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1. 发明申请

US20110198500A1 Novel method for on-line measurement in simulated moving bed units and application to control and regulation of said units 有权
标题翻译：模拟移动床单元在线测量的新方法和所述单元的控制和调节应用
公开(公告)号：US20110198500A1
公开(公告)日：2011-08-18
申请号：US12907597
申请日：2010-10-19
申请人： Gérard HOTIER , Philibert Leflaive , Mathieu Digne , Philippe Marteau , Jean-Lucien Molle , Michel Leclercq , Sophie Dewally-Morel
发明人： Gérard HOTIER , Philibert Leflaive , Mathieu Digne , Philippe Marteau , Jean-Lucien Molle , Michel Leclercq , Sophie Dewally-Morel
IPC分类号： G01J3/44
CPC分类号： G01N21/65 , B01D15/1821 , G01N21/8507 , G01N2201/084 , G01N2201/1211 , G01N2201/129
摘要： The present invention describes a method for measuring the concentrations of species present at one point of a separation unit functioning in simulated moving bed mode (SMB), using an immersing probe located at one point in the unit or on one of the streams entering or leaving said unit, and a thermocouple located in the vicinity of the immersing probe, in which a Raman spectrum obtained using a laser source functioning at a wavelength of 785 nm is utilized. Application of the method to controlling and regulating a SMB xylenes separation unit.
摘要翻译：本发明描述了一种用于测量存在于模拟移动床模式（SMB）中运行的分离单元的一个点处的物种的浓度的方法，其使用位于该单元中的一个点处的浸入探针或者进入或离开的一个流所述单元和位于浸渍探头附近的热电偶，其中使用使用波长为785nm的激光源获得的拉曼光谱。该方法用于控制和调节SMB二甲苯分离单元。

2. 发明授权

US06537451B1 Rotary valve 有权
标题翻译：旋转阀
公开(公告)号：US06537451B1
公开(公告)日：2003-03-25
申请号：US09590120
申请日：2000-06-09
申请人： Gérard Hotier
发明人： Gérard Hotier
IPC分类号： B01D1508
CPC分类号： B01D15/1842 , B01D2215/023 , B01D2259/40005 , F16K11/0743 , G01N2030/201 , Y10T137/86501 , Y10T137/86533 , Y10T137/86863
摘要： Disclosed is a rotary valve that makes it possible to link several groups of hoses referenced group G1, group G2, and group G3. The valve includes a stator (40) that is provided with means (E, F, R, S) for circulating fluid or fluids of group 1, means (45, 46) for passing at least two fluids F1, F2 that belong to group G3, and a rotor (47) that is equipped with means (9) for passing fluids of group G3 and also means (50) that make possible the linking either of fluids of G1 with group G3 or fluids of group G3 with G3.
摘要翻译：公开了一种旋转阀，其使得可以链接几组参考组G1，组G2和组G3的软管。该阀包括定子（40），该定子设有用于循环流体或组1的流体的装置（E，F，R，S），用于使至少两个属于组的流体F1，F2的装置（45,46） G3和具有用于使组G3的流体通过的装置（9）的转子（47），以及使G1与G3的流体或G3的流体与G3连接的装置（50）的装置（50）。

