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1. 发明授权

US5750642A Process for the preparation of copolymers 失效
标题翻译：制备共聚物的方法
公开(公告)号：US5750642A
公开(公告)日：1998-05-12
申请号：US801976
申请日：1997-02-19
申请人： Frank Baardman , Jayne Jubb
发明人： Frank Baardman , Jayne Jubb
IPC分类号： C08G67/02 , C08K5/49
CPC分类号： C08G67/02
摘要： A process for the preparation of copolymers of carbon monoxide with an olefinically unsaturated compound comprising copolymerizing the monomers in the presence of a catalyst composition based upon (a) a salt of a Group VIII metal, and (b) a cation which is selected from cationic oxidants and cations of the general formulae R.sub.n H.sub.4-n N.sup.+, R.sub.m H.sub.3-m C.sup.+ and R.sub.m H.sub.3-m O.sup.+, wherein n is 0, 1, 2, 3 or 4, m is 2 or 3, and R represents a hydrocarbyl group and/or two or three of R together with the atom carrying a positive charge represent a ring structure, on the understanding that when n is 3, at most two of R together with nitrogen represent a heterocyclic ring structure, and when n is 4, three of R together with nitrogen represent an aromatic heterocyclic ring structure.
摘要翻译：一种制备一氧化碳与烯属不饱和化合物的共聚物的方法，包括在催化剂组合物的存在下，基于（a）第Ⅷ族金属的盐和（b）选自阳离子氧化剂和通式为RnH4-nN +，RmH3-mC +和RmH3-mO +的阳离子，其中n为0,1,2,3或4，m为2或3，R为烃基和/或两个或三个的R原子与带正电荷的原子一起表示环结构，应当理解，当n为3时，R中最多两个与氮一起表示杂环结构，当n为4时，R中的三个与氮一起表示芳族杂环结构。

2. 发明授权

US4436937A Process for the ring alkylation of an aniline 失效
标题翻译：苯胺环烷基化方法
公开(公告)号：US4436937A
公开(公告)日：1984-03-13
申请号：US436215
申请日：1982-10-25
申请人： Frank Baardman , Robert van Helden , Margaretha J. de Nie-Sarink
发明人： Frank Baardman , Robert van Helden , Margaretha J. de Nie-Sarink
IPC分类号： C07B61/00 , B01J27/00 , B01J27/08 , C07C67/00 , C07C209/00 , C07C209/68 , C07C211/47 , C07C275/28 , C07C85/24
CPC分类号： C07C275/28 , C07C209/68 , Y02P20/582
摘要： An aniline is alkylated on the ring by treating it with an alkylating agent, preferably an alkyl chloride, in the liquid phase, and in the presence of at least 1.02 mole of an aluminum halide per mole of the aniline.
摘要翻译：通过在液相中用烷基化剂，优选烷基氯处理，并且在每摩尔苯胺存在至少1.02摩尔卤化铝的情况下，将苯胺烷基化在环上。

3. 发明授权

US4031152A Preparation of derivatives of cyclobutane and cyclobutene 失效
标题翻译：环丁烷和环丁烯衍生物的制备
公开(公告)号：US4031152A
公开(公告)日：1977-06-21
申请号：US643419
申请日：1975-12-22
申请人： Joachim H. Lukas , Frank Baardman , Adriaan P. Kouwenhoven
发明人： Joachim H. Lukas , Frank Baardman , Adriaan P. Kouwenhoven
IPC分类号： C07C2/42 , C07C3/03 , C07C13/06
CPC分类号： C07C2/42 , C07C2101/04 , C07C2102/18 , C07C2102/50 , C07C2531/14
摘要： Preparation of alkylidenecyclobutane derivatives and of cyclobutene derivatives by contacting a (cyclo)alkene with an allene or with a 1-alkyne in the liquid phase in the presence of a dissolved Lewis acid derived from an element of Group III A of the Periodic Table of the Elements, titanium, tin, antimony, tantalum, rhenium, iron, or zinc.
摘要翻译：通过使（环）烯与丙烯或与1-炔炔在液相中，在衍生自元素周期表第IIIA族元素的溶解路易斯酸的存在下，制备亚烷基环丁烷衍生物和环丁烯衍生物元素，钛，锡，锑，钽，铼，铁或锌。

