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    • 1. 发明授权
    • Chelating negative charge director for liquid electrographic toner
    • 液体电摄影调色剂的螯合负电荷导向器
    • US5393635A
    • 1995-02-28
    • US99021
    • 1993-07-28
    • Dale D. RussellJames G. Bearss
    • Dale D. RussellJames G. Bearss
    • G03G9/12G03G9/13G03G9/135
    • G03G9/13G03G9/135G03G9/1355
    • The invention is a negative charge director for liquid electrographic toners. The charge director comprises a very weakly associating, charged functional group covalently bonded in the resin coating of the toner particle, and a very strongly chelating, preferably neutrally charged, molecule dispersed in the liquid phase to achieve charge separation. The weak association site on the resin is prepared, via well-known ion-exchange chemistry, in the metal form desired. Preferred metals are those with no regulatory, health or environmental issues, such as K+, Na+, Ca.sup.2+, Al.sup.3+, Zn.sup.2+, Zr.sup.4+, Mg.sup.2+, ammonium (NH.sub.4 +), and organic cations.The cation-associated resin is brought into dispersion with the solution phase chelating molecule. When this is done, the equilibria that compete for the cation are such that it is released from the resin and bound in the chelate. The toner particle is left with a net negative charge which is permanent, but which is balanced by an equal, opposite charge on the chelated cationic species in the continuous phase. Preferably, there are no other sources of charge in the dispersion, and there is no excess of charge carriers in the continuous phase which would interfere with development.
    • 本发明是液体电摄像调色剂的负电荷导向器。 电荷导向剂包括共价结合在调色剂颗粒的树脂涂层中的非常弱缔合的带电官能团,以及分散在液相中非常强的螯合,优选中性带电的分子以实现电荷分离。 通过众所周知的离子交换化学,以所需的金属形式制备树脂上的弱缔合位点。 优选的金属是没有调节,健康或环境问题的金属,如K +,Na +,Ca2 +,Al3 +,Zn2 +,Zr4 +,Mg2 +,铵(NH4 +)和有机阳离子。 将阳离子相关树脂与溶液相螯合分子分散。 当这样做时,竞争阳离子的平衡使其从树脂中释放并结合在螯合物中。 剩余的调色剂颗粒具有永久性的净负电荷,但在连续相中的螯合阳离子物质上由相等的相反电荷平衡。 优选地,在分散体中不存在其它电荷源,并且在连续相中不会导致过量的电荷载体干扰显影。
    • 5. 发明授权
    • Mercury selective electrode
    • 汞选择电极
    • US06436259B1
    • 2002-08-20
    • US09144574
    • 1998-08-31
    • Dale D. Russell
    • Dale D. Russell
    • G01N2726
    • G01N27/30
    • The present invention is an apparatus for laboratory and field use in detecting and measuring Hg+ and Hg2+ in sample. A selective mercury binding agent, such as a chelating agent or clathrating agent, is covalently bound in a copolymer and deposited as an electrode layer. To prepare the preferred apparatus of the invention, thiophene, or other, similar monomer, is derivatized by covalent attachment thereto of Kryptofix-21™ (1,4,10-trioxa-7,13-diazacyclopentadecane) in the 3-position. The thiophene monomer and Kryptofix-21™ are co-polymerized and electrodeposited by known techniques onto a conductive substrate, such as platinum or glassy carbon, to obtain a multi-layer polymer coating of desired thickness. The resulting coated electrode has selective coordination sites for mercury of the order of Kf=1016, compared to Kf=103 for cadmium, Kf=105 for lead and Kf=105 for silver. Therefore, the resulting probe is very selective for mercury, compared to cadmium, lead and silver.
