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1. 发明授权

US4603048A Acid tenside-anion solution of chitosan and its use in cosmetic preparations 失效
标题翻译：壳聚糖的酸性表面活性剂 - 阴离子溶液及其在化妆品制剂中的应用
公开(公告)号：US4603048A
公开(公告)日：1986-07-29
申请号：US431573
申请日：1982-09-30
申请人： Eugen Konrad , Guenther Lang
发明人： Eugen Konrad , Guenther Lang
IPC分类号： C11D3/37 , A61K8/00 , A61K8/34 , A61K8/36 , A61K8/39 , A61K8/46 , A61K8/73 , A61Q5/00 , A61Q5/02 , A61Q5/06 , C08B37/08 , A61K7/06 , A61K7/09
CPC分类号： A61K8/39 , A61K8/736 , A61Q5/02 , A61Q5/06 , C08B37/003
摘要： Acid aqueous or aqueous-alcoholic solutions of a salt of chitosan, in which the anion of the salt is a tenside-anion of the general formula I[R--X--(CH.sub.2 CH.sub.2 O).sub.n --Y].sup..crclbar. (I)with R being C.sub.8 -C.sub.30 -alkyl or C.sub.8 -C.sub.30 -alkylene, X is O, COO, CONR' (R' is H, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -hydroxyalkyl), phenoxy, n is 1 to 100, and Y is (CH.sub.2).sub.m COO.sup..crclbar. (m is 1 to 4) or SO.sub.3.sup..crclbar., as well as cosmetic preparations with a content of these solutions. The chitosan salt solutions are obtained by dissolving chitosan in an aqueous or aqueous-alcoholic solution containing, relative to the free amino groups of the chitosan, an about equimolar amount of a tenside of the formula IIR--X--(CH.sub.2 CH.sub.2 O).sub.n --Y--H (II)in which R, X, n and Y have the above-given meanings. The chitosan salts contained in the solutions possess good film-forming characteristics of known chitosan salts, but in the presence of anionic tenside form no insoluble chitosan salts. The solutions can therefore be used as skin care, hair conditioning or hair strengthening component in cosmetic preparations, particularly also in shampoos on the basis of anionic tensides.
摘要翻译：壳聚糖盐的酸性水溶液或含水溶液，其中盐的阴离子是通式I [RX-（CH 2 CH 2 O）n Y]（ - ）（I）的表面活性剂，R为C8-C30 - 烷基或C 8 -C 30亚烷基，X是O，COO，CONR'（R'是H，C 1 -C 4 - 烷基或C 1 -C 4 - 羟烷基），苯氧基，n是1至100，Y是（CH 2） mOO（ - ）（m为1至4）或SO3（ - ），以及具有这些溶液含量的化妆品制剂。壳聚糖盐溶液是通过将壳聚糖溶解在含有相对于脱乙酰壳多糖游离氨基的水溶液或含水醇溶液中得到约等摩尔量式II RX-（CH 2 CH 2 O）n YH（II）表面活性剂在其中R，X，n和Y具有上述含义。包含在溶液中的壳聚糖盐具有已知的壳聚糖盐的良好的成膜特性，但是在阴离子表面活性剂存在下，不形成不溶性壳聚糖盐。因此，溶液可以用作化妆品制剂中的护肤品，头发调理剂或头发强化组分，特别是在阴离子表面活性剂的基础上用于洗发剂。