4. 发明授权

US5670611A Process for the copolymerization of carbon monoxide with an olefinically unsaturated compound 失效
标题翻译：一氧化碳与烯属不饱和化合物共聚的方法
公开(公告)号：US5670611A
公开(公告)日：1997-09-23
申请号：US615648
申请日：1996-03-13
申请人： Frank Baardman , Arleen Marie Bradford , Jayne Jubb , Pieter Scheerman , Rudolf Jacobus Wijngaarden , Erwin Paulus Petrus Bleeker , Johannes Adrianus Maria Van Broekhoven
发明人： Frank Baardman , Arleen Marie Bradford , Jayne Jubb , Pieter Scheerman , Rudolf Jacobus Wijngaarden , Erwin Paulus Petrus Bleeker , Johannes Adrianus Maria Van Broekhoven
IPC分类号： B01J31/14 , B01J31/18 , B01J31/24 , C08G67/00 , C08G67/02
CPC分类号： B01J31/2409 , B01J31/14 , B01J31/146 , B01J31/18 , C08G67/02 , B01J2531/824 , B01J31/1895
摘要： A process for the copolymerization of carbon monoxide with an olefinically unsaturated compound in which a solid particulate material is suspended in a liquid diluent in which the polymer to be produced forms a suspension. The monomers are contracted in the liquid diluent containing the suspended solid particulate material with a catalyst composition which is based on a source of a Group VIII metal and a boron hydrocarbyl compound.
摘要翻译：将一氧化碳与烯属不饱和化合物共聚的方法，其中将固体颗粒材料悬浮于待生产的聚合物形成悬浮液的液体稀释剂中。单体在含有悬浮固体颗粒材料的液体稀释剂中以基于VIII族金属源和硼烃基化合物的催化剂组合物收缩。

5. 发明授权

US5658982A Process for the copolymerization of carbon monoxide with an olefinically unsaturated compound 失效
标题翻译：一氧化碳与烯属不饱和化合物共聚的方法
公开(公告)号：US5658982A
公开(公告)日：1997-08-19
申请号：US614287
申请日：1996-03-12
申请人： Frank Baardman , Arleen Marie Bradford , Jayne Jubb , Pieter Scheerman , Rudolf Jacobus Wijngaarden
发明人： Frank Baardman , Arleen Marie Bradford , Jayne Jubb , Pieter Scheerman , Rudolf Jacobus Wijngaarden
IPC分类号： B01J31/14 , B01J31/18 , B01J31/24 , C08G67/00 , C08G67/02 , C08K5/49
CPC分类号： C08G67/02 , B01J31/146 , B01J31/2409 , B01J2531/824 , B01J31/1895 , Y02P20/584
摘要： A process for the copolymerization of carbon monoxide with an olefinically unsaturated in which the monomers are contacted with a catalyst composition which is based on a source of a Group VIII metal and a boron hydrocarbyl compound. Additional boron hydrocarbyl compound is added to the polymerization mixture during the copolymerization or when the catalyst has lost its activity. A process for recycling a polymerization catalyst is also presented. It includes the steps of recovering a Group VIII metal composition from a preceding copolymerization process for the preparation of a copolymer of carbon monoxide and an olefinicaIly unsaturated compound and adding a boron hydrocarbyl compound to the Group VIII metal composition.
摘要翻译：一种一氧化碳与烯属不饱和的共聚方法，其中单体与基于VIII族金属和硼烃基化合物的源的催化剂组合物接触。在共聚期间或当催化剂失去活性时，向聚合混合物中加入另外的硼烃基化合物。还提出了一种再循环聚合催化剂的方法。其包括从前述共聚方法中回收第VIII族金属组合物以制备一氧化碳和烯属不饱和化合物的共聚物并向第VIII族金属组合物中加入硼烃基化合物的步骤。

