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1. 发明专利

DE636736C 未知
公开(公告)号：DE636736C
公开(公告)日：1936-10-14
申请号：DEW0092899
申请日：1933-10-14
申请人： GUSTAV GUTH , HANS GUTH
IPC分类号： A22C13/00

2. 发明申请

US20050170970A1 Oxygen sorbent compositions and methods of using same 失效
标题翻译：氧吸附剂组合物及其使用方法
公开(公告)号：US20050170970A1
公开(公告)日：2005-08-04
申请号：US11005411
申请日：2004-12-06
申请人： Martin Bulow , Jurgen Boer , Wolfgang Burckhardt , Hans Guth , Helmut Ullmann , Vladimir Vashook
发明人： Martin Bulow , Jurgen Boer , Wolfgang Burckhardt , Hans Guth , Helmut Ullmann , Vladimir Vashook
IPC分类号： C01B3/38 , C01B13/02 , H01B1/00
CPC分类号： C01B13/0255 , C01B3/382 , C01B2203/0244 , C01B2203/0844 , C01B2203/1258 , C01B2203/142 , C01B2203/82 , C01B2210/0046 , Y10S502/525
摘要： Compositions and methods useful for oxygen sorption and other uses are presented, the compositions A composite material comprising components (A) and (B), wherein component (A) is selected from crystalline ceramic materials capable of forming a stable, reversible perovskite crystal phase at elevated temperatures (T>500° C.), and combinations thereof, and component (B) comprises a metal selected from rhodium (Rh), platinum (Pt), palladium (Pd), nickel (Ni) and silver (Ag), and combinations and alloys of these metals.
摘要翻译：提供了可用于氧气吸附和其它用途的组合物和方法，组合物A包含组分（A）和（B）的复合材料，其中组分（A）选自能够形成稳定的可逆钙钛矿结晶相的结晶陶瓷材料高温（T> 500℃）及其组合，组分（B）包括选自铑（Rh），铂（Pt），钯（Pd），镍（Ni）和银（Ag）以及这些金属的组合和合金。

3. 发明授权

US4010245A Production of hydrogen fluoride and calcium sulfate 失效
标题翻译：生产氟化氢和硫酸钙
公开(公告)号：US4010245A
公开(公告)日：1977-03-01
申请号：US596050
申请日：1975-07-15
申请人： Bernhard Spreckelmeyer , Hans Guth , Werner Schabacher , Hermann Rohe
发明人： Bernhard Spreckelmeyer , Hans Guth , Werner Schabacher , Hermann Rohe
IPC分类号： C01B7/19 , C01F11/46 , C01B7/22
CPC分类号： C01B7/192 , C01F11/46
摘要： In the production of hydrofluoric acid and calcium sulfate by subjecting sulfuric acid and fluorspar to a partial preliminary reaction in a preliminary reaction zone and the reaction is completed in an after-reaction zone at a temperature from about 100.degree. to 500.degree. C, the improvement which comprises effecting the preliminary reaction by circulating preliminary reaction product through said preliminary reaction zone, adding to the circulating preliminary reaction product at spaced locations in the preliminary reaction zone sulfuric acid preheated to a temperature of about 80.degree. to 200.degree. C and fluorspar preheated to a temperature of about 400.degree. to 800.degree. C, removing from said preliminary reaction zone gaseous hydrofluoric acid and a substantially dry mixture of calcium sulfate, unreacted sulfuric acid and fluorspar, and passing said dry mixture of calcium sulfate, unreacted sulfuric acid and fluorspar to said after-reaction zone. Only some of the necessary sulfuric acid may be supplied to the preliminary reaction zone and the balance supplied to the after-reaction zone. Heating of the preliminary reaction zone can be external or materials can be added which will react exothermically, e.g. SO.sub.3 to react with water in the system, CaO to react with sulfuric acid. A suitable apparatus is provided, comprising two parallel troughs connected at their ends by overflows and with oppositely rotating screws to circulate the contents. Means are provided for introducing reactants at spaced locations and for removing a mixture of product plus unreacted starting materials.
摘要翻译：在通过在预反应区中进行硫酸和氟化物部分预反应的氢氟酸和硫酸钙的生产中，反应区域在约100-500℃的温度下在反应后区域完成，其包括通过使预反应产物循环通过所述预反应区进行预反应，将预反应区中的间隔位置加入到循环的预反应产物中，硫酸预热至约80℃至200℃的温度，并将氟石预热至约400-800℃的温度，从所述预反应区除去气态氢氟酸和基本上干燥的硫酸钙，未反应的硫酸和氟石的混合物，并将硫酸钙，未反应的硫酸和氟石的干混合物通入说后反应区。可以仅将一些必需的硫酸供应到预反应区，并将余量供给到反应后区。预反应区的加热可以是外部的，或者可以添加可以放热反应的材料，例如 SO3与体系中的水反应，CaO与硫酸反应。提供了一种合适的装置，包括两个平行的槽，它们的端部通过溢流和相对旋转的螺钉连接，以使内容物循环。提供了用于在间隔位置引入反应物并用于除去产物混合物加未反应的起始材料的方法。