3. 发明授权

US06512154B1 Production of a xylene isomer in three stages: separation, isomerization with a catalyst with an EUO zeolite base and transalkylation with recycling of C10-aromatic compounds 有权
标题翻译：分三个阶段生产二甲苯异构体：用具有EUO沸石碱的催化剂进行分离，异构化，并用C10-芳族化合物的再循环进行烷基转移
公开(公告)号：US06512154B1
公开(公告)日：2003-01-28
申请号：US09598651
申请日：2000-06-22
申请人： Julia Magne-Drisch , Gérard Hotier , Jean-François Joly , Elisabeth Merlen , Fabio Alario
发明人： Julia Magne-Drisch , Gérard Hotier , Jean-François Joly , Elisabeth Merlen , Fabio Alario
IPC分类号： C07C522
CPC分类号： C07C15/08 , C07C5/2724 , C07C6/126 , C07C2529/18 , C07C2529/74 , C07C15/067
摘要： A process for the production of at least one xylene isomer, paraxylene, metaxylene or orthoxylene from an aromatic feedstock that has 7 to 10 carbon atoms per molecule. The process comprises a stage for transalkylation of C7- and C9-aromatic compounds, a stage for separation of xylenes and a stage for isomerization of xylenes. The isomerization catalyst used in the process comprises at least one EUO zeolite composition whose crystals are grouped in aggregates that have a grain size with a value of Dv,90 less than or equal to 500 microns and at least one element of group VIII.
摘要翻译：从每分子具有7至10个碳原子的芳族原料生产至少一种二甲苯异构体，对二甲苯，间二甲苯或邻二甲苯的方法。该方法包括C7-和C9-芳族化合物的烷基转移反应阶段，用于分离二甲苯的步骤和用于异构化二甲苯的步骤。在该方法中使用的异构化催化剂包含至少一种EUO沸石组合物，其结晶以具有Dv值，90小于或等于500微米的晶粒尺寸和至少一种VIII族元素的聚集体分组。

4. 发明授权

US06429346B2 Simultaneous process for simulated moving-bed dismutation and separation of toluene into benzene and xylenes 有权
标题翻译：模拟移动床歧视同时进行甲苯分离成苯和二甲苯
公开(公告)号：US06429346B2
公开(公告)日：2002-08-06
申请号：US09832872
申请日：2001-04-12
申请人： Gérard Hotier , Hugues Dulot , Michel Bailly , Karine Ragil
发明人： Gérard Hotier , Hugues Dulot , Michel Bailly , Karine Ragil
IPC分类号： C07C512
CPC分类号： C07C6/123 , C07C2529/40 , C07C2529/70 , Y02P20/544
摘要： A simultaneous process for simulated moving-bed dismutation and separation of a toluene feedstock into benzene and xylenes in the presence of a hydrogen-rich desorbent in at least one adsorber-reactor (100) that contains beds of a solid and comprises at least three zones (23, 24, 25) is described. Vapor-phase or supercritical feedstock (1) is introduced at the inlet of a reaction and adsorption zone (25) (zone III), and a raffinate (15) that is high in benzene and desorbent is recovered at the outlet. Desorbent (5, 7) is introduced at the inlet of a desorption zone (23) (zone I), and an effluent from which is drawn off a portion (8) in the form of an extract that is high in xylenes and desorbent is recovered at the outlet. The other portion of the effluent of zone I is introduced at the inlet of a reaction and desorption zone (24) (zone II), and an effluent is recovered at the outlet that is sent back to the inlet of reaction and adsorption zone III. Each of the zones comprises at least one bed that contains an adsorbent that is adapted to separate benzene, toluene and xylenes, and a catalyst that is adapted to dismutate toluene into benzene and xylenes, whereby the adsorbent and the catalyst are in solid form.
摘要翻译：在含有固体的床的至少一个吸附器 - 反应器（100）中，在富氢解吸剂存在下，将模拟的移动床歧化和甲苯原料分离成苯和二甲苯的同时进行的方法包括至少三个区（23,24,25）。在反应和吸附区（25）（区域III）的入口引入气相或超临界原料（1），在出口处回收苯和解吸剂高的萃余液（15）。将解吸剂（5,7）引入解吸区（23）（区域I）的入口处，将从二甲苯和解吸剂高的提取物形式的部分（8）中排出的流出物在出口处恢复。区域I的流出物的另一部分在反应和解吸区（24）的入口处引入（区域II），并且在出口处回收流出物，其被送回反应和吸附区域III的入口。每个区域包括至少一个床，其包含适于分离苯，甲苯和二甲苯的吸附剂，以及适于将甲苯分解成苯和二甲苯的催化剂，由此吸附剂和催化剂是固体形式。

