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    • 1. 发明授权
    • Substrates provided with a microstructured surface, methods for the production thereof, and their use
    • 具有微结构表面的基板,其制造方法及其用途
    • US06649266B1
    • 2003-11-18
    • US09959023
    • 2001-10-15
    • Frank GrossMartin MennigPeter W. OliveiraHelmut SchmidtStefan Sepeur
    • Frank GrossMartin MennigPeter W. OliveiraHelmut SchmidtStefan Sepeur
    • B32B1700
    • C09K3/18B05D1/40B05D5/08B08B17/06B08B17/065B29C59/026B29C2059/023Y10T428/31Y10T428/315Y10T428/31612Y10T428/31663
    • Substrates provided with a microstructured surface have a surface layer which (a) comprises a composition comprising condensates of one or more hydrolysable compounds of at least one element M from main groups III to V and/or transition groups II to IV of the Periodic Table of the Elements, at least some of these compounds containing not only hydrolysable groups A but also non-hydrolysable, carbon-containing groups B and the total molar ratio of groups A to groups B in the parent monomeric starting compounds being from 10:1 to 1:2, from 0.1 to 100 mol % of the groups B being groups B′ containing on average from 5 to 30 fluorine atoms which are attached to one or more aliphatic carbon atoms distanced from M by at least two atoms, and (b) has a microstructuring of such kind that the contact angle with respect to water or hexadecane is at least 5° higher than the contact angle of a corresponding smooth surface. The substrates provided with a microstructured surface are particularly suitable as transparent or translucent easy-to-clean systems.
    • 提供有微结构化表面的底物具有表面层,其表面层包含一种组合物,该组合物包含至少一种元素M的主要组III至V的一种或多种可水解化合物的缩合物和/或周期表的转变基团II至IV的组合物 元素,这些化合物中的至少一些化合物不仅含有可水解基团A,而且含有不可水解的含碳基团B,并且母体单体起始化合物中基团A与基团B的总摩尔比为10:1至1 2,0.1〜100摩尔%的基团B为含有平均5〜30个氟原子的基团B',其通过至少两个原子与一个或多个与M离开的一个或多个脂族碳原子连接,(b)具有 这种微结构化使得相对于水或十六烷的接触角比相应的光滑表面的接触角高至少5°。具有微结构化表面的基底特别合适 作为透明或半透明的易于清洁的系统。
    • 4. 发明申请
    • METHOD OF PRODUCING PHENOLATE ESTER COMPOUNDS
    • 苯酚酯化合物的制备方法
    • US20120059116A1
    • 2012-03-08
    • US13319784
    • 2010-05-04
    • Stefan SepeurFrank Gross
    • Stefan SepeurFrank Gross
    • C09D183/08C08G77/26B82Y30/00
    • C23C18/14C07F7/1804C09D183/04C23C18/1216C23C18/122C23C18/1254C23C18/127C25D13/02C25D13/04
    • The invention relates to phenolic ester compounds.In order to create a new product class which is suited as coating material, a compound is created within the scope of the invention, having a chemical structure of the following formula: [R1—Ph—O]aX(R2)b(R3)c(OR)n-a-b-c where X=Si, Ti, Zr, Mo, Mn, Cr, W, Hf, Ge, Sn, Pb where n=4 or X=B, V, Al, Ga, In where n=3 or X=Zn, Ni, Cu, alkaline earth where n=2 R1=O—H, H, O—Y or an organic side chain Y=an element which is different from or the same as X and has appropriate substituents R2=alkyl group or functional organic side chain R3=an organic side chain which is the same as or different from R2 Ph=aryl group R=alkyl group a is an integer between 1 and n; b=0 or 1 and c=0 or 1, and a+b+c=n. A compound is thus obtained, in which an aryl group is linked into an ester by way of an O—X group. Surprisingly, it was found that materials which resist hydrolysis and are highly stable towards chemicals are obtained by the transesterification of silanes with phenolic compounds.
    • 本发明涉及酚酯化合物。 为了制备适合作为涂料的新产品类,在本发明的范围内产生具有下式的化学结构的化合物:[R1-Ph-O] aX(R2)b(R3) c(OR)nabc其中X = Si,Ti,Zr,Mo,Mn,Cr,W,Hf,Ge,Sn,Pb,其中n = 4或X = B,V,Al,Ga,In,其中n = 3或 X = Zn,Ni,Cu,碱土,其中n = 2 R1 = O-H,H,O-Y或有机侧链Y =与X不同或相同且具有适当取代基的元素R 2 =烷基 基团或官能的有机侧链R3 =与R 2相同或不同的有机侧链Ph =芳基R =烷基a是1和n之间的整数; b = 0或1,c = 0或1,a + b + c = n。 由此得到通过O-X基团将芳基连接到酯中的化合物。 令人惊讶的是,发现耐水解和对化学物质稳定的材料是通过硅烷与酚类化合物的酯交换得到的。
    • 5. 发明申请
    • AIRBAG MODULE WITH AN AIRBAG AND A TUBULAR GAS GENERATOR THAT CAN BE FASTENED TO A MODULE HOUSING
    • 具有安全气囊的气囊模块和可以固定在模块壳体上的管状气体发生器
    • US20110163522A1
    • 2011-07-07
    • US13051940
    • 2011-03-18
    • Stefan HAMELSTobias FechnerFrank GrossChristian Kempe
    • Stefan HAMELSTobias FechnerFrank GrossChristian Kempe
    • B60R21/16
    • B60R21/2171
    • An airbag module with an airbag and a tubular gas generator fastened to a module housing is provided. Said tubular gas generator having gas outlet openings along the periphery thereof and can be fastened to the module housing by means of only a clamping ring that is movable over the tubular gas generator and over a section of the module housing. The clamping ring has in axial direction elongated sections being separated from each other and continuing axial in the opposite direction. The module housing has in its bottom an opening for inserting the tubular gas generator, wherein on the module housing below this opening a support for the tubular gas generator is provided. The clamping ring is designed such that said clamping ring reaches below the support after positioning the tubular gas generator with the elongated section by axial moving in direction of the centre of the tubular gas generator.
    • 提供一种具有安全气囊的安全气囊模块和固定在模块外壳上的管状气体发生器。 所述管式气体发生器具有沿着其周边的气体出口,并且可以仅通过可在管式气体发生器上方并在模块壳体的一部分上方的夹紧环紧固到模块壳体。 夹紧环在轴向上具有细长部分,彼此分离并在相反方向上轴向延伸。 模块壳体的底部具有用于插入管状气体发生器的开口,其中在该开口下方的模块壳体上设置有用于管状气体发生器的支撑件。 夹紧环设计成使得所述夹紧环通过在管状气体发生器的中心的方向上轴向移动而将管状气体发生器与细长部分定位之后到达支撑件下方。