    • 本发明是用于检测和测量样品中Hg +和Hg 2+的实验室和现场使​​用的装置。 选择性汞结合剂,例如螯合剂或包合剂,共价结合在共聚物中并沉积为电极层。 为了制备本发明的优选装置,噻吩或其它类似单体通过与3-位上的Kryptofix-21 TM(1,4,10-三氧杂-7,13-二氮杂环十五烷)共价连接而衍生化 。 噻吩单体和Kryptofix-21 TM通过已知技术共聚并电沉积到诸如铂或玻璃碳的导电基材上,以获得所需厚度的多层聚合物涂层。 所得到的涂覆电极具有Kf = 1016量级的汞的选择性配位位点,镉的Kf = 103,对于铅为Kf = 105,对于银为Kf = 105。 因此,与镉,铅和银相比,所得到的探针对汞是非常有选择性的。
    • 6. 发明授权
    • Electrophotographic imaging with toners of opposite sign electrical
charge
    • 电子照相成像与墨粉相反符号电荷
    • US5450189A
    • 1995-09-12
    • US196937
    • 1994-02-15
    • Dale D. RussellJames G. Bearss
    • Dale D. RussellJames G. Bearss
    • G03G13/01G03G15/01
    • G03G13/01G03G15/0126
    • A system and method for electrophotographic printing an image with a plurality of toners, where the plurality of toners includes toners that are attracted to either a first charge potential or a second charge potential. The electrophotographic system includes a photoconductive surface that is charged to the second charge potential. A laser selectively discharges the photoconductive surface to the first charge potential in accordance the image to be printed. Those toners that are attracted to the first charge potential are applied to the photoconductive surface, wherein the toners are electrostatically attracted to those areas of the photoconductive surface that are at the first charge potential. The photoconductive surface again charged to the second charge potential. The photoconductive surface is again discharged to the first charge potential in accordance with those areas of the image to which those toners that are attracted to the second charge potential are to be repelled. Those toners that are attracted to the second charge potential are applied to the photoconductive surface, wherein the toners are electrostatically attracted to those areas of the photoconductive surface that remain at the first charge potential. Finally, the image is transferred to a receiving surface.
    • 一种用于利用多个调色剂电子照相印刷图像的系统和方法,其中多个调色剂包括被吸引到第一电荷电位或第二充电电位的调色剂。 电子照相系统包括充电到第二充电电位的光电导表面。 激光器根据要印刷的图像选择性地将光电导面放电到第一充电电位。 被吸引到第一电荷电位的那些调色剂被施加到光电导表面,其中调色剂被静电吸引到处于第一充电电位的光导表面的那些区域。 光电导表面再次充电到第二电荷电位。 根据被吸引到第二充电电位的那些调色剂要被排斥的图像的那些区域,再次将光电导表面放电到第一充电电位。 被吸引到第二电荷电位的那些调色剂被施加到光电导表面,其中调色剂被静电吸引到保持在第一电荷电位的光导表面的那些区域。 最后,图像被传送到接收表面。
    • 7. 发明授权
    • Cage complexes for charge direction in liquid toners
    • 笼式复合物用于液体调色剂中的电荷方向
    • US5589311A
    • 1996-12-31
    • US345144
    • 1994-11-28
    • Dale D. Russell
    • Dale D. Russell
    • G03G9/135
    • G03G9/135G03G9/1355
    • Disclosed are negatively and positively charged liquid toners for electrophotography (EP). The charge on the toner particle is obtained by adding cage complex molecules, or clathrates/cryptates, to the liquid toner. The cage complex molecules have at least three chains, with at least one electron pair donor atom in each chain, for a total of at least three electron pair donor atoms (EPD's). Or, the cage complex molecules have at least two connected rings, with a total of at least three EPD's in the molecule including at least one EPD in each of the connected rings. For negatively charged toner particles, the clathrates/cryptates are distributed in the liquid dispersion, and metal cations are weakly associated with anionic functional groups on the toner particle. This way, the clathrates/cryptates in dispersion complex selectively with the cations and strip them from the toner particle, leaving a negatively charged particle. For positively charged toner particles, the clathrates/cryptates are covalently bound to the toner particles, and weakly associated metal cations are added with corresponding anionic species to the liquid dispersion. This way, the clathrates/cryptates on the toner particles complex selectively with the cations, and strip them from the dispersion, creating a positively charged particle.