5. 发明授权

US07473368B2 Simulated moving bed separation process and device 有权
标题翻译：模拟移动床分离过程及装置
公开(公告)号：US07473368B2
公开(公告)日：2009-01-06
申请号：US11136729
申请日：2005-05-25
申请人： Gérard Hotier
发明人： Gérard Hotier
IPC分类号： B01D15/00
CPC分类号： C07C7/12 , B01D15/1871 , B01D53/0423 , B01D2259/40005 , B01D2259/4146 , Y10T436/11 , C07C15/08
摘要： A simulated moving bed (SMB) separation device comprises at least one column, beds of adsorbent arranged in this column, trays Pi with a chamber Ci for distribution and extraction of fluids, a multi-way rotary valve for the distribution of the fluids feeding or leaving said trays, and junction lines Li between this valve and said trays. The SMB device also comprises a plurality of bypass lines Li,i+1 between adjacent lines, these bypasses being outside the multi-way rotary valve and situated in proximity to this valve, for the circulation of rinsing liquids with a small or zero concentration gradient. The invention makes it possible to use all types of distribution and extraction trays and all types of adsorbent loading, while preserving a high level of product purity. Application of the separation devices is in particular to the separation of paraxylene or metaxylene from a C8 aromatic charge.
摘要翻译：模拟移动床（SMB）分离装置包括至少一个柱，在该塔中排列的吸附剂床，具有用于分配和提取流体的腔室Ci的托盘Pi，用于分配流体的多通旋转阀或在该阀和所述托盘之间留下所述托盘和接合线Li。 SMB设备还包括在相邻线路之间的多个旁路管线Li，i + 1，这些旁路在多路旋转阀外部并且位于该阀附近，用于循环具有小或零浓度梯度的冲洗液体。本发明使得可以使用所有类型的分配和提取塔板和所有类型的吸附剂负载，同时保持高水平的产品纯度。分离装置的应用特别是从C8芳族电荷分离对二甲苯或间二甲苯。

6. 发明授权

US06969495B1 Mat element that has a distribution function 有权
标题翻译：具有分布函数的Mat元素
公开(公告)号：US06969495B1
公开(公告)日：2005-11-29
申请号：US09590380
申请日：2000-06-09
申请人： Gérard Hotier , Pierre Renard , Xavier Decoodt
发明人： Gérard Hotier , Pierre Renard , Xavier Decoodt
IPC分类号： B01J8/04 , C07C7/00 , B01J10/00
CPC分类号： B01J8/0492 , C07C7/00 , C07C15/067
摘要： For use in a separation column, a mat element or a beam element has at least: an upper part 2; at least one distributor-collector part (3) having one or more secondary orifices (7i) and at least one main orifice (6), whereby the passage sections of orifices (8) and (7i) are different; and a lower part (4). The distributor-collector part or parts (3) arranged between the upper part (2) and the lower part (4). A sealing element (5a) arranged between the distributor-collector part (3) and the upper part (2), and a sealing element (5b) arranged between the distributor-collector part (3) and the lower part (4). A separation element (8) arranged at distributor-collector part (3), thus delimiting two spaces (3a, 3b) for circulation of fluids.
摘要翻译：为了在分离柱中使用，垫元件或梁元件至少具有：上部2; 至少一个分配器 - 收集器部分（3）具有一个或多个次级孔（7i）和至少一个主孔（6），由此孔口（8）和（7i）的通道部分不同; 和下部（4）。布置在上部（2）和下部（4）之间的分配器 - 收集器部分（3）。布置在分配器 - 收集器部分（3）和上部部分（2）之间的密封元件（5a）和布置在分配器 - 收集器部分（3）和下部部分（4）之间的密封元件（5b）。布置在分配器 - 收集器部分（3）处的分离元件（8），从而限定用于流体循环的两个空间（3a，3b）。

