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    • 1. 发明授权
    • Phosphate-built automatic dishwashing composition comprising catalysts
    • 含磷酸盐的自动餐具洗涤组合物包含催化剂
    • US5939373A
    • 1999-08-17
    • US28633
    • 1998-02-24
    • Donna Jean HaeggbergWilliam Michael Scheper
    • Donna Jean HaeggbergWilliam Michael Scheper
    • C11D3/02C11D1/722C11D3/06C11D3/16C11D3/36C11D3/39C11D3/395C11D17/00C11D7/16C11D7/18C11D7/42
    • C11D1/722C11D17/0039C11D3/06C11D3/3927C11D3/3932C11D3/3935
    • Automatic dishwashing detergent compositions comprising phosphate builder and metal-containing bleach catalyst, preferably catalysts containing manganese and/or selected from selected cobalt/ammonia catalysts. Preferred compositions comprise cobalt bleach catalyst having the formula:�Co(NH3).sub.n (M).sub.m (B).sub.b !T.sub.ywherein cobalt is in the +3 oxidation state; n is 4 or 5 (preferably 5); M is one or more ligands coordinated to the cobalt by one site; B is a ligand coordinated to the cobalt by two sites; b is 0 or 1 (preferably 0); and when b=0, then m+n 6, and when b=1, then m=0 and n=4; and T is one or more appropriately selected counteranions present in a number y, wherein y is an integer to obtain a charge-balanced salt (preferably y is 1-3; most preferably 2 when T is a -1 charged anion); and wherein further the catalyst has a base hydrolysis rate constant of less than 0.23M.sup.-1 s.sup.-1 at 25.degree. C. Preferred automatic dishwashing compositions further comprise amylase and/or protease.
    • 包括磷酸盐助洗剂和含金属的漂白催化剂的自动餐具洗涤剂组合物,优选含有锰和/或选自选择的钴/氨催化剂的催化剂。 优选的组合物包含具有下式的钴漂白催化剂:[Co(NH 3)n(M)m(B)b]其中钴处于+3氧化态; n为4或5(优选5); M是通过一个位点与钴配位的一种或多种配体; B是通过两个位点与钴配位的配体; b为0或1(优选0); 当b = 0时,m + n 6,当b = 1时,m = 0,n = 4; 并且T是存在于数y中的一个或多个适当选择的余离子,其中y是获得电荷平衡盐的整数(优选地,y为1-3;当T为带负电荷的阴离子时,最优选为2)。 并且其中所述催化剂在25℃下的碱水解速率常数小于0.23M-1s -1。优选的自动餐具洗涤组合物还包含淀粉酶和/或蛋白酶。
    • 2. 发明授权
    • Compositions including ether-capped poly(oxyalkylated) alcohol surfactants
    • 组合物包括醚封端的聚(烷氧基化)醇表面活性剂
    • US06593287B1
    • 2003-07-15
    • US09660363
    • 2000-09-12
    • Glenn Thomas Jordan, IVWilliam Michael ScheperMark Robert SivikDonna Jean HaeggbergBernard William Kluesener
    • Glenn Thomas Jordan, IVWilliam Michael ScheperMark Robert SivikDonna Jean HaeggbergBernard William Kluesener
    • C11D172
    • A61K8/39A61Q5/02A61Q19/10C11D1/721C11D1/75C11D1/825
    • Compositions including ether-capped poly(oxyalkylated) alcohol surfactants having superior grease cleaning abilities and improved spotting/filming benefits are provided. The alcohol surfactants have the formula: RO(R1O)xR2 wherein, R is selected from the group consisting of linear or branched, saturated or unsaturated, substituted or unsubstituted, aliphatic or aromatic hydrocarbon radicals having from about 1 to about 30 carbon atoms; R1 may be the same or different, and is independently selected from the group consisting of branched or linear C2 to C7 alkylene in any given molecule; R2 is selected from the group consisting of: (i) a 4 to 8 membered substituted, or unsubstituted heterocyclic ring containing from 1 to 3 hetero atoms; (ii) a 7 to 13 membered substituted, or unsubstituted polycyclic ring; (iii) a hydrocarbon of the formula: —(CH2)y—X  wherein, y is an integer from 1 to 7, X is a 4 to 8 membered substituted, or unsubstituted, saturated or unsaturated cyclic or aromatic hydrocarbon radical; and (iv) a hydrocarbon radical of the formula: —C(CH3)2R3  wherein R3 is selected from the group consisting of linear or branched, saturated or unsaturated, substituted or unsubstituted, aliphatic or aromatic hydrocarbon radicals having from about 1 to about 30 carbon atoms, provided that when R3 is methyl, R is branched; wherein x is a number from 1 to about 30.
