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1. 发明申请

US20120148808A1 TRANSPARENT FLUORINE-CONTAINING POLYMER 有权
标题翻译：透明含氟聚合物
公开(公告)号：US20120148808A1
公开(公告)日：2012-06-14
申请号：US13391056
申请日：2010-08-16
申请人： Toshio Kubota , Takehiro Nagasawa , Akira Hirooka , Makoto Hirooka , Eiko Hirooka
发明人： Toshio Kubota , Takehiro Nagasawa , Akira Hirooka , Makoto Hirooka , Eiko Hirooka
IPC分类号： B32B3/00 , C08F220/06 , C08L33/02 , C08L33/10 , C08F220/10 , C08F8/00
CPC分类号： C08F220/18 , C08F216/125 , Y10T428/24802 , C08F220/12
摘要： Disclosed is a fluorine-containing polymer obtained by polymerizing a 1,6-diene-type ether compound represented by formula [1] and, for example, a (meth)acrylic acid compound represented by formula [2]. The fluorine-containing polymer shows high transparency, has a high glass transition point, and is soluble in a solvent and therefore has moldability. In the case where a (meth)acrylic unit has a reactive substituent, by utilizing the crosslinking reaction thereof, a thin film having high solvent resistance can be produced. In formulae [1] and [21, R1 and R2 each independently represent a hydrogen atom or an alkyl group having 1 to 12 carbon atoms, which may be substituted, R3 represents a hydrogen atom, a fluorine atom, or a methyl group, and R4 represents a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, which may be substituted, or an aromatic group having 5 to 10 ring members, which may be substituted.
摘要翻译：公开了通过使由式[1]表示的1,6-二烯型醚化合物和例如由式[2]表示的（甲基）丙烯酸化合物聚合而获得的含氟聚合物。含氟聚合物显示高透明度，玻璃化转变点高，并且溶于溶剂，因此具有成型性。在（甲基）丙烯酸单元具有反应性取代基的情况下，通过利用其交联反应，可以制备耐溶剂性高的薄膜。在式[1]和[21]中，R 1和R 2各自独立地表示氢原子或碳原子数1〜12的烷基，可以被取代，R 3表示氢原子，氟原子或甲基， R4表示氢原子，可以被取代的碳原子数1〜12的烷基或可以被取代的环状成员5〜10的芳香族基。

2. 发明申请

US20110281090A1 GERMANIUM-CONTAINING HIGH-REFRACTIVE-INDEX THIN FILM AND PRODUCTION METHOD THEREOF 审中-公开
标题翻译：含锗的高折射率薄膜及其生产方法
公开(公告)号：US20110281090A1
公开(公告)日：2011-11-17
申请号：US13127180
申请日：2009-11-11
申请人： Akira Watanabe , Tokuji Miyashita , Takehiro Nagasawa , Akira Hirooka , Makoto Hirooka , Eiko Hirooka
发明人： Akira Watanabe , Tokuji Miyashita , Takehiro Nagasawa , Akira Hirooka , Makoto Hirooka , Eiko Hirooka
IPC分类号： C08G79/00
CPC分类号： G02B1/10 , C07F7/30 , C08G79/00 , C09D185/00 , G02B1/00 , G02B1/118 , Y10T428/24942
摘要： There is provided a high refractive-index coating film and a production method of the high refractive-index coating film. The production method comprises producing a coating film containing a germanium compound containing a Ge—Ge bond as a backbone thereof, and baking the coating film under vacuum or in an inert gas atmosphere. The high refractive-index coating film produced by the method is soluble in a solvent and has a high moldability and film-formation property, and has a high refractive index of 1.8 or more and further 2.3 or more, and is chemically stable.
摘要翻译：提供高折射率涂膜和高折射率涂膜的制造方法。该制造方法包括制造含有Ge-Ge键的锗化合物作为其主链的涂膜，并在真空或惰性气体气氛下烘烤该涂膜。通过该方法制造的高折射率涂膜可溶于溶剂，成型性和成膜性高，折射率高1.8以上2.3以上，化学稳定。

3. 发明授权

US08871332B2 Transparent fluorine-containing polymer 有权
标题翻译：透明含氟聚合物
公开(公告)号：US08871332B2
公开(公告)日：2014-10-28
申请号：US13391056
申请日：2010-08-16
申请人： Toshio Kubota , Takehiro Nagasawa , Makoto Hirooka , Eiko Hirooka
发明人： Toshio Kubota , Takehiro Nagasawa , Akira Hirooka
IPC分类号： B32B3/00 , C08F220/06 , C08L33/02 , C08L33/10 , C08F8/00 , C08F220/18 , C08F216/12
CPC分类号： C08F220/18 , C08F216/125 , Y10T428/24802 , C08F220/12
摘要： Disclosed is a fluorine-containing polymer obtained by polymerizing a 1,6-diene-type ether compound represented by formula [1] and, for example, a (meth)acrylic acid compound represented by formula [2]. The fluorine-containing polymer shows high transparency, has a high glass transition point, and is soluble in a solvent and therefore has moldability. In the case where a (meth)acrylic unit has a reactive substituent, by utilizing the crosslinking reaction thereof, a thin film having high solvent resistance can be produced. In formulae [1] and [2], R1 and R2 each independently represent a hydrogen atom or an alkyl group having 1 to 12 carbon atoms, which may be substituted, R3 represents a hydrogen atom, a fluorine atom, or a methyl group, and R4 represents a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, which may be substituted, or an aromatic group having 5 to 10 ring members, which may be substituted.
摘要翻译：公开了通过使由式[1]表示的1,6-二烯型醚化合物和例如由式[2]表示的（甲基）丙烯酸化合物聚合而获得的含氟聚合物。含氟聚合物显示高透明度，玻璃化转变点高，并且溶于溶剂，因此具有成型性。在（甲基）丙烯酸单元具有反应性取代基的情况下，通过利用其交联反应，可以制备耐溶剂性高的薄膜。在式[1]和[2]中，R 1和R 2各自独立地表示氢原子或碳原子数1〜12的烷基，可以被取代，R 3表示氢原子，氟原子或甲基， R 4表示氢原子，可以被取代的碳原子数1〜12的烷基或可以被取代的环状成员5〜10的芳香族基。