4. 发明授权

US3933575A Separation of corrosive liquid mixtures 失效
标题翻译：腐蚀性液体混合物的分离
公开(公告)号：US3933575A
公开(公告)日：1976-01-20
申请号：US442937
申请日：1974-02-15
申请人： Hans Guth , Hans-Joachim Kaiser , Klaus Kleine-Weischede , Hermann Wieschen , Hans L. Kuhnlein
发明人： Hans Guth , Hans-Joachim Kaiser , Klaus Kleine-Weischede , Hermann Wieschen , Hans L. Kuhnlein
IPC分类号： B01D1/22 , B01D1/00 , B01D1/06 , B01D1/10 , B01J19/00 , C01B17/88 , B41D3/00 , C01B17/90
CPC分类号： B01D1/065 , B01D1/00 , B01D1/10 , C01B17/88 , Y10S159/13 , Y10S159/15 , Y10S159/19 , Y10S159/32
摘要： In the processing of a corrosive liquid mixture, such as 50 to 80% aqueous sulfuric acid, by its passage over one surface of a wall of inert heat resistant material, and heating the other surface of said wall, thereby to evaporate from said corrosive liquid mixture the more volatile component thereof, the improvement which comprises heating said wall by contact with an inert liquid material, and heating said inert liquid material indirectly through heat exchange with a normally solid molten material. Desirably the wall of inert material is a pipe surrounded by a molten metal in a first annular jacket and a molten salt in a second annular jacket.