    • 提供了包括具有优异的油脂清洁能力和改进的斑点/成膜益处的具有醚封端的聚(烷氧基化)醇表面活性剂的组合物。 醇表面活性剂具有下式:其中R选自具有约1至约30个碳原子的直链或支链,饱和或不饱和的取代或未取代的脂族或芳族烃基; R 1可以相同或不同,并且独立地选自任何给定分子中的支链或直链C2至C7亚烷基; R2选自:(i)含有1至3个杂原子的4至8元取代或未取代的杂环;(ii)7至13元取代或未取代的多环;(iii) 下式的烃:其中,y是1至7的整数,X是4至8元取代或未取代的饱和或不饱和的环状或芳族烃基; 和(iv)下式的烃基:其中R 3选自具有约1至约30个碳原子的直链或支链,饱和或不饱和的,取代或未取代的脂族或芳族烃基,条件是当 R3是甲基,R是支链的;其中x是从1到大约30的数。
    • 9. 发明授权
    • Ether-capped poly(oxyalkylated) alcohol surfactants
    • 醚封端的聚(烷氧基化)醇表面活性剂
    • US06844309B1
    • 2005-01-18
    • US09660175
    • 2000-09-12
    • Mark Robert SivikGlenn Thomas Jordan, IVBernard William KluesenerWilliam Michael ScheperDonna Jean HaeggbergKristen Lynne McKenzie
    • Mark Robert SivikGlenn Thomas Jordan, IVBernard William KluesenerWilliam Michael ScheperDonna Jean HaeggbergKristen Lynne McKenzie
    • C07C43/11C07C43/164C07D307/32C07D309/12C11D1/72C11D1/722C11D3/37
    • C07D307/32C07C43/11C07C43/164C07D309/12C11D1/721
    • Ether-capped poly(oxyalkylated) alcohol surfactants having superior grease cleaning abilities and improved spotting/filming benefits are provided. The alcohol surfactants have the formula: RO(R1O)xR2 wherein, R is selected from the group consisting of linear or branched, saturated or unsaturated, substituted or unsubstituted, aliphatic or aromatic hydrocarbon radicals having from about 1 to about 30 carbon atoms; R1 may be the same or different, and is independently selected from the group consisting of branched or linear C2 to C7 alkylene in any given molecule; R2 is selected from the group consisting of: (i) a 4 to 8 membered substituted, or unsubstituted heterocyclic ring containing from 1 to 3 hetero atoms; (ii) a 7 to 13 membered substituted, or unsubstituted polycyclic ring; (iii) a hydrocarbon of the formula: —(CH2)y—X  wherein, y is an integer from 1 to 7, X is a 4 to 8 membered substituted, or unsubstituted, saturated or unsaturated cyclic or aromatic hydrocarbon radical; and (iv) a hydrocarbon radical of the formula: —C(CH3)2R3  wherein R3 is selected from the group consisting of linear or branched, saturated or unsaturated, substituted or unsubstituted, aliphatic or aromatic hydrocarbon radicals having from about 1 to about 30 carbon atoms, provided that when R3 is methyl, R is branched; wherein x is a number from 1 to about 30.
    • 提供了具有优异的油脂清洁能力和改善的点样/成膜效益的具有醚封端的聚(烷氧基化)醇表面活性剂。 醇表面活性剂具有下式:其中R选自具有约1至约30个碳原子的直链或支链,饱和或不饱和的取代或未取代的脂族或芳族烃基; R 1可以相同或不同,并且独立地选自任何给定分子中的支链或直链C2至C7亚烷基; R 2选自:(i)含有1至3个杂原子的4至8元取代或未取代的杂环;(ii)7至13元取代或未取代的多环;( iii)下式的烃:其中,y是1至7的整数,X是4至8元取代或未取代的饱和或不饱和的环状或芳族烃基; 和(iv)下式的烃基:其中R 3选自具有约1至约30个碳原子的直链或支链,饱和或不饱和的取代或未取代的脂族或芳族烃基, 条件是当R 3为甲基时,R为支链;其中x为1至约30的数。