and m expresses an integer of 1 to 3;B. is a solid plasticizer having 50.degree. to 100.degree. C of softening point, less than 50 of bromine value and 500 to 3,000 of number average molecular weight; and,C. is a vinyl monomer.
摘要翻译：具有100份（a），5至120份（b）和50至500份（c）的柔性聚丁二烯树脂组合物，其中A.是具有500至100,000的分子量的热固性树脂，并且具有式：

10. 发明授权

US4780507A Curable thermosetting cyanate ester composition 失效
标题翻译：固化性热固性氰酸酯组合物
公开(公告)号：US4780507A
公开(公告)日：1988-10-25
申请号：US939772
申请日：1986-11-14
申请人： Morio Gaku , Hidenori Kimbara , Hiroo Muramoto , Shiro Higashida , Fumio Sato
发明人： Morio Gaku , Hidenori Kimbara , Hiroo Muramoto , Shiro Higashida , Fumio Sato
IPC分类号： C08G59/12 , C08G59/40 , C08L19/00 , C08L63/00 , H05K1/03 , C08L25/10
CPC分类号： H05K1/0353 , C08G59/12 , C08G59/4014 , C08L19/006 , C08L63/00 , C08L63/10 , C08L79/06 , Y10T428/31525 , Y10T428/31529 , Y10T428/31645 , Y10T428/31692
摘要： There is disclosed a thermosetting resin composition comprising a thermosetting cyanate ester resin composition (A) and a butadiene based copolymer (B)(i) or an epoxy resin-modified butadiene based copolymer (B)(ii), in which said component (B)(i) or (B)(ii) are used for modifying said component (A), component (A) and (B) being as follows;(A) a cyanate ester thermosetting resin composition comprising a cyanate ester compound selected from the group consisting of,(i) a polyfunctional cyanate ester having at least two cyanate group in its molecule,(ii) prepolymer of the cyanate ester of (i),(iii) coprepolymer of the cyanate ester of (i) and an amine, and(iv) mixtures thereof, and optionally adding another thermosetting resin,(B)(i) a butadiene based copolymer comprising a butadienaromatic vinytl monomer copolymer having 0.5 or more functional groups selected from a group consisting of carboxyl radical, hydroxyl radical, acid anhydride radical, mercapto radical, epoxy radical and amino radical, and a melting point of 10.degree. C. or more, in which 1,2-type content in butadiene structure of copolymer chain is 50% or more,(ii) an epoxy resin-modified butadiene based copolymer comprising said butadiene based copolymer (B)(i) having a carboxyl radical modified with polyfunctional epoxy resin, and having a melting point of 10.degree. C. or more and an epoxy equivalent of 300-8,000.
摘要翻译： PCT No.PCT / JP86 / 00173 Sec。一九八六年十一月十四日 102（e）1986年11月14日PCT PCT公布1986年4月9日PCT公布。公开号WO86 / 06085 公开了包含热固性氰酸酯树脂组合物（A）和丁二烯基共聚物（B）（i）或环氧树脂改性丁二烯共聚物（B）（ii）的热固性树脂组合物，，其中所述组分（B）（i）或（B）（ii）用于改性所述组分（A），组分（A）和（B）如下：（A）氰酸酯热固性树脂组合物，其包含氰酸酯化合物，所述氰酸酯化合物选自：（i）分子中具有至少两个氰酸酯基的多官能氰酸酯，（ii）（i）的氰酸酯的预聚物，，（iii）（i）的氰酸酯与胺的共聚合物，和（iv）它们的混合物，以及任选地加入另外的热固性树脂，（B）（ⅰ）一种丁二烯基共聚物，其包含具有0.5或6的丁二烯芳族iny单体共聚物，更多选自羧基，羟基，酸酐基，巯基，环氧基和氨基的官能团，熔点为10℃以上，其中丁二烯中的1,2-型含量共聚物链的结构为50％以上，（ii）环氧树脂改性丁二烯系共聚物，其含有具有用多官能环氧树脂改性的羧基的丁二烯基共聚物（B）（i），熔点为1 0℃以上，环氧当量300〜8000。

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