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1. 发明专利

TW201522355A 被胺基取代之三甲矽烷基胺及三乙矽烷基胺化合物及其合成方法审中-公开
简体标题：被胺基取代之三甲硅烷基胺及三乙硅烷基胺化合物及其合成方法
公开(公告)号：TW201522355A
公开(公告)日：2015-06-16
申请号：TW103133646
申请日：2014-09-26
申请人：桑確斯安東尼奧 , SANCHEZ, ANTONIO , 吉拉德珍馬克 , GIRARD, JEAN-MARC
发明人：桑確斯安東尼奧 , SANCHEZ, ANTONIO , 吉拉德珍馬克 , GIRARD, JEAN-MARC
IPC分类号： C07F7/02 , C07F7/10
CPC分类号： C07F7/025 , C07F7/10 , H01L21/02219 , H01L21/02617
摘要：本說明書描述經由藉由過渡金屬催化劑催化的對應未經取代之三甲矽烷胺與胺之間的脫氫偶合製備之不含鹵素的被胺取代之三甲矽烷基胺及三乙矽烷基胺化合物及其製備方法。此新穎方法係基於Si-H與N-H部分之催化脫氫偶合，形成含有Si-N之化合物及氫氣。該方法可藉由諸如Ru(0)/碳、Pd(0)/MgO之過渡金屬非均相催化劑以及充當均相催化劑之過渡金屬有機金屬錯合物催化。該等含-Si-N之產物不含鹵素。該等化合物可適用於藉由化學氣相沈積或原子層沈積含Si膜來沈積薄膜。
简体摘要：本说明书描述经由借由过渡金属催化剂催化的对应未经取代之三甲硅烷胺与胺之间的脱氢偶合制备之不含卤素的被胺取代之三甲硅烷基胺及三乙硅烷基胺化合物及其制备方法。此新颖方法系基于Si-H与N-H部分之催化脱氢偶合，形成含有Si-N之化合物及氢气。该方法可借由诸如Ru(0)/碳、Pd(0)/MgO之过渡金属非均相催化剂以及充当均相催化剂之过渡金属有机金属错合物催化。该等含-Si-N之产物不含卤素。该等化合物可适用于借由化学气相沉积或原子层沉积含Si膜来沉积薄膜。

2. 发明专利

CA1307471C PROCEDE DE DESALCOOLISATION PARTIELLE OU TOTALE DU VIN ET/OU DU CIDRE ET DISPOSITIF POUR LA MISE EN OEUVRE DE CE PROCEDE 未知
公开(公告)号：CA1307471C
公开(公告)日：1992-09-15
申请号：CA525861
申请日：1986-12-19
申请人： GIRARD JEAN MARC
发明人： GIRARD JEAN-MARC , CUENAT PHILIPPE
IPC分类号： A23L2/38 , C12G3/08 , B01D61/02
摘要： Procédé de désalcoolisation partielle ou totale d'un liquide alcoolisé, notamment de vin et/ou de cidre, par osmose inverse, caractérisé en ce que l'on effectue le stockage et le traitement de ce liquide à désalcooliser dans un circuit de désalcoolisation sous une atmosphère non oxydante, en ce que l'on fait passer ce liquide dans un module d'osmose inverse, en ce que l'on compense en permanence la perte de volume due à la séparation du perméat par un apport d'eau déminéralisée totalement débarrassée de toute trace de chlore, en ce que l'on rajoute au rétentat des ingrédients naturels ou synthétiques non extraits du liquide original par traitement thermique, et en ce que l'on fait subir au rétentat ainsi complété un collage et un filtrage suivi d'une pasteurisation.

3. 发明专利

SG11201602301WA AMINE SUBSTITUTED TRISILYLAMINE AND TRIDISILYLAMINE COMPOUNDS 未知
公开(公告)号：SG11201602301WA
公开(公告)日：2016-04-28
申请号：SG11201602301W
申请日：2014-09-19
申请人： SANCHEZ ANTONIO , GIRARD JEAN-MARC
发明人： SANCHEZ ANTONIO , GIRARD JEAN-MARC
IPC分类号： C09K3/18
摘要： Compounds and method of preparation of Si—X and Ge—X compounds (X=N, P, As and Sb) via dehydrogenative coupling between the corresponding unsubstituted silanes and amines (including ammonia) or phosphines catalyzed by metallic catalysts is described. This new approach is based on the catalytic dehydrogenative coupling of a Si—H and a X—H moiety to form a Si—X containing compound and hydrogen gas (X=N, P, As and Sb). The process can be catalyzed by transition metal heterogenous catalysts such as Ru(O) on carbon, Pd(O) on MgO) as well as transition metal organometallic complexes that act as homogeneous catalysts. The —Si—X products produced by dehydrogenative coupling are inherently halogen free. Said compounds can be useful for the deposition of thin films by chemical vapor deposition or atomic layer deposition of Si—containing films.