6. 发明授权

US4262124A Bicyclic lactams and process for their preparation 失效
标题翻译：双环内酰胺及其制备方法
公开(公告)号：US4262124A
公开(公告)日：1981-04-14
申请号：US147419
申请日：1980-05-06
申请人： Gary Scholes , Frank Baardman
发明人： Gary Scholes , Frank Baardman
IPC分类号： C07D209/52 , C07D221/04 , C07D295/10
CPC分类号： C07D221/04 , C07D209/52
摘要： A process for preparing the cis-racemate of 3-azabicyclo-(3.1.0)hexane-2-carboxylic acid, and certain novel intermediates involved therein.
摘要翻译：制备3-氮杂双环（3.1.0）己烷-2-羧酸的顺式外消旋物的方法，以及其中涉及的某些新型中间体。

7. 发明授权

US5741939A Process for the copolymerization of carbon monoxide with an olefinically unsaturated compound 失效
标题翻译：一氧化碳与烯属不饱和化合物共聚的方法
公开(公告)号：US5741939A
公开(公告)日：1998-04-21
申请号：US619868
申请日：1996-03-21
申请人： Frank Baardman , Arleen Marie Bradford , Jayne Jubb , Pieter Scheerman , Rudolf Jacobus Wijngaarden
发明人： Frank Baardman , Arleen Marie Bradford , Jayne Jubb , Pieter Scheerman , Rudolf Jacobus Wijngaarden
IPC分类号： B01J31/18 , B01J31/24 , C08G67/02 , C07C45/49
CPC分类号： C08G67/02 , B01J31/2409 , B01J2531/80 , B01J31/1895
摘要： A process for the copolymerization of carbon monoxide with an olefinically unsaturated compound comprising contacting the monomers in the presence of a liquid diluent with a catalyst composition which is based on (a) a source of a Group VIII metal, (b) a bidentate ligand of the general formula R.sup.1 R.sup.2 M.sup.1 --R--M.sup.2 R.sup.3 R.sup.4 wherein M.sup.1 and M.sup.2 independently represent a phosphorus, arsenic or antimony atom, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represent unsubstituted or substituted hydrocarbyl groups on the understanding that at least one of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represents a polar substituted aryl group and R represents a bivalent bridging group containing at least two carbon atoms in the bridge, and (c) a boron hydrocarbyl compound, with application of a stirring power transmitted to the polymerization mixture of at least 0.25 kW/m.sup.3.
摘要翻译：一种一氧化碳与烯属不饱和化合物共聚的方法，包括在液体稀释剂存在下使单体与催化剂组合物接触，所述催化剂组合物基于（a）Ⅷ族金属源，（b）二元配体通式R1R2M1-R-M2R3R4其中M1和M2独立地表示磷，砷或锑原子，R1，R2，R3和R4独立地表示未取代或取代的烃基，其理解是R1，R2，R3和 R4表示极性取代的芳基，R表示桥中含有至少两个碳原子的二价桥连基团，和（c）硼烃基化合物，通过施加向聚合混合物中传递至少0.25kW / m3。

8. 发明授权

US5668249A Process for the copolymerization of carbon monoxide with an olefinically unsaturated compound 失效
标题翻译：一氧化碳与烯属不饱和化合物共聚的方法
公开(公告)号：US5668249A
公开(公告)日：1997-09-16
申请号：US615649
申请日：1996-03-13
申请人： Frank Baardman , Arleen Marie Bradford , Jayne Jubb , Pieter Scheerman , Rudolf Jacobus Wijngaarden , Erwin Paulus Petrus Bleeker , Johannes Adrianus Maria Van Broekhoven
发明人： Frank Baardman , Arleen Marie Bradford , Jayne Jubb , Pieter Scheerman , Rudolf Jacobus Wijngaarden , Erwin Paulus Petrus Bleeker , Johannes Adrianus Maria Van Broekhoven
IPC分类号： B01J31/14 , B01J31/18 , B01J31/24 , C08G67/00 , C08G67/02
CPC分类号： C08G67/02 , B01J31/146 , B01J31/2409 , B01J2531/824 , B01J31/1895
摘要： A process for the copolymerization of carbon monoxide with an olefinically unsaturated compound in which the monomers are contacted in the presence of a liquid diluent and a protic compound with a catalyst composition which is based on a source of a Group VIII metal and a hydrocarbylborane. A stirring power is transmitted to the polymerization mixture of at least 0.25 kW/m.sup.3.
摘要翻译：一种一氧化碳与烯属不饱和化合物共聚的方法，其中单体在液体稀释剂和质子化合物存在下与催化剂组合物接触，催化剂组合物基于VIII族金属和烃基硼烷的来源。搅拌功率传递至至少0.25kW / m 3的聚合混合物。

