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    • 3. 发明申请
    • TITANIUM DIOXIDE COATED WITH SILICON DIOXIDE
    • 用二氧化硅涂布的二氧化钛
    • WO2004056927A3
    • 2004-08-26
    • PCT/EP0313534
    • 2003-12-02
    • DEGUSSASCHUMACHER KAIBATZ-SOHN CHRISTOPHHASENZAHL STEFFEN
    • SCHUMACHER KAIBATZ-SOHN CHRISTOPHHASENZAHL STEFFEN
    • C01G23/07C09C1/36
    • C09C1/3661C01G23/07C01P2004/03C01P2004/84C01P2006/12C01P2006/90Y10T428/2993
    • Powder consisting of particles with a core of titanium dioxide and a coating of silicon dioxide, which powder has a content of silicon dioxide of between 0.5 and 40 wt.%, a BET surface of between 5 and 300 m /g, and which consists of primary particles that have a coating of silicon dioxide and a core of titanium dioxide. The powder is produced according to a process in which a vaporisable silicon compound and a vaporisable titanium compound are mixed corresponding to the subsequently desired ratio of SiO2 and TiO2 in the product, are vaporised at temperatures of 200°C or less, and conveyed by means of an inert gas stream together with hydrogen and air or with oxygen-enriched air to the central pipe (core) of a known burner, the reaction mixture is ignited at the mouth of the burner and introduced together with secondary air, is combusted in a cooled flame pipe, following which the titanium dioxide powder coated with silicon dioxide is separated from the gaseous reaction products and if necessary is freed in moist air from adhering hydrogen chloride, the ratio of primary air to secondary air being greater than 0.3, the ratio of core hydrogen to secondary air being greater than 1, and the ratio of titanium dioxide precursor to secondary air being greater than 0.5. Sunscreen agent containing the powder in an amount of between 0.01 and 25 wt.%.
    • 由具有二氧化钛核心和二氧化硅涂层的颗粒组成的粉末,所述粉末具有0.5至40重量%的二氧化硅含量,5至300平方米/克的BET表面积和 它由具有二氧化硅涂层和二氧化钛核心的初级颗粒组成。 该粉末是按照下述方法生产的,其中将可汽化的硅化合物和可汽化的钛化合物相应于产品中随后所需的SiO 2和TiO 2的比例混合,在200℃或更低的温度下汽化,并通过装置 的惰性气流与氢气和空气或富氧空气一起加入到已知燃烧器的中心管(芯)中,反应混合物在燃烧器的口部点燃并与二次空气一起引入,在 然后将涂覆有二氧化硅的二氧化钛粉末与气态反应产物分离,并且如果需要的话,在潮湿的空气中从附着的氯化氢中释放,一次空气与二次空气的比率大于0.3, 核心氢与二次空气的摩尔比大于1,二氧化钛前体与二次空气的摩尔比大于0.5。 含有0.01至25重量%粉末的防晒剂。