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1. 发明授权

US06248707B1 Method for producing sodium percarbonate 有权
标题翻译：生产过碳酸钠的方法
公开(公告)号：US06248707B1
公开(公告)日：2001-06-19
申请号：US09331010
申请日：1999-08-13
申请人： Werner Doetsch , Manfred Mathes , Helmut Honig , Gabriele Wasem
发明人： Werner Doetsch , Manfred Mathes , Helmut Honig , Gabriele Wasem
IPC分类号： C11D3395
CPC分类号： C11D3/3942 , B01J2/00 , C01B15/103 , C11D1/04 , C11D3/128 , C11D17/065
摘要： A method for the “dry” production of sodium percarbonate (dry process), in which monohydrate crystals of sodium carbonate are reacted with a quasi-stoichiometric quantity of concentrated aqueous hydrogen peroxide solution, relative to the quantity of active oxygen required in the sodium percarbonate to be produced. This method can be combined to great advantage with subsequent compaction of the sodium percarbonate obtained. Sodium percarbonate products containing varying concentrations of active oxygen of at least 10 weight percent, particularly high active oxygen concentrations of above 14.5 weight percent, can be produced. The resulting sodium percarbonate products are distinguished in that they have remarkably advantageous dissolution rates, stabilities and compatibility with detergent bases, and are superior to conventional sodium percarbonates obtained, for example, by a crystallization process. The invention also relates to the sodium percarbonate products obtained and to detergent compositions containing such sodium percarbonate products.
摘要翻译：相对于过碳酸钠中所需的活性氧的量，将碳酸钠的一水合物晶体与准化学计算量的浓缩的过氧化氢水溶液进行“干”生产过碳酸钠（干法）的方法要生产。所得到的过碳酸钠随后的压实可以将该方法组合起来具有很大的优势。可以生产含有至少10重量％的不同浓度的活性氧的过碳酸钠产物，特别是高于14.5重量％的特别高的活性氧浓度。所得到的过碳酸钠产物的特征在于它们具有非常有利的溶解速率，稳定性和与洗涤剂碱的相容性，并且优于例如通过结晶方法获得的常规过碳酸钠。本发明还涉及所得的过碳酸钠产品和含有过碳酸钠产品的洗涤剂组合物。

2. 发明授权

US5369190A Crosslinking components for cathodically depositable paint binders 失效
标题翻译：用于阴极沉积的涂料粘合剂的交联组分
公开(公告)号：US5369190A
公开(公告)日：1994-11-29
申请号：US149783
申请日：1993-11-10
申请人： Helmut Honig , Herbert Matzer , Georg Pampouchidis , Willibald Paar
发明人： Helmut Honig , Herbert Matzer , Georg Pampouchidis , Willibald Paar
IPC分类号： C08G18/64 , C08G18/80 , C08G18/81 , C08G71/00 , C09D5/44 , C09D175/00 , C08L69/00
CPC分类号： C08G18/643 , C08G18/8058 , C08G18/8061 , C08G18/807 , C08G18/8175 , C08G71/00 , C09D5/4496 , Y10S524/901
摘要： Crosslinking components for cationic paint binders which are reaction products of hydroxyl-functional carbamate compounds with half-blocked diisocyanates are described. The carbamate compounds are reaction products of cyclic organic carbonates with aliphatic monoamines and/or diamines and/or triamines and/or tetraamines and/or alkanolamines, all such amines having primary and/or secondary amino groups. The crosslinking components produced according to the invention, in combination with resin components carrying hydroxyl groups and/or primary or secondary amino groups, preferably with those based on epoxide/amine adducts or containing similar molecular units, give binders which can be baked at temperatures of 140.degree. C. and higher.
摘要翻译：描述了作为羟基官能氨基甲酸酯化合物与半封端二异氰酸酯的反应产物的阳离子涂料粘合剂的交联组分。氨基甲酸酯化合物是环状有机碳酸酯与脂族单胺和/或二胺和/或三胺和/或四胺和/或链烷醇胺的反应产物，所有这些胺具有伯和/或仲氨基。根据本发明制备的交联组分与携带羟基和/或伯或仲氨基的树脂组分组合，优选与基于环氧化物/胺加合物或含有相似分子单元的组分，得到粘合剂，其可以在 140℃以上。

