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    • 1. 发明申请
    • Low odor compositions and methods to attain low odor compositions
    • 低气味组合物和获得低气味组合物的方法
    • US20110166257A1
    • 2011-07-07
    • US12928408
    • 2010-12-10
    • James BohlingPaul F. DollDavid E. FrattarelliKathleen R. MannaAlvin M. Maurice
    • James BohlingPaul F. DollDavid E. FrattarelliKathleen R. MannaAlvin M. Maurice
    • C09D131/04C09D189/00C08J3/00C09D133/06
    • C08F6/006C09D131/04C08L33/06C08L31/02
    • This invention provides stable aqueous compositions including stable coating compositions, and methods of their production. The stable aqueous compositions and stable aqueous coating compositions comprise i) an aqueous dispersion of one or more emulsion-polymerized addition polymer comprising polymerized units of one or more carboxylester monomer, wherein at least one carboxylester monomer is a vinyl ester monomer; ii) one or more carboxylesterase enzyme; iii) one or more mono-alcohol with a formula molecular weight of less than 76; iv) optionally, acetaldehyde; and v) optionally, one or more organic carboxylester with a normal boiling point of less than 150° C.; and wherein the aqueous composition has a headspace volatile organic compound(VOC) content, as measured by headspace gas chromatography-mass spectrometry (GC-MS) at 33° C., characterized by a content of less than 10 ppm of acetaldehyde, and less than 10 ppm of the one or more organic carboxylester, and more than 50 ppm of the one or more mono-alcohol. Preferably, the ester hydrolysis activity in the composition is less than 0.010 micromole/minute.
    • 本发明提供稳定的含水组合物,包括稳定的涂料组合物及其生产方法。 稳定的含水组合物和稳定的水性涂料组合物包含i)一种或多种乳液聚合的加成聚合物的水分散体,其包含一个或多个羧酸酯单体的聚合单元,其中至少一个羧酸酯单体是乙烯基酯单体; ii)一种或多种羧酸酯酶; iii)一种或多种具有式分子量小于76的单醇; iv)任选的乙醛; 和v)任选的一种或多种正常沸点低于150℃的有机羧酸酯; 并且其中所述含水组合物具有顶空挥发性有机化合物(VOC)含量,其通过顶空气相色谱 - 质谱(GC-MS)在33℃下测量,其特征在于小于10ppm的乙醛含量和较少 超过10ppm的一种或多种有机羧酸酯,以及大于50ppm的一种或多种单醇。 优选地,组合物中的酯水解活性小于0.010微摩尔/分钟。