2. 发明授权

US6153178A Agent and process for permanent hair wave based on mercaptoacetamides 失效
标题翻译：基于巯基乙酰胺的永久性毛发的代理和工艺
公开(公告)号：US6153178A
公开(公告)日：2000-11-28
申请号：US981367
申请日：1997-12-19
申请人： Guenther Lang , Beate Dannecker , Wolfgang Hanefeld , Heiko Walther
发明人： Guenther Lang , Beate Dannecker , Wolfgang Hanefeld , Heiko Walther
IPC分类号： A61K8/00 , A61K8/46 , A61K8/49 , A61Q5/04 , C07D295/088 , C07D295/185 , A61K7/09 , A61K7/11 , A61K7/13
CPC分类号： A61Q5/04 , A61K8/4913 , A61K8/4926 , C07D295/185
摘要： The aqueous composition for permanent hair-styling has a pH of from 6.5 to 9.5 and contains from 3 to 28% by weight of a compound of formula I, ##STR1## wherein A represents --CH.sub.2 --, --C.dbd.O--, --S--, --O-- and --NR-- and R is an alkyl group having from 1 to 6 carbon atoms or a hydroxyalkyl group having from 1 to 6 carbon atoms, m is an integer from 1 to 3 and n is an integer from 0 to 3, with the proviso that n=0 only when A is methylene; water and one or more cosmetic additive ingredient selected from the group consisting of thickening agents, anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, opacifiers, alcohols, sugars, solubilizers, stabilizers, buffer substances, perfume oils, colorants, hair conditioning and hair treatment ingredients.
摘要翻译： PCT No.PCT / EP97 / 01028 Sec。 371 1997年12月19日第 102（e）1997年12月19日PCT PCT 1997年3月1日PCT公布。公开号WO97 / 41828 日期1997年11月13日永久性发型用水性组合物的pH为6.5〜9.5，含有3〜28重量％的式I化合物，其中A表示-CH 2 - ， - C = O-， -S-，-O-和-NR-，R为具有1至6个碳原子的烷基或具有1至6个碳原子的羟烷基，m为1至3的整数，n为 0至3，条件是仅当A为亚甲基时n = 0; 水和一种或多种选自增稠剂，阴离子表面活性剂，阳离子表面活性剂，两性表面活性剂，非离子表面活性剂，遮光剂，醇，糖，增溶剂，稳定剂，缓冲物质，香料油，着色剂，头发调理剂和头发处理成分。

3. 发明授权

US06482808B1 Use of reductive compounds for strengthening and improving the structure of materials containing keratin 失效
标题翻译：使用还原性化合物强化和改善含有角蛋白的材料的结构
公开(公告)号：US06482808B1
公开(公告)日：2002-11-19
申请号：US09700871
申请日：2001-01-23
申请人： Christian Springob , Manuela Javet , Ursula Hehner , Thomas Kripp , Beate Grasser , Kirstin Uhl , Guenther Lang
发明人： Christian Springob , Manuela Javet , Ursula Hehner , Thomas Kripp , Beate Grasser , Kirstin Uhl , Guenther Lang
IPC分类号： A01N5700
CPC分类号： A61K8/676 , A61Q5/00
摘要： The composition for hardening, strengthening and restructuring keratin-containing materials and/or for increasing the volume of keratin-containing fibers, such as hair, contains from 0.3 to 50.0% by weight of one or more reductones, each having a —(HO)C═C(OH)— group. The reductone ingredient is preferably ascorbic or isoascorbic acid, a salt of ascorbic or isoascorbic acid, such as an alkali metal or alkaline earth metal salt, an ester of ascorbic or isoascorbic acid, 6-O-palmitoyl ascorbate, ascorbyl phosphate, 2,3-dihydroxy-2-propenal and hydroxypropanedial. A method of treating keratin-containing materials or fibers to harden, strengthen and restructure keratin-containing materials and/or to increase the volume of the keratin-containing fibers by applying this composition and allowing it to act is described. A method of pre-treating keratin-containing material that is to be subjected to a chemical or physical treatment, such as dyeing or permanent shaping is also described.
摘要翻译：用于硬化，强化和重组含角蛋白的材料和/或用于增加含角蛋白的纤维如毛发的体积的组合物含有0.3至50.0重量％的一种或多种还原剂，每种还原剂具有 - （HO） C = C（OH） - 基。还原酮成分优选为抗坏血酸或异抗坏血酸，抗坏血酸或异抗坏血酸的盐，例如碱金属或碱土金属盐，抗坏血酸或异抗坏血酸的酯，6-O-棕榈酰抗坏血酸，抗坏血酸磷酸2,3 - 二羟基-2-丙醛和羟基丙二醛。描述了通过应用该组合物并使其起作用来治疗含角蛋白的材料或纤维来硬化，加强和重组含角蛋白的材料和/或增加含角蛋白的纤维的体积的方法。还描述了预处理待进行化学或物理处理的含角蛋白的材料如染色或永久成形的方法。