3. 发明授权

US5232680A Method for purifying hydrogen peroxide for microelectronics uses 失效
标题翻译：纯化过氧化氢用于微电子技术的方法
公开(公告)号：US5232680A
公开(公告)日：1993-08-03
申请号：US841536
申请日：1992-02-26
申请人： Helmut Honig , Siegfried Geigel
发明人： Helmut Honig , Siegfried Geigel
IPC分类号： B01J20/26 , B01D15/00 , C01B15/013
CPC分类号： C01B15/013 , B01D15/00
摘要： A method for further purifying previously distilled hydrogen peroxide for use in microelectronics in which a hydrogen peroxide starting solution purified initially by distillation is contacted, after the addition of a small amount of chelating agent, with a non-ion-exchanging polymeric adsorbent, such as a styrene-divinylbenzene copolymer, to obtain a highly purified hydrogen peroxide solution which satisfies the stringent purity requirements for use in producing 4-megabit and 16-megabit microprocessor chips.
摘要翻译：一种用于进一步纯化用于微电子学中的先前蒸馏的过氧化氢的方法，其中通过蒸馏最初纯化的过氧化氢起始溶液在加入少量螯合剂之后与非离子交换聚合物吸附剂接触，例如苯乙烯 - 二乙烯基苯共聚物，以获得满足用于生产4兆位和16兆位微处理器芯片的严格纯度要求的高度纯化的过氧化氢溶液。

4. 发明授权

US5101000A Process for the preparation of binders for cathodically depositable paints, the binders produced, and to the use thereof in paints 失效
标题翻译：用于制作阴离子涂层的粘合剂的方法，生产的粘合剂及其在涂料中的用途
公开(公告)号：US5101000A
公开(公告)日：1992-03-31
申请号：US570624
申请日：1990-08-21
申请人： Willibald Paar , Helmut Honig , Georg Pampouchidis
发明人： Willibald Paar , Helmut Honig , Georg Pampouchidis
IPC分类号： C08G59/14 , C08G59/18 , C08G59/56 , C08G59/58 , C09D5/44 , C09D163/00 , C09D171/00
CPC分类号： C08G59/56 , C08G59/184 , C08G59/58 , C09D5/4434
摘要： A process for the preparation of water-dilutable binders for cathodically depositable electrodeposition paints wherein 5 to 60 mol % of the epoxy groups of a resinous compound having at least two 1,2-epoxy groups per molecule are reacted with disecondary diamines obtained by the reaction of polypropylene glycol diglycidylethers or polypropylene glycol diacrylates with compounds containing a primary amino group is described. The binders prepared in accordance with the invention are suitable, in particular, for formulating electrodeposition paints, to provide films having a greater layer thickness under normal deposition conditions.
摘要翻译：制备用于阴极沉积的电沉积涂料的水可稀释粘合剂的方法，其中每分子具有至少两个1,2-环氧基的树脂化合物的5至60摩尔％的环氧基与通过反应获得的二中二胺反应的聚丙二醇二缩水甘油醚或聚丙二醇二丙烯酸酯与含有伯氨基的化合物进行了描述。根据本发明制备的粘合剂特别适用于配制电沉积涂料，以在正常沉积条件下提供具有更大层厚度的膜。

5. 发明授权

US4684702A Cathodically depositable synthetic resin binders and process for producing same 失效
标题翻译：阴极沉积合成树脂粘结剂及其制造方法
公开(公告)号：US4684702A
公开(公告)日：1987-08-04
申请号：US593268
申请日：1984-03-26
申请人： Willibald Paar , Georg Pampouchidis , Helmut Honig
发明人： Willibald Paar , Georg Pampouchidis , Helmut Honig
IPC分类号： C08G59/14 , C09D5/44 , C08F283/00
CPC分类号： C09D5/4457 , C08G59/1477 , C09D5/4496
摘要： Cathodically depositable self-crosslinking binders for electrodeposition having a substantially water-insoluble component which is a derivative of a dioxazolidine which carries chain-end or side-chain unsaturated double bonds are described. The binders have favorable wetting properties and emulsifying characteristics, as well as excellent film characteristics in the finished coatings.
摘要翻译：描述了具有基本上不溶于水的组分的用于电沉积的阴极沉积的自交联粘合剂，其是携带链末端或侧链不饱和双键的二恶唑烷的衍生物。粘合剂具有良好的润湿性能和乳化特性，以及成品涂层中优异的膜特性。