7. 发明授权

US07915471B2 Method for producing paraxylene comprising an adsortion step and two isomerization steps 有权
标题翻译：一种生产对二甲苯的方法，其包括一个老化步骤和两个异构化步骤
公开(公告)号：US07915471B2
公开(公告)日：2011-03-29
申请号：US10580345
申请日：2004-11-23
申请人： Philibert Leflaive , Luc Wolff , Gérard Hotier
发明人： Philibert Leflaive , Luc Wolff , Gérard Hotier
IPC分类号： C07C7/12
CPC分类号： C07C5/2775 , C07C5/2737 , C07C7/12 , C07C15/08
摘要： A process for producing para-xylene from a hydrocarbon feed is described in which an adsorption column operating as a simulated moving bed with at least five zones delivers an extract, a 2-raffinate and an intermediate raffinate.The extract is distilled and the distillate is optionally re-crystallized to recover para-xylene with a purity of at least 99.7%. The 2-raffinate is distilled then isomerized in a reactor preferably operating in the liquid phase and at a low temperature. The intermediate raffinate with an enriched ethylbenzene content is distilled then isomerized in the vapour phase.
摘要翻译：描述了从烃进料生产对二甲苯的方法，其中作为具有至少五个区域的模拟移动床操作的吸附塔递送萃取物，2-萃余液和中间萃余液。将提取物蒸馏，任选地将馏出物重结晶以回收对数二甲苯，纯度至少为99.7％。蒸馏出2萃余液，然后在反应器中异构化，优选在液相和低温下操作。将富含乙苯含量的中间残液蒸馏，然后在汽相中异构化。

8. 发明授权

US07288200B1 System for injecting a by-pass fluid in a separation method in a simulated moving bed 有权
标题翻译：用于在模拟移动床中以分离方法注入旁通流体的系统
公开(公告)号：US07288200B1
公开(公告)日：2007-10-30
申请号：US09762580
申请日：2000-05-26
申请人： Gérard Hotier , Xavier Decoodt , Gilles Ferschneider , Jean-Christophe Viguie
发明人： Gérard Hotier , Xavier Decoodt , Gilles Ferschneider , Jean-Christophe Viguie
IPC分类号： B01D15/08
CPC分类号： B01D15/1842 , C07C7/12 , C07C15/08
摘要： Device and process for separating at least one compound from a mixture in a simulated moving bed, comprising: an enclosure comprising several absorbent beds, two adsorbent beds being separated by a fluid distribution and extraction plate (Pi), the plate comprising one or more distribution, mixing and/or extracting panels, comprising a chamber (Ci), main fluid delivery (4) and extraction (2) lines, several secondary fluid extraction or injection lines (10, 11, 12, 13, Ti), a bypass circuit communicating a distribution plate with a bypass line, means (14, Voi,j, 20) communicating at least one chamber (Ci) with at least one bypass line (Li,j), at least one of the ends of a bypass line communicates with a zone Ri, R′I of an adsorbent bed, said zone being distinct from a distribution chamber (Ci) and another end is connected to said chamber (Ci).
摘要翻译：一种用于在模拟移动床中从混合物中分离至少一种化合物的装置和方法，包括：包含多个吸收床的外壳，两个吸附床由流体分配和提取板（Pi）隔开，所述板包括一个或多个分布，混合和/或提取面板，包括室（Ci），主流体输送（4）和萃取（2）管线，若干二次流体萃取或注入管线（10,11,12,13，Ti），旁路回路将分配板与旁路管路连通，使至少一个腔室（Ci）与至少一个旁通管线（Li，j）连通的装置（14，Voi，j，20），旁路管线的至少一个端部连通具有吸附床的区域Ri，R'I，所述区域与分配室（Ci）不同，另一端连接到所述室（Ci）。

