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    • 2. 发明授权
    • Hydrolysis-resistant polyamides
    • 耐水解聚酰胺
    • US08629220B2
    • 2014-01-14
    • US13351664
    • 2012-01-17
    • Manoranjan PrustyArno LangeClaus GabrielMatthias Scheibitz
    • Manoranjan PrustyArno LangeClaus GabrielMatthias Scheibitz
    • C08L77/00C08F210/10
    • C08L77/06C08L23/22
    • Thermoplastic molding compositions comprising A) from 10 to 99.9% by weight of a thermoplastic polyamide, B) from 0.1 to 20% by weight of a terpolymer obtainable via copolymerization of (B1) from 1 to 70% by weight of at least one electron-deficient olefin, (B2) from 0 to 85% by weight of at least one olefin which, at its olefinic double bond, bears only hydrogen atoms and/or carbon atoms without electron-withdrawing substituents, and (B3) from 1 to 99% by weight of at least one alkoxyvinylsilane, C) from 0 to 50% by weight of a fibrous or particulate filler or a mixture of these, D) from 0 to 50% by weight of other additives, where the total of the percentages by weight of components A) to D) is 100%.
    • 热塑性成型组合物,其包含A)10至99.9重量%的热塑性聚酰胺,B)0.1至20重量%的三元共聚物,其通过(B1)1至70重量%的至少一种电子 - (B2)0至85重量%的至少一种烯烃,其烯属双键仅具有不具有吸电子取代基的氢原子和/或碳原子,和(B3)1至99重量% 的至少一种烷氧基乙烯基硅烷,C)0至50重量%的纤维或颗粒填料或它们的混合物,D)0至50重量%的其它添加剂,其中总重量百分比 的组分A)至D)为100%。
    • 3. 发明授权
    • Magnetorheological formulation
    • 磁流变公式
    • US08486292B2
    • 2013-07-16
    • US12442463
    • 2007-09-18
    • Christoffer KieburgJürgen PfisterClaus GabrielGünter OetterMartin LaunRene Lochtman
    • Christoffer KieburgJürgen PfisterClaus GabrielGünter OetterMartin LaunRene Lochtman
    • H01F1/44
    • H01F1/447
    • Magnetorheological formulations, processes for preparing the same and uses therefor, the formulations comprising: (a) an ionic liquid comprising anions and cations, and (b) dispersed magnetizable particles having a mean diameter of 0.1 to 500 μm; wherein the ionic liquid comprises one or more salts selected from the group consisting of 1-butyl-3-methyl-imidazolium methylsulfate, 1-ethyl-3-methylimidazolium ethylsulfate, 1-ethyl-3-methyl-imidazolium thiocyanate, 1-butyl-3-methylimidazolium thiocyanate, 1-ethyl-3-methyl-imidazolium acetate, 1-butyl-3-methylimidazolium acetate, 1-ethyl-3-methylpyridinium ethylsulfate, 1-ethyl-3-methylimidazolium dicyanamide, 1-butyl-3-methylimidazolium tetrafluoroborate, 1-hexyl-3-methylimidazolium tetrafluoroborate, 1-methyl-3-octylimidazolium tetrafluoroborate, 1-methyl-3-octylimidazolium hexafluorophosphate, 1-ethyl-3-methylimidazolium hexafluorophosphate, 1-hexyl-3-methylimidazolium hexafluorophosphate, methyltrioctylammonium bis(trifluoromethylsulfonyl)imide, 1-ethyl-3-methylimidazolium 2-(2-methoxyethoxy)ethylsulfate and mixtures thereof.