9. 发明授权

US4533379A Herbicidal urea compounds 失效
标题翻译：除草脲类化合物
公开(公告)号：US4533379A
公开(公告)日：1985-08-06
申请号：US504349
申请日：1983-06-14
申请人： Robert van Helden , Frank Baardman , Johannes L. M. Syrier
发明人： Robert van Helden , Frank Baardman , Johannes L. M. Syrier
IPC分类号： A01N47/30 , C07C205/19 , C07C205/34 , C07C275/32 , C07D319/06 , C07D319/08 , C07D327/10 , A01N43/00 , C07D319/00
CPC分类号： C07D319/08 , A01N47/30 , C07C205/19 , C07C205/34 , C07C275/32 , C07D319/06 , C07D327/10
摘要： Novel compounds of the general formula ##STR1## wherein R represents a hydrogen or halogen atom or a (cyclo) alkyl group, R.sup.3 represents H, CH.sub.3, or OCH.sub.3, n=0 or 1, and when n=0, R.sup.2 represents a hydrogen atom and R.sup.1 a hydrogen atom or a monovalent substituent thereby forming an alkoxide, ether, ester, or other alcohol derivative, and when n=1, each R.sup.1 and R.sup.2 independently represents one of the atoms specified for R.sup.1 when n=0, or R.sup.1 and R.sup.2 together represent a bivalent group thereby forming a cyclic ether, ester, or other diol derivative, have useful herbicidal properties.
摘要翻译：新颖的通式的化合物，其中R表示氢或卤素原子或（环）烷基，R3表示H，CH3或OCH3，n = 0或1，当n = 0时，R2表示氢原子和R 1为氢原子或一价取代基，由此形成醇盐，醚，酯或其它醇衍生物，当n = 1时，每个R 1和R 2独立地表示当n = 0时为R 1规定的原子之一，或R 1 并且R2一起代表二价基，从而形成环醚，酯或其它二醇衍生物，具有有用的除草性质。

10. 发明授权

US3965204A Preparation of derivatives of cyclobutane and cyclobutene 失效
标题翻译：环丁烷和环丁烯衍生物的制备
公开(公告)号：US3965204A
公开(公告)日：1976-06-22
申请号：US468949
申请日：1974-05-10
申请人： Joachim H. Lukas , Frank Baardman , Adriaan P. Kouwenhoven
发明人： Joachim H. Lukas , Frank Baardman , Adriaan P. Kouwenhoven
IPC分类号： B01J27/00 , C07B61/00 , C07C1/00 , C07C2/42 , C07C13/06 , C07C13/32 , C07C13/38 , C07C13/44 , C07C67/00 , C07C3/03
CPC分类号： C07C13/44 , C07C13/06 , C07C13/38 , C07C2/42 , C07C2101/04 , C07C2102/18 , C07C2102/50 , C07C2531/14
摘要： Preparation of alkylidenecyclobutane derivatives and of cyclobutene derivatives by contacting a (cyclo)alkene with an allene or with a 1-alkyne in the liquid phase in the presence of a dissolved Lewis acid derived from an element of Group III A of the Periodic Table of the Elements, titanium, tin, antimony, tantalum, rhenium, iron, or zinc.
摘要翻译：通过使（环）烯与丙烯或与1-炔炔在液相中，在衍生自元素周期表第IIIA族元素的溶解路易斯酸的存在下，制备亚烷基环丁烷衍生物和环丁烯衍生物元素，钛，锡，锑，钽，铼，铁或锌。

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