4. 发明申请

WO2019213110A1 HETEROGENEOUS WET SYNTHESIS PROCESS FOR PREPARATION OF HIGH PURITY TUNGSTEN PENTAHALIDE 审中-公开
公开(公告)号：WO2019213110A1
公开(公告)日：2019-11-07
申请号：PCT/US2019/029958
申请日：2019-04-30
申请人： L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE , AMERICAN AIR LIQUIDE, INC. , LIU, Yumin , LI, Feng , WAN, Zhiwen , FAFARD, Claudia , WIESE, Stefan , HUSSON, Guillaume , NIKIFOROV, Grigory , SUI, Bin , GIRARD, Jean-Marc
发明人： LIU, Yumin , LI, Feng , WAN, Zhiwen , FAFARD, Claudia , WIESE, Stefan , HUSSON, Guillaume , NIKIFOROV, Grigory , SUI, Bin , GIRARD, Jean-Marc
IPC分类号： C01G41/04
摘要： Synthesis of tungsten pentahalide compositions having low impurity profiles are disclosed. The specific impurity profile permits deposition of high purity tungsten-containing films using vapor deposition processes or other semiconductor manufacturing processes without introduction of performance-impacting contaminants.

5. 发明申请

WO2018122612A1 ZIRCONIUM, HAFNIUM, TITANIUM PRECURSORS AND DEPOSITION OF GROUP 4 CONTAINING FILMS USING THE SAME 审中-公开
公开(公告)号：WO2018122612A1
公开(公告)日：2018-07-05
申请号：PCT/IB2017/001739
申请日：2017-12-29
申请人： L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE , KIM, Daehyeon , GATINEAU, Satoko , NOH, Wontae , GATINEAU, Julien , GIRARD, Jean-marc
发明人： KIM, Daehyeon , GATINEAU, Satoko , NOH, Wontae , GATINEAU, Julien , GIRARD, Jean-marc
IPC分类号： H01L21/316 , C23C16/18 , H01L21/31
摘要： Group 4 transition metal-containing film forming compositions are disclosed. The Group 4 transition metal-containing film forming compositions comprise Group 4 transition metal precursors having the formula L 2 -M-(R)C 5 R 3 -[(ER 2 ) 2 -NR]-, wherein M is Ti, Zr, or Hf bonded in an η 5 bonding mode to the Cp group; each E is independently C, Si, B or P; each R is independently a hydrogen or a C 1 -C 4 hydrocarbon group; and each L is independently a -1 anionic ligand selected from the group consisting of NR' 2 , OR', Cp, amidinate, β-diketonate, or keto-iminate, wherein R' is a H or a C 1 -C 4 hydrocarbon group and adjacent R' s may be joined to form a hydrocarbyl ring; provided that at least one R on the Cp is C 1 to C 4 . Also disclosed are methods of synthesizing and using the disclosed precursors to deposit Group 4 transition metal-containing films on one or more substrates via vapor deposition processes.

6. 发明申请

WO2018122603A3 ZIRCONIUM, HAFNIUM, TITANIUM PRECURSORS AND DEPOSITION OF GROUP 4 CONTAINING FILMS USING THE SAME 审中-公开
公开(公告)号：WO2018122603A3
公开(公告)日：2018-07-05
申请号：PCT/IB2017/001658
申请日：2017-12-14
申请人： L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE , GATINEAU, Satoko , NOH, Wontae , KIM, Daehyeon , GATINEAU, Julie , GIRARD, Jean-Marc
发明人： GATINEAU, Satoko , NOH, Wontae , KIM, Daehyeon , GATINEAU, Julie , GIRARD, Jean-Marc
IPC分类号： C23C16/455 , C04B35/622 , C07F17/00 , C23C16/50 , C23C16/06
摘要： Group 4 transition metal-containing film forming compositions are disclosed comprising Group 4 transition metal precursors having the formula: L 2 -M-C 4 AR 3 -3-[(ER 2 ) m -(ER 2 ) n -L']-, L 2 -M-(C 3 ( m -A 2 )R2-4-[(ER 2 ) m - (ER 2 ) n -L']-, L 2 -M-(C 5 AR 4 -4-[(ER 2 ) m -(ER 2)n -L'], and L 2 -M-(C 4 ( m - A 2 )R 3 -4-[(ER 2 ) m -(ER 2 ) n -L']-, wherein M is Ti, Zr, or Hf; each A is independently N, Si, B or P; each E is independently C, Si, B or P; m and n is independently 0, 1 or 2; m + n >1; each R is independently a H or a C 1 -C 4 hydrocarbon group; each L is independently a -1 anionic ligand selected from the group consisting of NR' 2 , OR', Cp, amidinate, β- diketonate, or keto-iminate, wherein R' is a H or a C 1 -C 4 hydrocarbon group; and L' is NR" or O, wherein R' is a H or a C 1 -C 4 hydrocarbon group. Also disclosed are methods of synthesizing and using the disclosed precursors to deposit Group 4 transition metal-containing films on one or more substrates via vapor deposition processes.