4. 发明授权

US6153196A Use of flower wax in liquid hair-treatment agents 失效
标题翻译：花蜡在液体护发剂中的使用
公开(公告)号：US6153196A
公开(公告)日：2000-11-28
申请号：US68419
申请日：1998-05-13
申请人： Thomas Kripp , Beate Krause , Guenther Lang , Wolfgang Maurer , Ingrid Toeche-Mittler
发明人： Thomas Kripp , Beate Krause , Guenther Lang , Wolfgang Maurer , Ingrid Toeche-Mittler
IPC分类号： A61K8/00 , A61K8/92 , A61K8/97 , A61Q5/00 , A61Q5/02 , A61Q5/06 , A61Q5/12 , A61Q17/04 , A61Q19/00 , A61K35/78
CPC分类号： A61Q19/00 , A61K8/922 , A61Q5/02 , A61Q5/06 , A61Q5/12 , A61Q17/04
摘要： The use of flower wax, preferably from flowers of the jasmine, the mimosa, the narcissus, the bitter orange or the wild camomile in liquid hair treatment agents, as well as liquid hair treatment agents containing flower wax.
摘要翻译： PCT No.PCT / EP97 / 05459 Sec。 371日期1998年5月13日 102（e）日期1998年5月13日PCT提交1997年10月4日PCT公布。公开号WO98 / 16188 日期1998年4月23日使用花蜡，优选来自茉莉花，含羞草，水仙，苦橙或野生甘菊的液体毛发处理剂，以及含有花蜡的液体毛发处理剂。

5. 发明申请

US20050226838A1 Hair treatment compositions containing N-hydroxy-alkyl-O-benzyl chitosans and methods of using same 审中-公开
标题翻译：包含N-羟基 - 烷基-O-苄基壳聚糖的头发处理组合物及其使用方法
公开(公告)号：US20050226838A1
公开(公告)日：2005-10-13
申请号：US11100225
申请日：2005-04-06
申请人： Thomas Krause , Jan Baumeister , Dirk Weber , Guenther Lang , Angelika Beyer , Ellen Florig , Klaus Gaenger , Hartmut Schiemann
发明人： Thomas Krause , Jan Baumeister , Dirk Weber , Guenther Lang , Angelika Beyer , Ellen Florig , Klaus Gaenger , Hartmut Schiemann
IPC分类号： A61K8/73 , A61Q5/00 , A61Q5/02 , A61Q5/06 , A61Q5/12 , A61K7/06 , A61K7/11
CPC分类号： A61K8/736 , A61Q5/02 , A61Q5/06 , A61Q5/065 , A61Q5/10 , A61Q5/12
摘要： The hair treatment composition contains preferably from 0.01 to 20 percent by weight of at least one N-hydroxyalkyl-O-benzyl chitosan and from 0.01 to 20 percent by weight of at least one other hair treatment effective ingredient. The at least one N-hydroxyalkyl-O-benzyl chitosan has at least one hydroxylalkyl group, preferably a hydroxyethyl, hydroxypropyl or hydroxybutyl group, and has from 2 to 20 carbon atoms. Various methods of treating hair with hair treatment compositions containing one or more of the N-hydroxyalkyl-O-benzyl chitosans are described.
摘要翻译：头发处理组合物优选含有0.01至20重量％的至少一种N-羟烷基-O-苄基壳聚糖和0.01至20重量％的至少一种其它头发处理有效成分。至少一种N-羟基烷基-O-苄基壳聚糖具有至少一个羟基烷基，优选羟乙基，羟丙基或羟基丁基，并且具有2至20个碳原子。描述了含有一种或多种N-羟烷基-O-苄基壳聚糖的头发处理组合物处理毛发的各种方法。