    • 公开了负电和带正电的液晶电视机(EP)液体调色剂。 调色剂颗粒上的电荷是通过将笼状络合物分子或包合物/隐蔽剂加入到液体调色剂中而获得的。 笼状复合分子具有至少三个链,每个链中至少有一个电子对供体原子,总共至少三个电子对供体原子(EPD)。 或者,笼状复合分子具有至少两个连接的环,在分子中总共具有至少三个EPD,包括每个连接环中的至少一个EPD。 对于带负电荷的调色剂颗粒,包合物/隐蔽剂分布在液体分散体中,并且金属阳离子与调色剂颗粒上的阴离子官能团弱相关。 这样,分散体中的包合物/穴状物与阳离子选择性地混合并将其从调色剂颗粒上剥离,留下带负电的颗粒。 对于带正电荷的调色剂颗粒,包合物/隐蔽物与调色剂颗粒共价结合,并且弱相关金属阳离子与液体分散体中加入相应的阴离子物质。 这样,调色剂颗粒上的包合物/穴状物与阳离子选择性地复合,并从分散体中剥离,产生带正电的颗粒。
    • 8. 发明授权
    • Cage complexes for charge direction in liquid toners
    • 笼式复合物用于液体调色剂中的电荷方向
    • US5529875A
    • 1996-06-25
    • US424699
    • 1995-04-19
    • Dale D. Russell
    • Dale D. Russell
    • G03G9/135
    • G03G9/135G03G9/1355
    • Disclosed are negatively and positively charged liquid toners for eleotrophotography (EP). The charge on the toner particle is obtained by adding cage complex molecules, or clathrates/cryptates, to the liquid toner. The cage complex molecules have at least three chains, with a least one electron pair donor atom in each chain, for a total of at least three electron pair donor atoms (EPD's). Or, the cage complex molecules have at least two connected rings, with a total of at least three EPD's in the molecule including at least one EPD in each of the connected rings. For negatively charged toner particles, the clathrates/cryptates are distributed in the liquid dispersion, and metal cations are weakly associated with anionic functional groups on the toner particle. This way, the clathrates/cryptates in dispersion complex selectively with the cations and strip them from the toner particle, leaving a negatively charged particle. For positively charged toner parities, the clathrates/cryptates are covalently bound to the toner particles, and weakly associated metal cations are added with corresponding anionic species to the liquid dispersion. This way, the clathrates/cryptaes on the toner particles complex selectively with the cations, and strip them from the dispersion, creating a positively charged particle.
    • 公开了用于电子照相(EP)的带负电和带正电的液体调色剂。 调色剂颗粒上的电荷是通过将笼状络合物分子或包合物/隐蔽剂加入到液体调色剂中而获得的。 笼状络合物分子具有至少三个链,每个链中至少有一个电子对供体原子,总共至少三个电子对供体原子(EPD)。 或者,笼状复合分子具有至少两个连接的环,在分子中总共具有至少三个EPD,包括每个连接环中的至少一个EPD。 对于带负电荷的调色剂颗粒,包合物/隐蔽剂分布在液体分散体中,并且金属阳离子与调色剂颗粒上的阴离子官能团弱相关。 这样,分散体中的包合物/穴状物与阳离子选择性地混合并将其从调色剂颗粒上剥离,留下带负电的颗粒。 对于带正电的调色剂,包合物/隐蔽剂共价结合到调色剂颗粒上,并且与相关联的阴离子物质向弱液相分散体中加入弱结合的金属阳离子。 这样,调色剂颗粒上的包合物/隐窝物与阳离子选择性地复合,并将其从分散体中剥离,产生带正电的颗粒。