7. 发明申请

WO2017165626A1 SI-CONTAINING FILM FORMING COMPOSITIONS AND METHODS OF MAKING AND USING THE SAME 审中-公开
标题翻译：含SI膜形成组合物及其制备和使用方法
公开(公告)号：WO2017165626A1
公开(公告)日：2017-09-28
申请号：PCT/US2017/023779
申请日：2017-03-23
申请人： L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE , AIR LIQUIDE ADVANCED MATERIALS, INC. , KHANDELWAL, Manish , KERRIGAN, Sean , GIRARD, Jean-Marc , SANCHEZ, Antonio , ZHANG, Peng
发明人： KHANDELWAL, Manish , KERRIGAN, Sean , GIRARD, Jean-Marc , SANCHEZ, Antonio , ZHANG, Peng
IPC分类号： C08G77/60 , C08J5/18
摘要： Si-containing film forming compositions are disclosed comprising a precursor having the formula [-NR-R 4 R 5 Si-(CH 2 )t-SiR 2 R 3 -] n wherein n = 2 to 400; R, R 2 , R 3 , R 4 , and R 5 are independently H, a hydrocarbon group, or an alkylamino group, and provided that at least one of R 2 , R 3 , R 4 , and R 5 is H; and R is independently H, a hydrocarbon group, or a silyl group. Exemplary precursors include, but are not limited to, [-NH-SiH 2 -CH 2 -SiH 2 -] n , and [-N(SiH 2 -CH 2 -SiH 3 )-SiH 2 -CH 2 -SiH 2 -] n .
摘要翻译：公开了含有含Si成膜组合物，其包含具有式[-NR-R 4 R 5 Si-（CH _{2 -SiH <子> 2 - 。] <子>名词}

8. 发明申请

WO2003046253A1 METHOD FOR DEPOSITING SILICON NITRIDE FILMS AND SILICON OXYNITRIDE FILMS BY CHEMICAL VAPOR DEPOSITION 审中-公开
标题翻译：通过化学蒸气沉积法沉积硅酸盐膜和硅氧烷膜的方法
公开(公告)号：WO2003046253A1
公开(公告)日：2003-06-05
申请号：PCT/EP2002/013869
申请日：2002-11-27
申请人： L'AIR LIQUIDE, SOCIETE ANONYME A DIRECTOIRE ET CONSEIL DE SURVEILLANCE POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE , DUSSARRAT, Christian , GIRARD, Jean-Marc
发明人： DUSSARRAT, Christian , GIRARD, Jean-Marc
IPC分类号： C23C16/34
CPC分类号： C23C16/308 , C23C16/345
摘要： (Problem) To provide a method for the production of silicon nitride and silicon oxynitride films by CVD technology, wherein said method provides acceptable film - deposition rates even at lower temperatures and is not accompanied by the production of large amounts of ammonium chloride. (Solution) Use of a hydrocarbylaminodisilane compound with the formula (R 0 ) 3 -Si-Si-(R 0 ) 3 (I) {each R 0 is independently selected from the hydrogen atom, chlorine atom, and -NR 1 (R 2 ) groups (wherein R 1 and R 2 are each independently selected from the hydrogen atom and C 1 to C 4 hydrocarbyl with the proviso that R 1 and R 2 may not both be the hydrogen atom) and at least one R 0 is the -NR 1 (R 2 ) group} as a precursor for silicon nitride and silicon oxynitride.
摘要翻译：（问题）提供通过CVD技术制造氮化硅和氮氧化硅膜的方法，其中所述方法即使在较低温度下也提供可接受的膜沉积速率，并且不伴随产生大量的氯化铵。（溶液）式（R 0）3 -Si-Si-（R 0）3（I）{各R 0）的烃基氨基二硅烷化合物的用途独立地选自氢原子，氯原子，和-NR 1（R 2）基团（其中R 1和R 2各自独立地选自氢原子和C 1至C 4烃基，条件是R 1和R 2独立地选自氢，可能不都是氢原子），并且至少一个R 0是-NR 1（R 2）基团）作为氮化硅和氮氧化硅的前体。