5. 发明申请

US20050226798A1 Oxygen sorbent compositions and methods of using same 审中-公开
公开(公告)号：US20050226798A1
公开(公告)日：2005-10-13
申请号：US11005408
申请日：2004-12-06
申请人： Martin Bulow , Jurgen Boer , Wolfgang Burckhardt , Hans Guth , Helmut Ullmann , Vladimir Vashook
发明人： Martin Bulow , Jurgen Boer , Wolfgang Burckhardt , Hans Guth , Helmut Ullmann , Vladimir Vashook
IPC分类号： B01D53/02 , B01D53/86 , B01J23/00 , B01J23/10 , B01J23/14 , B01J23/18 , B01J23/22 , B01J23/26 , B01J23/34 , B01J23/70 , B01J23/83 , C01B3/36 , C01B13/02 , C04B35/01 , C04B35/26
CPC分类号： C04B35/01 , B01D53/02 , B01D53/864 , B01D2253/10 , B01D2255/2042 , B01D2255/2045 , B01D2255/20738 , B01D2255/20746 , B01D2255/20761 , B01D2255/402 , B01D2257/104 , B01D2257/702 , B01J23/002 , B01J23/14 , B01J23/18 , B01J23/22 , B01J23/26 , B01J23/34 , B01J23/70 , B01J23/83 , B01J2523/00 , C01B3/36 , C01B13/0262 , C01B2203/0227 , C01B2203/0244 , C01B2203/025 , C01B2210/0046 , C01B2210/0051 , C01B2210/0062 , C04B35/016 , C04B35/2633 , C04B35/2641 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3227 , C04B2235/3229 , C04B2235/3241 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/768 , B01J2523/17 , B01J2523/25 , B01J2523/36 , B01J2523/24 , B01J2523/3706 , B01J2523/842 , B01J2523/845
摘要： Compositions and methods useful for oxygen sorption and other uses are presented, the compositions being within the general formulas (1), (2), (3), and (4): AxByO3-δ, (1) AxA′x′ByB′y′O3-δ, and (2) AxA′x′A″x″ByB′y′B″y″O3-δ, (3) MOn (4) and combinations thereof, especially those where the B sites are independently selected from cations of the d block transition metals Cr, Mn, Fe, Co, Ni, and Cu. One desirable set of compositions of the invention are combinations of any one or more of the compounds of generals formulas (1), (2), or (3) with one or more compounds of the general formula (4). In combination with an active support or matrix oxide within general formulas (1), (2), and (3), stability of the binary metal oxides within general formula (4) can be enhanced, while extending the oxygen sorption/desorption capacities of the matrix oxide.

6. 发明申请

US20050176588A1 Oxygen sorbent compositions and methods of using same 审中-公开
公开(公告)号：US20050176588A1
公开(公告)日：2005-08-11
申请号：US11005422
申请日：2004-12-06
申请人： Martin Bulow , Jurgen Boer , Wolfgang Burckhardt , Hans Guth , Helmut Ullmann , Vladimir Vashook
发明人： Martin Bulow , Jurgen Boer , Wolfgang Burckhardt , Hans Guth , Helmut Ullmann , Vladimir Vashook
IPC分类号： C01B3/38 , C01B13/02 , H01B1/00
CPC分类号： C01B3/382 , C01B13/0255 , C01B2203/0244 , C01B2203/0844 , C01B2203/1258 , C01B2203/142 , C01B2203/82 , C01B2210/0046
摘要： Compositions and methods useful for oxygen sorption and other uses are presented within the general formulas (1), (2), (3), (4), (5), (6), and (7): A2BO4−δ(1) A2B2O5−δ(2) AO(ABO3−δ)n(3) AM2Cu3O7−δ(4) Bi4V2(1−x)Me2xO11−3x,(5) A′B′O3 where B′ is W or Mo;(6) A2B2O7−δ,(7) and combinations thereof, wherein: A is a cation of atoms having atomic numbers ranging from 57-71, inclusive, a cation of yttrium, cations of Groups 1 and 2 atoms, and combination thereof; B is a cation of a d-block transition metal; A′ is a cation of Na or Li; M is a metal cation selected from cations of Group 2 atoms; Me is a metal cation of Cu, Bi, and Co atoms; x ranges from 0.01 to 1.00; and δ ranges from 0.05 to 0.30. The compounds (1)-(7) may function as active supports for binary metal oxides to enhance the oxygen sorption/desorption capacity of the composites.