6. 发明授权

US5637295A Methods and compositions for permanent shaping of hair 失效
标题翻译：头发永久成型的方法和组合物
公开(公告)号：US5637295A
公开(公告)日：1997-06-10
申请号：US559375
申请日：1995-11-16
申请人： Guenther Lang , Kirstin Uhl , Gerhard Sendelbach , Gerhard Maresch
发明人： Guenther Lang , Kirstin Uhl , Gerhard Sendelbach , Gerhard Maresch
IPC分类号： A61K8/895 , A61K8/898 , A61Q5/04 , A61K7/09
CPC分类号： A61Q5/04 , A61K8/898
摘要： The permanent shaping composition for permanent shaping of hair includes from 2 to 25 percent by weight of a conventional keratin-reducing compound and from 0.02 to 5 percent by weight of certain diquaternary polysiloxanes. The permanent wave-pretreatment composition includes from 0.02 to 5 percent by weight of the diquaternary polysiloxanes. The permanent shaping composition advantageously includes mercaptocarbonic acid reducing agents and has a pH of from 6 to 10 and may include conventional cosmetic additives. Methods for using the permanent shaping composition and the permanent wave-pretreatment composition are described which provide a more uniform permanant wave from the hair roots to the hair tips.
摘要翻译：用于永久成型头发的永久性成形组合物包含2至25重量％的常规角蛋白减少化合物和0.02至5重量％的某些二季聚硅氧烷。永久波浪预处理组合物包含0.02至5重量％的二季聚硅氧烷。永久性成形组合物有利地包括巯基碳酸还原剂，并且pH为6至10，并且可以包括常规的化妆品添加剂。描述了使用永久成形组合物和永久性波浪预处理组合物的方法，其提供从发根到毛发尖端的更均匀的永久波。

7. 发明授权

US5503826A Hair keratin-reducing mono, di- and triglycerides of cysteine and compositions 失效
标题翻译：头发角蛋白降低的半胱氨酸和组合物的单，二和甘油三酯
公开(公告)号：US5503826A
公开(公告)日：1996-04-02
申请号：US330363
申请日：1994-10-27
申请人： Guenther Lang , Hans-Juergen Braun , Gerhard Maresch
发明人： Guenther Lang , Hans-Juergen Braun , Gerhard Maresch
IPC分类号： A61K8/00 , A61K8/44 , A61Q5/04 , C07C323/58 , A61K7/09 , A61K7/06
CPC分类号： A61Q5/04 , A61K8/447 , C07C323/58
摘要： The new keratin-reducing substances useful in compositions for permanent shaping of hair are glyceryl esters of cysteine, especially the monoglyceryl esters. As monoglyceryl esters of cysteine 2-amino-3-mercaptopropionic acid-(2',3'-dihydroxypropyl)ester and 2-amino-3-mercaptopropionic acid-(1',3'-dihydroxyisopropyl)ester are particularly preferred. A preferred embodiment of the compositions for permanent shaping of hair consists of a ready-to-use mixture of a water-free component including at least one glyceryl ester of cysteine and at least one other component which is kept physically separately from the water-free component until the mixture is prepared. The compositions also can include other conventional ingredients normally used in permanent shaping compositions such as surfactants and thickeners. The compositions have a preferred pH range of 6.0 to 8.5 and contain from 8 to 28 percent by weight of the glyceryl esters of cysteine.
摘要翻译：用于头发永久成型的组合物中的新的角蛋白还原物质是半胱氨酸的甘油酯，特别是单甘油酯。作为半胱氨酸2-甘氨酸酯，2-氨基-3-巯基丙酸 - （2'，3'-二羟基丙基）酯和2-氨基-3-巯基丙酸 - （1'，3'-二羟基异丙基）酯是特别优选的。用于永久成型头发的组合物的优选实施方案是由包含至少一种半胱氨酸甘油酯和至少一种其它成分的无水组分的即用混合物组成的物质与水分离物质分开组分直到制备混合物。组合物还可以包括通常用于永久成型组合物如表面活性剂和增稠剂的其它常规成分。组合物具有6.0至8.5的优选pH范围并且含有8至28重量％的半胱氨酸的甘油酯。