    • 磁流变学配方,其制备方法及用途,所述制剂包含:(a)包含阴离子和阳离子的离子液体,和(b)平均直径为0.1至500μm的可分散的可分散颗粒; 其中所述离子液体包含一种或多种选自1-丁基-3-甲基 - 咪唑鎓甲基硫酸盐,1-乙基-3-甲基咪唑鎓乙基硫酸盐,1-乙基-3-甲基 - 咪唑鎓硫氰酸盐,1-丁基-3-甲基咪唑鎓硫氰酸盐, 3-甲基咪唑鎓硫氰酸酯,1-乙基-3-甲基 - 咪唑鎓乙酸酯,1-丁基-3-甲基咪唑鎓乙酸酯,1-乙基-3-甲基吡啶鎓乙基硫酸盐,1-乙基-3-甲基咪唑二氰胺,1-丁基-3-甲基咪唑鎓 四氟硼酸1-己基-3-甲基咪唑鎓,四氟硼酸1-甲基-3-辛基咪唑鎓,六氟磷酸1-甲基-3-辛基咪唑鎓,六氟磷酸1-乙基-3-甲基咪唑鎓,六氟磷酸1-己基-3-甲基咪唑鎓,二(甲基三辛基铵二 三氟甲基磺酰基)酰亚胺,1-乙基-3-甲基咪唑鎓2-(2-甲氧基乙氧基)乙基硫酸盐及其混合物。
    • 5. 发明申请
    • MAGNETORHEOLOGICAL FORMULATION
    • 磁流变配方
    • US20090289214A1
    • 2009-11-26
    • US12442463
    • 2007-09-18
    • Christoffer KieburgJürgen PfisterClaus GabrielGünter OetterMartin LaunRene Lochtman
    • Christoffer KieburgJürgen PfisterClaus GabrielGünter OetterMartin LaunRene Lochtman
    • C09K3/00
    • H01F1/447
    • Magnetorheological formulations, processes for preparing the same and uses therefor, the formulations comprising: (a) an ionic liquid comprising anions and cations, and (b) dispersed magnetizable particles having a mean diameter of 0.1 to 500 μm; wherein the ionic liquid comprises one or more salts selected from the group consisting of 1-butyl-3-methyl-imidazolium methylsulfate, 1-ethyl-3-methylimidazolium ethylsulfate, 1-ethyl-3-methyl-imidazolium thiocyanate, 1-butyl-3-methylimidazolium thiocyanate, 1-ethyl-3-methyl-imidazolium acetate, 1-butyl-3-methylimidazolium acetate, 1-ethyl-3-methylpyridinium ethylsulfate, 1-ethyl-3-methylimidazolium dicyanamide, 1-butyl-3-methylimidazolium tetrafluoroborate, 1-hexyl-3-methylimidazolium tetrafluoroborate, 1-methyl-3-octylimidazolium tetrafluoroborate, 1-methyl-3-octylimidazolium hexafluorophosphate, 1-ethyl-3-methylimidazolium hexafluorophosphate, 1-hexyl-3-methylimidazolium hexafluorophosphate, methyltrioctylammonium bis(trifluoromethylsulfonyl)imide, 1-ethyl-3-methylimidazolium 2-(2-methoxyethoxy)ethylsulfate and mixtures thereof.
    • 磁流变学配方,其制备方法及用途,所述制剂包含:(a)包含阴离子和阳离子的离子液体,和(b)平均直径为0.1至500μm的可分散的可分散颗粒; 其中所述离子液体包含一种或多种选自1-丁基-3-甲基 - 咪唑鎓甲基硫酸盐,1-乙基-3-甲基咪唑鎓乙基硫酸盐,1-乙基-3-甲基 - 咪唑鎓硫氰酸盐,1-丁基-3-甲基咪唑鎓硫氰酸盐, 3-甲基咪唑鎓硫氰酸酯,1-乙基-3-甲基 - 咪唑鎓乙酸酯,1-丁基-3-甲基咪唑鎓乙酸酯,1-乙基-3-甲基吡啶鎓乙基硫酸盐,1-乙基-3-甲基咪唑二氰胺,1-丁基-3-甲基咪唑鎓 四氟硼酸1-己基-3-甲基咪唑鎓,四氟硼酸1-甲基-3-辛基咪唑鎓,六氟磷酸1-甲基-3-辛基咪唑鎓,六氟磷酸1-乙基-3-甲基咪唑鎓,六氟磷酸1-己基-3-甲基咪唑鎓,二(甲基三辛基铵二 三氟甲基磺酰基)酰亚胺,1-乙基-3-甲基咪唑鎓2-(2-甲氧基乙氧基)乙基硫酸盐及其混合物。
    • 8. 发明授权
    • Rheometer
    • 流变仪
    • US08132445B2
    • 2012-03-13
    • US12438017
    • 2007-08-16
    • Martin LaunJürgen PfisterRene LochtmanGünter OetterClaus Gabriel
    • Martin LaunJürgen PfisterRene LochtmanGünter OetterClaus Gabriel
    • G01N11/14
    • G01N11/14G01N2011/0026
    • The invention relates to a rheometer having a rotatable shaft (1) on which a rotor plate (2) is fastened, and having a measuring instrument (10) for measuring torques exerted on the rotor plate (2) by a substance (6) to be studied during rotation of the shaft (1), a first measurement gap (5) for holding the substance (6) to be studied being formed between a first side (3) of the rotor plate (2) and a first shear face (4) and a second measurement gap (9) for holding the substance (6) to be studied being formed between a second side (7) of the rotor plate (2), opposite the first side, and a second shear face (8). The rheometer contains a magnet for generating a magnetic field in the first and second measurement gaps (5, 9).
