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    • 1. 发明授权
    • Process for co-production of metaxylene and paraxylene
    • 共生产间二甲苯和对二甲苯的方法
    • US06359186B1
    • 2002-03-19
    • US09382577
    • 1999-08-25
    • Gérard HotierLarry MankFrançoise Montecot
    • Gérard HotierLarry MankFrançoise Montecot
    • C07C712
    • C07C7/12C07C15/08
    • For co-production of metaxylene and paraxylene from a feedstock (line-4) of hydrocarbons, there is employed a simulated moving bed chromatographic column 5 having at least five zones and which delivers an extract, a raffinate and an intermediate raffinate. The feedstock has an ethylbenzene content of less than 5% by weight, and the chromatographic column comprises at least twenty-five beds, of which at least five beds are in zone 3B. The raffinate is distilled (31) to recover the metaxylene at a purity of at least 99% and orthoxylene. The extract is distilled (7, 10) to recover the paraxylene at a purity of at least 99.6%. The recovered isomers can be synthesized into isophthalic acid and terephthalic acid.
    • 为了从烃的原料(管线-4)共同生产间二甲苯和对二甲苯,使用具有至少五个区并且提供萃取物,萃余液和中间萃余液的模拟移动床色谱柱5。 原料的乙苯含量小于5重量%,色谱柱包含至少二十五张床,其中至少五张床位于3B区。 蒸馏塔(31)以回收至少99%纯度的邻二甲苯和邻二甲苯。 将提取物蒸馏(7,10)以回收纯度至少为99.6%的对二甲苯。 回收的异构体可以合成为间苯二甲酸和对苯二甲酸。