8. 发明授权

US07341715B2 Method and agents on the basis of 2-mercaptopropionic acid amides for durable hair forming and a method for producing same 有权
标题翻译：基于用于耐久发型的2-巯基丙酸酰胺的方法和试剂及其制备方法
公开(公告)号：US07341715B2
公开(公告)日：2008-03-11
申请号：US09979965
申请日：2001-05-21
申请人： Beate Dannecker , Ursus Schweizer , Guenther Lang , Regina Ortmann , Wolfgang Hanefeld
发明人： Beate Dannecker , Ursus Schweizer , Guenther Lang , Regina Ortmann , Wolfgang Hanefeld
IPC分类号： A61Q5/04 , C07D295/22 , C07D307/02 , C07D211/20 , C07D211/30
CPC分类号： A61Q5/04 , A61K8/447 , A61K8/46
摘要： The preparation for permanently deforming hair has a pH of 6.5 to 9.5 and contains, as keratin-reducing agent, a 2-mercaptopropion-amide of the formula (I): in which R1 and R2, independently of one another, represent H, a linear or branched alkylaminoalkyl group with 2 to 8 carbon atoms, or a morpholinoalkyl group with 2 to 3 carbon atoms in the alkyl portion of the morpholinoalkyl group, with the proviso that R1 and R2 are not simultaneously H, or that R1 and R2, together with the nitrogen atom, form a five-or six-membered heterocyclic ring, which optionally contain an additional N or O and are optionally substituted with one or two OH and/or methyl groups.
摘要翻译：用于永久变形毛发的制剂的pH为6.5至9.5，并且作为角蛋白还原剂包含式（I）的2-巯基丙酰胺：其中R 1和R 2 > 2 <！ - SIPO - >彼此独立地表示H，具有2至8个碳原子的直链或支链烷基氨基烷基或在吗啉代烷基的烷基部分具有2至3个碳原子的吗啉代烷基，条件是 R 1和R 2不是同时为H，或者R 1和R 2，以及R 1和R 2 氮原子形成五元或六元杂环，其任选地含有另外的N或O，并且任选被一个或两个OH和/或甲基取代。

9. 发明授权

US06399051B2 Method and agents for permanently styling hair, with a base consisting of N,N-disubstituted mercaptoacetamides 有权
标题翻译：用于永久定型毛发的方法和试剂，其中由N，N-二取代的巯基乙酰胺组成的底物
公开(公告)号：US06399051B2
公开(公告)日：2002-06-04
申请号：US09269901
申请日：1999-06-08
申请人： Beate Dannecker , Guenther Lang , Wolfgang Hanefeld , Heiko Walther
发明人： Beate Dannecker , Guenther Lang , Wolfgang Hanefeld , Heiko Walther
IPC分类号： A61K709
CPC分类号： A61Q5/04 , A61K8/46 , C07C323/60
摘要： The present invention relates to a composition and method for permanently shaping hair, in which an N,N-disubstituted mercaptoacetamide of the formula I: or a salt thereof, wherein R1 and R2 are each independently selected from the group consisting of straight-chain alkyl groups having 1 to 6 carbon atoms, branched-chain alkyl groups having 1 to 6 carbon atoms, monohydroxyalkyl groups having 1 to 6 carbon atoms, polyhydroxyalkyl groups having 1 to 6 carbon atoms and carboxyalkyl groups having 1 to 6 carbon atoms, is employed as keratin reducing agent. A process for making these mercaptoacetamides is also described as well as a novel mercaptoacetamide, N-ethyl-2′-hydroxyethyl-mercaptoacetamide. The mercaptoacetamides provide gentle and uniform shaping of hair in a pH range of 4.5 to 9.5 and do not cause allergic or sensitizing reactions.
摘要翻译：本发明涉及用于永久形成头发的组合物和方法，其中式I的N，N-二取代的巯基乙酰胺或其盐，其中R 1和R 2各自独立地选自直链烷基使用具有1至6个碳原子的基团，具有1至6个碳原子的支链烷基，具有1至6个碳原子的单羟基烷基，具有1至6个碳原子的多羟基烷基和具有1至6个碳原子的羧基烷基作为角蛋白还原剂。还描述了制备这些巯基乙酰胺的方法以及新的巯基乙酰胺，N-乙基-2'-羟乙基 - 巯基乙酰胺。巯基乙酰胺在4.5至9.5的pH范围内提供温和均匀的头发成型，并且不引起过敏或致敏反应。