4. 发明申请

US20120065320A1 FLUORINE-CONTAINING 1,6-DIENE ETHER COMPOUND AND FLUORINE-CONTAINING POLYMER 审中-公开
标题翻译：含氟的1,6-二烯醚化合物和含氟聚合物
公开(公告)号：US20120065320A1
公开(公告)日：2012-03-15
申请号：US13321311
申请日：2010-05-18
申请人： Toshio Kubota , Ko-ichi Yanai , Takehiro Nagasawa , Akira Hirooka , Makoto Hirooka , Eiko Hirooka
发明人： Toshio Kubota , Ko-ichi Yanai , Takehiro Nagasawa , Akira Hirooka , Makoto Hirooka , Eiko Hirooka
IPC分类号： C08F16/32 , C07C43/192 , C09D129/10
CPC分类号： C07C43/192 , C07C2601/10 , C08F216/125
摘要： A fluorine-containing polymer obtained using a 1,6-diene ether compound represented by formula [1] is a high-performance polymer exhibiting a low refractive index, high glass transition point, a high degree of transparency, and solubility in solvents. There are many potential uses, such as use as a coating material or bulk material. For example, said polymer could be effectively used in high-tech fields such as: optical materials such as low-reflection films and optical waveguide cladding; semiconductor materials such as pellicles and resists in semiconductor lithography; and protective film materials, insulating film materials, and water-repellent materials. (In the formula, R1 represents a C6-18 aryl group or a C1-12 alkyl group, which may be substituted.)
摘要翻译：使用由式[1]表示的1,6-二烯烃化合物获得的含氟聚合物是表现出低折射率，高玻璃化转变点，高透明度和在溶剂中的溶解性的高性能聚合物。有许多潜在用途，例如用作涂层材料或散装材料。例如，所述聚合物可以有效地用于高科技领域，如：低反射膜和光波导包层等光学材料; 半导体光刻中的薄膜和抗蚀剂等半导体材料; 保护膜材料，绝缘膜材料和防水材料。（式中，R1表示可以被取代的C6-18芳基或C1-12烷基。）

5. 发明授权

US5282136A Vertical releasing control device of crane hanging load 失效
标题翻译：起重机吊装垂直释放控制装置
公开(公告)号：US5282136A
公开(公告)日：1994-01-25
申请号：US677337
申请日：1991-03-29
申请人： Hiroshi Zui , Hideaki Yoshimatsu , Eiko Hirooka , Koichi Fukushima
发明人： Hiroshi Zui , Hideaki Yoshimatsu , Eiko Hirooka , Koichi Fukushima
IPC分类号： B66C13/06 , B66C13/20 , B66C13/22 , B66C23/00
CPC分类号： B66C13/20 , B66C13/063
摘要： For use where a hanging load 81 is vertically hung and released with a crane having either a jib or a boom which can be raised or lowered, or where a long hanging load 81 is raised from its lowered state to its vertical state so as to be hung-up and released a control device of the has a control section for performing automatically the raising of the jib 60 or boom 61 and the winding-up or -down of the winding-up rope 70, in cooperation with each other in response to their initial states. In case that the initial angle of the jib or boom is large or small, it is controlled in such a way as a rate of variation of the hanging load .DELTA.T applied to the winding-up rope 70 becomes constant. It positions the extreme end of the jib or boom on the vertical line passing through a center of gravity of the hanging load. With such a control device, the handing load is not oscillated and a smooth vertical releasing is carried out. An entire long hanging load 81 is vertically hung up and released from the ground after its vertical releasing without displacing the position of the other end from its lowered state.
摘要翻译：对于悬挂载荷81垂直悬挂并用具有可升降的起重臂或吊臂的起重机或者其中长悬挂载荷81从其降低状态升高到其垂直状态的吊装装置81，以便于挂起并释放一个控制装置，该控制装置具有一个控制部分，用于自动执行起重臂60或起重臂61的升起以及绕组绳索70的卷起或下降，以响应于他们的初始状态。在起重臂或起重臂的初始角度大或小的情况下，以对施加到卷绕绳索70的悬挂载荷（Delta）T的变化率变得恒定的方式进行控制。它将起重臂或起重臂的最末端定位在通过悬挂载荷重心的垂直线上。利用这种控制装置，处理负载不振荡，并且执行平滑的垂直释放。整个长悬挂装置81在其垂直释放之后垂直地悬挂并从地面释放，而不会使另一端的位置从其降低的状态移位。

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