6. 发明授权

US4652353A Process for producing multiple-coat paint systems based on thermically polymerizable resin systems as binders and paint systems thereby produced 失效
标题翻译：用于生产基于热可聚合树脂体系的多层涂料体系作为粘合剂和由此生产的涂料体系的方法
公开(公告)号：US4652353A
公开(公告)日：1987-03-24
申请号：US695310
申请日：1985-01-28
申请人： Helmut Honig , Georg Pampouchidis
发明人： Helmut Honig , Georg Pampouchidis
IPC分类号： B05D1/36 , B05D3/00 , B05D3/02 , B05D3/06 , B05D7/00 , B05D7/16 , C09D5/44 , C25D13/08
CPC分类号： B05D3/0209 , B05D7/546 , C09D5/44 , B05D3/0254 , B05D3/067
摘要： A process for producing multiple-coat paint systems is described wherein a cathodically electro-depositable primer containing thermically polymerizable synthetic resins as the binder, immediately prior to the application of an additional coating, is irradiated with ionizing irradiation for a period of from one to 20 seconds. The irradiation for the short period of time cures the primer so that subsequent coatings applied to the primer do not detrimentally affect the primer coating or the finished paint system.
摘要翻译：本发明描述了一种生产多层涂料体系的方法，其中在施加附加涂层之前，将含有热可聚合合成树脂作为粘合剂的阴极电沉积底漆照射电离辐照1至20 秒。短时间的照射使底漆固化，使得施加到底漆上的后续涂层不会对底漆涂层或成品涂料体系产生不利影响。

7. 发明授权

US4579932A Novel cationic epoxy resin esters and process of producing same 失效
标题翻译：新型阳离子环氧树脂酯及其制备方法
公开(公告)号：US4579932A
公开(公告)日：1986-04-01
申请号：US549328
申请日：1983-11-07
申请人： Willibald Paar , Helmut Honig
发明人： Willibald Paar , Helmut Honig
IPC分类号： C08G59/00 , C08G59/14 , C08G59/16 , C08G59/17 , C09D5/03 , C09D5/44 , C09D5/46 , C09D163/00 , C08G59/20 , C08G59/40
CPC分类号： C09D5/4426
摘要： Cationic epoxy resin esters suitable as binders for stoving coating compositions, particularly for application by electrodeposition, and as mill base resins for grinding pigments and extenders; and a process for producing same is described. The resin esters are produced through reaction of a resinous compound carrying at least two 1,2-epoxy groups with carboxylic acids and, optionally, with primary and/or secondary alkyl- and/or alkanolamines. The carboxylic acid employed, totally or partially, is the reaction product of a dicarboxylic acid anhydride and a tertiary amine which has the structure - ##STR1## wherein R and R.sub.x are a hydrogen atom or an alkyl radical or an aryl radical which may be substituted, R.sub.7 is an alkyl radical, an amino-alkyl radical having the primary amino groups, if present, blocked (as a ketimine) or the moiety remaining after the reaction with an active hydrogen atom of an acrylic or methacrylic monomer monofunctional with regard to the double bond, and wherein n is 2 or 3, the quantity of basic component being chosen in order that the epoxy-free final product has an amine value of at least 35, and preferably of from 40 to 140 mg KOH/g.
摘要翻译：适用于烘烤涂料组合物的粘合剂的阳离子环氧树脂酯，特别是通过电沉积施用的阳离子环氧树脂酯，以及用于研磨颜料和增量剂的研磨基树脂; 并说明其制造方法。通过使带有至少两个1,2-环氧基的树脂化合物与羧酸和任选地与伯和/或仲烷基和/或烷醇胺反应来制备树脂酯。全部或部分使用的羧酸是具有以下结构的二羧酸酐和叔胺的反应产物 - 其中R和Rx是氢原子或可以被取代的烷基或芳基，R7是烷基，如果有氨基，如果存在的氨基 - 烷基，被封端（作为酮亚胺）或在与丙烯酸或甲基丙烯酸单体的单官能团的活性氢原子反应后残留的部分相对于双键，其中n为2或3，选择碱性组分的量，以使无环氧的最终产物的胺值至少为35，优选为40至140mg KOH / g。

8. 发明授权

US4177371A Welding machine for welding pre-weld flanges and slip-on flanges onto pipes 失效
标题翻译：用于将预焊接法兰和滑动法兰焊接到管道上的焊接机
公开(公告)号：US4177371A
公开(公告)日：1979-12-04
申请号：US787621
申请日：1977-04-14
申请人： Helmut Honig
发明人： Helmut Honig
IPC分类号： B23K9/028 , B23K31/00
CPC分类号： B23K9/028
摘要： A welding machine for welding pre-weld flanges and slip-on flanges onto pipes which includes an upper welding station and a lower welding station for respectively welding a flange onto a pipe from the outside and the inside of the pipe. Both welding stations are as a unit supported by a stand.
摘要翻译：一种用于将预焊接法兰和滑动法兰焊接到管道上的焊接机，其包括上焊接站和下焊接站，用于分别从管道的外部和内部将法兰焊接到管道上。两个焊接站都是由支架支撑的单元。