7. 发明授权

US4096065A Apparatus for aerobic treatment of activated sludge 失效
标题翻译：活性污泥需氧处理装置
公开(公告)号：US4096065A
公开(公告)日：1978-06-20
申请号：US742313
申请日：1976-11-15
申请人： Werner Bruch , Hans Guth , Helmut Kuhn
发明人： Werner Bruch , Hans Guth , Helmut Kuhn
IPC分类号： B03D1/14 , C02F3/12 , C02F3/26 , B01D19/00
CPC分类号： C02F3/12 , C02F3/26 , Y02W10/15
摘要： In an apparatus for the gasification of a biomass in an aqueous medium in the presence of organic substances degradable by the biomass, comprising a gasification tank, and a clearing chamber for the gasified water-containing biomass provided concentrically around the gasification tank, the gasification tank communicating with the clearing chamber through an inlet in the latter, the improvement whereinA. the gasification tank is from about 10 to 32 meters high, has a height/diameter ratio between approximately 40 and 0.2, is provided adjacent its floor with gas inlet points, and is connected via inlet pipes to at least one gas removal and flocculation cyclone;B. the same liquid level in all the clearing chambers is maintained by means of an overflow channel at about 0.1 to 2 meters below the liquid level of the gasification tank; andC. a sludge removal pipe connects each clearing chamber with a collector pipe.Advantageously the clearing chamber is funnel shaped.
摘要翻译：在用于生物质降解的有机物质存在下，在含水介质中气化生物质的装置，包括气化罐和用于气化水的生物质的清灰室，所述气化的含水生物质设置在气化罐周围，所述气化罐通过后者的入口与清灰室连通，其改进之处在于：A.气化罐的高度约为10至32米，高于40和0.2之间的高度/直径比，它们与气体入口点相邻。，并通过入口管道连接到至少一个气体去除和絮凝循环; B.所有清洁舱中的相同液位由燃油通道的液面维持在0.1至2米以下的流量通道上; 和C.一个排污管连接每个清洁室与收集管。

8. 发明授权

US4023938A Process for dehydrating gas with sulfuric acid 失效
标题翻译：用硫酸脱气的方法
公开(公告)号：US4023938A
公开(公告)日：1977-05-17
申请号：US568341
申请日：1975-04-15
申请人： Hans Guth , Gerhard Jonas , Klaus Kleine-Weischede , Hermann Wieschen , Hans-Joachim Kaiser , Karl-Heinz Dorr , Hugo Grimm
发明人： Hans Guth , Gerhard Jonas , Klaus Kleine-Weischede , Hermann Wieschen , Hans-Joachim Kaiser , Karl-Heinz Dorr , Hugo Grimm
IPC分类号： B01D53/14 , B01D53/18 , B01D53/26 , C01B17/56
CPC分类号： B01D53/263 , B01D1/007 , B01D53/14 , B01D53/1406 , B01D53/18 , C01B17/56
摘要： In the removal of water from a gas by contact with sulfuric acid, the improvement which comprises supplying the sulfuric acid in finely divided form having a surface of about 10.sup.4 to 10.sup.7 m.sup.2 /h at a concentration of about 95 to 99% and a temperature of about 35.degree. to 80.degree. C and with a contact time of about 0.2 to 2 seconds, whereby the residual moisture content of the gas is reduced to about 30 to 250 mg of H.sub.2 O/Nm.sup.3. Preferably the sulfuric acid is sprayed through a constriction into a vessel through which the gas is passed. The large sulfuric acid surface area permits high levels of dehydration to be achieved with far less sulfuric acid than heretofore believed possible and with small vessels and minimal contact times. Contact may be effected serially in several stages with the spent acids combined, brought up to initial concentration and recirculated.
摘要翻译：在通过与硫酸接触从气体除去水时，其改进包括以约95至99％的浓度提供具有约104至107m 2 / h表面的细碎形式的硫酸和温度约35℃至80℃，接触时间约0.2至2秒，从而将气体的残留水分降低至约30至250mg的H 2 O / Nm 3。优选地，硫酸通过收缩部喷射到气体通过的容器中。大的硫酸表面积允许以比迄今所认为可能的少得多的硫酸和小容器和最小的接触时间来实现高水平的脱水。接触可以在几个阶段中连续进行，废酸组合，达到初始浓度并再循环。