9. 发明授权

US06841714B2 Process for co-production of paraxylene, metaxylene and/or orthoxylene 有权
标题翻译：共生产对二甲苯，间二甲苯和/或邻二甲苯的方法
公开(公告)号：US06841714B2
公开(公告)日：2005-01-11
申请号：US10247830
申请日：2002-09-20
申请人： Philibert Leflaive , Luc Wolff , Gérard Hotier , Alain Methivier
发明人： Philibert Leflaive , Luc Wolff , Gérard Hotier , Alain Methivier
IPC分类号： C07C7/00 , C07C7/13 , C07C15/08 , C07C7/12
CPC分类号： C07C15/08 , C07C7/005 , C07C7/13
摘要： A process for co-production of paraxylene, metaxylene and/or orthoxylene from a hydrocarbon feedstock (1) that comprises [1] a separation stage of the feedstock in a simulated moving bed in a chromatographic column (9) that contains a number of beds of an adsorbent, interconnected in a loop, is described, whereby said column comprises an injection (3) of the feedstock, a draw-off (10) of an extract that consists of paraxylene and desorbent, an intermediate fraction (11) (extract or raffinate) that contains ethylbenzene, and a raffinate (12) that contains a mixture of metaxylene and orthoxylene that is virtually free of ethylbenzene and paraxylene and [2] a crystallization stage (27) of the metaxylene and/or orthoxylene fraction. Upstream from the adsorption zone and/or upstream from the crystallization zone, it is possible to distill the entering mixture to produce an orthoxylene-enriched fraction at the bottom and a metaxylene-enriched fraction at the top.
摘要翻译：一种从烃原料（1）共同生产对二甲苯，间二甲苯和/或邻二甲苯的方法，其包括[1]在色谱柱（9）中的模拟移动床中的原料的分离阶段，其包含多个床描述了以循环相互连接的吸附剂，其中所述柱包括原料的注入物（3），由对二甲苯和解吸剂组成的萃取物的萃取物（10），中间馏分（11）或萃余液）和含有实际上不含乙苯和对二甲苯的间二甲苯和邻二甲苯混合物的萃余液（12），[2]间二甲苯和/或邻二甲苯馏分的结晶阶段（27）。从吸附区上游和/或结晶区上游，可以蒸馏进入的混合物，在底部产生富含邻二甲苯的馏分，并在顶部产生富含甲炔的馏分。

10. 发明授权

US06838588B2 Process for co-producing para-xylene and metaxylene, comprising two separation steps 有权
标题翻译：共同生产对二甲苯和间二甲苯的方法，包括两个分离步骤
公开(公告)号：US06838588B2
公开(公告)日：2005-01-04
申请号：US10108392
申请日：2002-03-29
申请人： Philibert Leflaive , Alain Methivier , Gérard Hotier
发明人： Philibert Leflaive , Alain Methivier , Gérard Hotier
IPC分类号： C07C7/04 , C07C7/00 , C07C7/12 , C07C7/13 , C07C15/08
CPC分类号： C07C7/005 , C07C7/13 , C07C15/08
摘要： A process is described for co-producing metaxylene and paraxylene from a hydrocarbon feed comprising two separation steps. The first step of the process is a counter-current simulated moving bed system in a chromatographic column containing at least five zones, comprising injecting the feed and injecting a desorbent and delivering an extract, a raffinate and an intermediate raffinate either continuously or discontinuously. The extract is distilled to obtain a paraxylene with a purity of at least 99.7%. The raffinate, which is richer in metaxylene, is distilled to extract the desorbent and injected into a counter-current simulated moving bed continuously delivering an extract and a raffinate. One of these two streams is enriched in metaxylene. The most metaxylene-rich stream is distilled to obtain metaxylene with a purity of more than 99%.
摘要翻译：描述了从包含两个分离步骤的烃进料共同生产间二甲苯和对二甲苯的方法。该方法的第一步是在含有至少五个区域的色谱柱中的逆流模拟移动床系统，包括注射进料并注入解吸剂并连续地或不连续地递送提取物，萃余液和中间萃余液。蒸馏提取物，得到纯度至少为99.7％的对二甲苯。富含中间二甲苯的萃余液被蒸馏以提取解吸剂并注入到逆流模拟移动床中，连续输送提取物和萃余液。这两条河中的一条富含间二甲苯。蒸馏出最富含中间二甲烷的料流，得到纯度大于99％的间二甲苯。

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