10. 发明授权

US6153180A Agent and method for permanently shaping the hair, based on n-branched-chain alkyl-substituted mercapto acetamides and process for their preparation 有权
标题翻译：基于正链支链烷基取代的巯基乙酰胺永久定型毛发的剂和方法及其制备方法
公开(公告)号：US6153180A
公开(公告)日：2000-11-28
申请号：US142576
申请日：1998-09-10
申请人： Guenther Lang , Beate Dannecker , Wolfgang Hanefeld , Heiko Walther
发明人： Guenther Lang , Beate Dannecker , Wolfgang Hanefeld , Heiko Walther
IPC分类号： A61K8/00 , A61K8/44 , A61K8/46 , A61K31/16 , A61Q5/04 , A61Q5/10 , A61K7/09
CPC分类号： A61Q5/04 , A61K8/447 , A61K8/46 , A61Q5/10
摘要： The subject of the invention is an agent for the permanent shaping of hair, characterized in that it contains as active keratin-reducing substance a compound in accordance with the general formula ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 stand for H, carboxy or a straight- or branched-chain alkyl radical, monohydroxyalkyl radical or polyhydroxyalkyl radical with 1 to 6 carbon atoms respectively, on the condition thatnot all radicals R.sub.1 to R.sub.3 stand for H at the same time;if R.sub.1 and R.sub.2 stand for H, then R.sub.3 is carboxy or a branched alkyl, branched monohydroxyalkyl or branched polyhydroxyalkyl radical with 1 to 6 carbon atoms;if none of the radicals R.sub.1 to R.sub.2 stand for carboxy or have a branched alkyl, branched monohydroxyalkyl or branched polyhydroxyalkyl radical with 1 to 6 carbon atoms, then at least two of the radicals R.sub.1, R.sub.2 or R.sub.3 stand for a straight-chain alkyl, monohydroxyalkyl or polyhydroxyalkyl radical with 1 to 6 carbon atoms andif one of the radicals is carboxy, then the other two radicals are not carboxy at the same time.The agent allows for gentle, even shaping of the hair in a way that protects the skin and the hair, at a pH range of 6.5 to 9.5, without causing allergic and sensitizing reactions.
摘要翻译： PCT No.PCT / EP97 / 06860 Sec。 371日期：1998年9月10日 102（e）1998年9月10日PCT 1997年12月9日PCT PCT。第WO98 / 30197号公报日本1998年7月16日本发明的主题是头发永久成形剂，其特征在于，其含有作为活性角蛋白还原剂的化合物，其中R1，R2和R3代表H，羧基或直链或支链烷基，单羟基烷基基团或具有1至6个碳原子的多羟基烷基基团，条件是不是所有基团R 1至R 3同时代表H; 如果R1和R2代表H，则R3是羧基或具有1-6个碳原子的支链烷基，支链一羟基烷基或支链多羟基烷基; 如果基团R 1至R 2不能代表羧基或具有1至6个碳原子的支链烷基，支化单羟基烷基或支链多羟基烷基，则基团R 1，R 2或R 3中的至少两个表示直链烷基，具有1至6个碳原子的单羟基烷基或多羟基烷基，如果其中一个基团是羧基，则其它两个基团不是同时为羧基。该试剂允许以6.5至9.5的pH范围以保护皮肤和毛发的方式温和，均匀地成形，而不引起过敏和敏化反应。

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