9. 发明授权

US5409972A Process for the preparation of modified aminoalkylation products and cationic paint binders made by the process 失效
标题翻译：通过该方法制备改性氨基烷基化产物和阳离子涂料粘合剂的方法
公开(公告)号：US5409972A
公开(公告)日：1995-04-25
申请号：US879427
申请日：1992-05-07
申请人： Roland Feola , Willibald Paar , Georg Pampouchidis , Johann Gmoser , Helmut Honig
发明人： Roland Feola , Willibald Paar , Georg Pampouchidis , Johann Gmoser , Helmut Honig
IPC分类号： C08G18/32 , C08G18/50 , C08G18/54 , C08G18/58 , C08G18/64 , C08G18/80 , C09D5/44 , C09D175/00 , C09D175/04 , C09D175/12 , C25D13/06 , C08K3/20
CPC分类号： C09D5/4465 , C08G18/5033 , C08G18/546 , C08G18/643 , Y10S525/901
摘要： This invention relates to a process for the preparation of self-crosslinking cationic paint binders which can be diluted with water after protonation and are based on modified aminoalkylation products of phenols; to the binders prepared by this process and to their use for formulating water-dilutable paints, in particular electrodeposition paints which can be deposited cathodically. The process is characterized in that an aminoalkylation product of a phenol containing at least one secondary amino group is reacted with epoxide compounds, and after temperature treatment, the reaction product is reacted with partly blocked isocyanate compounds. The process permits the use of blocking agents which allow stoving temperatures in the range of 130 to 150.degree. C.
摘要翻译：本发明涉及一种制备自交联阳离子涂料粘合剂的方法，其可以在质子化后用水稀释并且基于酚的改性氨基烷基化产物; 与通过该方法制备的粘合剂以及它们用于配制水可稀释涂料的用途，特别是可沉积阴极的电沉积涂料。该方法的特征在于含有至少一个仲氨基的苯酚的氨基烷基化产物与环氧化合物反应，并且在温度处理后，使反应产物与部分封端的异氰酸酯化合物反应。该方法允许使用阻挡剂，其允许烘烤温度在130至150℃的范围内。

10. 发明授权

US5264497A Crosslinking components for cathodically depositable paint binders 失效
标题翻译：用于阴极沉积的涂料粘合剂的交联组分
公开(公告)号：US5264497A
公开(公告)日：1993-11-23
申请号：US787313
申请日：1991-09-17
申请人： Helmut Honig , Herbert Matzer , Georg Pampouchidis , Willibald Paar
发明人： Helmut Honig , Herbert Matzer , Georg Pampouchidis , Willibald Paar
IPC分类号： C08G18/64 , C08G18/80 , C08G18/81 , C08G71/00 , C09D5/44 , C09D175/00 , C08F283/01 , C08F283/02 , C08F283/04
CPC分类号： C08G18/643 , C08G18/8058 , C08G18/8061 , C08G18/807 , C08G18/8175 , C08G71/00 , C09D5/4496 , Y10S524/901
摘要： Crosslinking components for cationic paint binders which are reaction products of hydroxyl-functional carbamate compounds with half-blocked diisocyanates are described. The carbamate compounds are reaction products of cyclic organic carbonates with aliphatic monoamines and/or diamines and/or triamines and/or tetraamines and/or alkanolamines, all such amines having primary and/or secondary amino groups. The crosslinking components produced according to the invention, in combination with resin components carrying hydroxyl groups and/or primary or secondary amino groups, preferably with those based on epoxide/amine adducts or containing similar molecular units, give binders which can be baked at temperatures of 140.degree. C. and higher.
摘要翻译：描述了作为羟基官能氨基甲酸酯化合物与半封端二异氰酸酯的反应产物的阳离子涂料粘合剂的交联组分。氨基甲酸酯化合物是环状有机碳酸酯与脂族单胺和/或二胺和/或三胺和/或四胺和/或链烷醇胺的反应产物，所有这些胺具有伯和/或仲氨基。根据本发明制备的交联组分与携带羟基和/或伯或仲氨基的树脂组分组合，优选与基于环氧化物/胺加合物或含有相似分子单元的组分，得到粘合剂，其可以在 140℃以上。

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