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    • 3. 发明授权
    • Dense fine grained monotungsten carbide-transition metal cemented
carbide body and preparation thereof
    • 密集细晶碳化钨 - 过渡金属硬质合金体及其制备
    • US5773735A
    • 1998-06-30
    • US752513
    • 1996-11-20
    • Ellen M. DubenskyRobert T. Nilsson
    • Ellen M. DubenskyRobert T. Nilsson
    • B22F3/15C22C1/05C22C29/08C22C29/00
    • B22F3/156C22C1/051C22C29/08B22F2998/00
    • A cemented tungsten carbide body having a transition metal binder phase selected from the group consisting of iron, nickel and cobalt is formed, wherein the WC grains have an average WC grain size of at most about 0.5 micrometer in diameter and a maximum WC grain size of at most about 0.8 micrometer in diameter. Also, about 50 percent by volume of the WC grains in the body are angular grains and the body (1) contains an amount of the transition metal ranging from about 3 percent to about 18 percent by weight of the body, (2) is essentially free of grain growth inhibitors and (3) is essentially pore free. Said cemented tungsten carbide body is formed by mechanically mixing a source of WC with a source of transition metal, shaping the mixture into a porous body and sintering the porous body at a sintering temperature, superatmospheric pressure and time at temperature and time at superatmospheric pressure sufficient to form the cemented tungsten carbide body, wherein the sintering occurs without the formation of a liquid in the body and at least a portion of the time at superatmospheric pressure is at the sintering temperature.
    • 形成具有从铁,镍和钴组成的组中选择的过渡金属粘合剂相的硬质合金碳化物体,其中WC颗粒的平均WC晶粒尺寸直径至多为0.5微米,最大WC晶粒尺寸为 直径最大约为0.8微米。 另外,身体中大约50体积%的WC颗粒是角状颗粒,并且身体(1)含有一定量的过渡金属,其量约为本体重量的约3%至约18%,(2)本质上 没有晶粒生长抑制剂和(3)基本上是无孔的。 所述粘结碳化钨体通过将WC源与过渡金属源机械混合而形成,将混合物成形为多孔体,并在烧结温度,超大气压力和超高压下的时间和温度和时间下在足够大的压力下烧结多孔体 以形成粘结碳化钨体,其中在不在体内形成液体的情况下进行烧结,并且在超大气压下的至少一部分时间处于烧结温度。