9. 发明申请

WO2002076641A2 CLEANING APPARATUS AND CLEANING METHOD 审中-公开
标题翻译：清洁装置和清洁方法
公开(公告)号：WO2002076641A2
公开(公告)日：2002-10-03
申请号：PCT/EP2002/002458
申请日：2002-01-22
申请人： L'AIR LIQUIDE, SOCIETE ANONYME A DIRECTOIRE ET CONSEIL DE SURVEILLANCE POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE , LETESSIER, Olivier , GIRARD, JEAN-MARC , NASU, Akinobu , XU, Mindi
发明人： LETESSIER, Olivier , GIRARD, JEAN-MARC , NASU, Akinobu , XU, Mindi
IPC分类号： B08B9/027
CPC分类号： B08B9/027 , B08B9/00 , B08B9/032 , B08B9/08
摘要： To provide a cleaning apparatus and a cleaning method that require a smaller conduit population and less space and as a result cost less and provide an improved operability. A cleaning apparatus (30) contains a gastight container (32) for holding solvent; the interior of this container is partitioned in a gastight manner by a partition wall (34) into a feed compartment (36) that holds fresh solvent and a recovery compartment (38) that holds spent solvent. The partition wall (34) is slideably supported by a sliding support member (42) in such a manner that the pressure within the feed compartment (36) becomes equalized with the pressure within the recovery compartment (38). The feed compartment (36) is connected to a manifold (12) by a feed conduit (44) and the recovery compartment (38) is connected to the manifold (12) by a recovery conduit (46). A gas introduction conduit (52) is connected to the feed conduit (44) in order to introduce pressurization gas from a pressurized gas source (54). An exhaust conduit (62) is connected to the recovery conduit (46) in order to conduct vacuum exhaust using a vacuum exhaust source (64).
摘要翻译：为了提供一种清洁装置和清洁方法，其需要较小的管道总数和更少的空间，并且因此降低了成本并且提供了改进的可操作性。清洁装置（30）包含用于保持溶剂的气体容器（32）该容器的内部以气密的方式被分隔壁（34）分隔成保持新鲜溶剂的进料室（36）和容纳废溶剂的回收室（38）。分隔壁（34）以滑动支撑构件（42）可滑动地支撑，使得进料室（36）内的压力与回收室（38）内的压力相等。进料室（36）通过进料管道（44）连接到歧管（12），并且回收室（38）通过回收管道（46）连接到歧管（12）。气体导入管道（52）连接到进料管道（44），以便从加压气体源（54）引入加压气体。排气导管（62）连接到回收管道（46），以便使用真空排气源（64）进行真空排气。

10. 发明申请

WO1987003902A1 METHOD FOR PARTIAL OR TOTAL DEALCOHOLIZATION OF WINE AND/OR CIDER AND DEVICE FOR IMPLEMENTING SUCH METHOD 审中-公开
标题翻译：用于葡萄酒和/或食品的部分或总体醇化的方法和用于实施这种方法的装置
公开(公告)号：WO1987003902A1
公开(公告)日：1987-07-02
申请号：PCT/CH1986000178
申请日：1986-12-18
申请人： FEDERATION DES COOPERATIVES MIGROS , GIRARD, Jean-Marc , CUENAT, Philippe
发明人： FEDERATION DES COOPERATIVES MIGROS
IPC分类号： C12G03/08
CPC分类号： C12G3/085
摘要： Partial or total dealcoholization of wine and/or cider while preserving the taste and aroma of the product treated. The device used in this method comprises a vat (5) containing the liquid to be treated, a reverse osmosis unit (13) and a closed circuit between said above-mentioned elements to circulate the liquid to be treated through the unit and to bring it back to the tank. In this circuit are mounted a high-pressure pump (11) and means for the control and regulation of the pressure, temperature and flow rate in order to perform the dealcoholization process. Means (68, 63, 57) are provided to inject demineralized water free of chlorine in order to compensate for the loss of permeate. An ingredient vat (70) is provided to mix the ingredients which tend to render to the treated liquid its original taste and aroma. The invention is applicable to all liquids containing alcohol, particularly wine.
摘要翻译：葡萄酒和/或苹果酒的部分或全部脱醇，同时保留所处理产品的味道和香气。在该方法中使用的装置包括含有待处理液体的桶（5），反渗透单元（13）和所述上述元件之间的闭合回路，以使待处理的液体通过该单元循环并使其回到坦克。在该电路中安装有高压泵（11）和用于控制和调节压力，温度和流速的装置，以便进行脱醇过程。提供装置（68,63,57）以注入不含氯的软化水，以补偿渗透物的损失。提供成分桶（70）以混合倾向于使处理液体具有其原始味道和香气的成分。本发明适用于含有酒精，特别是葡萄酒的所有液体。

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