9. 发明授权

US4166790A Single stage process for continuous introduction of oxygen-containing gases into effluent containing activated sludge 失效
标题翻译：将含氧气体连续引入含活性污泥的废水中的单阶段方法
公开(公告)号：US4166790A
公开(公告)日：1979-09-04
申请号：US790108
申请日：1977-04-22
申请人： Marko Zlokarnik , Hans Guth , Theo Mann
发明人： Marko Zlokarnik , Hans Guth , Theo Mann
IPC分类号： B01F3/04 , B01F3/08 , B01F5/02 , B01F5/04 , C02F3/12 , C02F3/26 , F04F5/46 , C02C1/12
CPC分类号： C02F3/1294 , B01F3/0876 , B01F5/0212 , B01F5/0413 , B01F5/0428 , C02F3/26 , F04F5/46 , B01F2003/04879 , B01F2005/0446 , B01F3/04099 , Y02W10/15
摘要： A process and apparatus for the continuous introduction of air or oxygen-containing gases into an effluent containing activated sludge, the oxygen-containing gas largely being consumed by the effluent containing activated sludge in a single absorption stage, comprising introducing through a plurality of gas inlets an oxygen-containing gas into an effluent containing activated sludge which is in a basin under its own hydrostatic pressure of at least about 0.9 bar, the gas pressure of the gas introduced being about 0.01 to 0.5 bar above the hydrostatic pressure prevailing at the gas inlet, each gas inlet having a gas-swept cross-sectional area of at least about 0.01 m.sup.2 which is loaded by at least about 100 effective cubic meters of gas per square meter of cross-sectional area per hour, and the individual gas inlets being separated by a distance of at least about 0.5 meter, as measured from the middle point of a gas inlet. The gas inlets may be nozzles, ejectors or apertured plates preferably spaced equidistantly from one another and each may be supplied with propulsion liquid comprising effluent containing activated sludge. Preferred ranges from the various parameters depend upon whether the gas introduced contains more or less than 50% by volume of oxygen. Special gas injectors are also provided.
摘要翻译：一种用于将空气或含氧气体连续引入含有活性污泥的流出物的方法和装置，所述含氧气体在单一吸收阶段主要被含有活性污泥的流出物消耗，包括通过多个气体入口将含氧气体输送到含有活性污泥的流出物中，活性污泥在其本身的至少约0.9巴的静水压力下处于盆中，所引入的气体的气体压力高于气体入口处的静水压力约0.01至0.5巴每个气体入口具有至少约0.01m 2的气体扫掠横截面积，其每小时每平方米横截面面积加载至少约100个有效立方米的气体，并且各个气体入口被分离从气体入口的中点测量至少约0.5米的距离。气体入口可以是优选彼此间隔等距离地分开的喷嘴，喷射器或多孔板，并且每个可以供应包括含有活性污泥的流出物的推进液。来自各种参数的优选范围取决于引入的气体是否含有多于或少于50体积％的氧。还提供特殊气体喷射器。

10. 发明申请

US20050176589A1 Oxygen sorbent compositions and methods of using same 失效
公开(公告)号：US20050176589A1
公开(公告)日：2005-08-11
申请号：US11005579
申请日：2004-12-06
申请人： Martin Bulow , Jurgen Boer , Wolfgang Burckhardt , Hans Guth , Helmut Ullmann , Vladimir Vashook
发明人： Martin Bulow , Jurgen Boer , Wolfgang Burckhardt , Hans Guth , Helmut Ullmann , Vladimir Vashook
IPC分类号： C01B3/38 , C01B13/02 , H01B1/00
CPC分类号： C01B13/0255 , C01B3/382 , C01B2203/0244 , C01B2203/0844 , C01B2203/1258 , C01B2203/142 , C01B2203/82 , C01B2210/0046 , Y10S502/525
摘要： Composites and methods useful for oxygen sorption and other uses are presented, the composites comprising: (A) one or more crystalline ceramic oxides selected from compounds within general formula (1): AxA′x′ByB′y′O3-δ (1) and (B) one or more crystalline ceramic oxides selected from compounds within general formulas (2), (3), (4), (5), (6), (7), and (8): A2BO4-δ (2) A2B2O5-δ (3) AO(ABO3-δ)n (4) AM2Cu3O7-δ (5) Bi4V2(1-x)Me2xO11-3x, (6) A″B″O3 (7) A2B2O7-δ (8)

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