    • 本发明涉及一种具有可旋转轴(1)的流变仪,其上固定有转子板(2),并具有测量仪器(10),用于测量通过物质(6)施加在转子板(2)上的转矩 在轴(1)的旋转期间进行研究,用于保持要研究的物质(6)的第一测量间隙(5)形成在转子板(2)的第一侧(3)和第一剪切面 4)和用于保持要研究的物质(6)形成在与第一侧相对的转子板(2)的第二侧(7)和第二剪切面(8)之间的第二测量间隙(9) 。 流变仪包含用于在第一和第二测量间隙(5,9)中产生磁场的磁体。
    • 9. 发明申请
    • NANOCOMPOSITE BLENDS WITH POLYESTERS
    • 与聚酯的纳米复合物混合
    • US20120046399A1
    • 2012-02-23
    • US13212566
    • 2011-08-18
    • Sachin JainClaus GabrielAlexander Traut
    • Sachin JainClaus GabrielAlexander Traut
    • C08K5/5445B82Y30/00
    • B82Y30/00C08K3/22C08K5/544C08K9/06C08L51/04C08L67/02
    • Thermoplastic molding compositions comprising A) from 10 to 98.95% by weight of at least one thermoplastic polyester, B) from 0.05 to 30% by weight of at least one nanoparticulate oxide and/or oxide hydrate of at least one metal or of at least one semimetal with a number-average primary particle diameter of from 0.5 to 50 nm and with a hydrophobic particle surface, C) from 1 to 60% by weight of at least one graft polymer, composed of c1) from 20 to 80% by weight of a graft base composed of an elastomeric polymer based on alkyl acrylates having from 1 to 8 carbon atoms in the alkyl moiety and/or dienes having a glass transition temperature below 10° C. c2) from 20 to 80% by weight of a graft composed of c21) from 60 to 95% by weight of styrene or of substituted styrenes of the general formula I  where R is an alkyl radical having from 1 to 8 carbon atoms or a hydrogen atom, and R1 is an alkyl radical having from 1 to 8 carbon atoms, and n is 1, 2, or 3, and c22) from 5 to 40% by weight of at least one unsaturated nitrile, D) from 0 to 60% by weight of further additives, where the total of the percentages by weight of components A) to D) is 100%.
    • 包含A)10至98.95重量%的至少一种热塑性聚酯,B)0.05至30重量%的至少一种至少一种金属或至少一种金属的纳米颗粒氧化物和/或氧化物水合物的热塑性模制组合物 数均一次粒径为0.5〜50nm,疏水性颗粒表面的半金属,C)1〜60重量%的至少一种接枝聚合物,由c1)20〜80重量% 由基于在烷基部分具有1至8个碳原子的丙烯酸烷基酯和/或具有玻璃化转变温度低于10℃的二烯的丙烯酸烷基酯的弹性聚合物构成的接枝基质。c2)20至80重量%的接枝组合物 的c21)60至95重量%的苯乙烯或通式I的取代苯乙烯,其中R是具有1至8个碳原子的烷基或氢原子,并且R 1是具有1至8个碳原子的烷基 碳原子,n为1,2或3,c22)为5〜40% 至少一种不饱和腈,D)0至60重量%的其它添加剂,其中组分A)至D)的重量百分比的总和为100%。
    • 10. 发明申请
    • Process for Producing Thermoformed Articles
    • 生产热成型制品的工艺
    • US20090012239A1
    • 2009-01-08
    • US11883715
    • 2006-01-30
    • Friederike MorhardGabriella SartoriAlexander FuchsClaus Gabriel
    • Friederike MorhardGabriella SartoriAlexander FuchsClaus Gabriel
    • C08L23/12
    • B29C51/002B29K2023/12C08L23/10C08L23/12C08L23/14C08L23/142C08L2205/02C08L2666/06
    • A process for obtaining thermoformed articles, comprising the following steps: a) forming a sheet comprising a propylene resin; b) thermoforming the sheet obtained in step a); wherein said propylene resin has the following characteristics: a) distribution of molecular weight Mw/Mn lower than 4; preferably lower than 3; b) 2.1 insertions measured with by 13C-NMR lower than 0.50%; preferably lower than 0.40%; c) eta* and the frequency ω meet the following relation for ω comprised between 0.1 and 1: eta*>3700ω(−0 13) d) melt flow rate (MFR) (ISO 1133) lower than 5; preferably lower than 4; more preferably lower than 3; wherein the polypropylene resin comprises: (i) from 10 to 100% by weight of a propylene homopolymer or a propylene copolymer containing from 0.1% to 10% by mol of derived units of ethylene or an alpha-olefin of formula CH2═CHZ wherein Z is a linear or branched C2-C20 radical; and (ii) from 0 to 90% by weight of a propylene copolymer containing from 0.1% to 10% by mol of derived units of ethylene or an alpha-olefin of formula CH2═CHZ wherein Z is a linear or branched C2-C20 radical, said propylene copolymer having a content of ethylene or an alpha-olefin of formula CH2═CHZ different from the propylene copolymer (i).
    • 一种获得热成型制品的方法,包括以下步骤:a)形成包含丙烯树脂的片材; b)对在步骤a)中获得的片材进行热成型; 其中所述丙烯树脂具有以下特性:a)分子量Mw / Mn低于4的分布; 优选低于3; b)2.1用13 C-NMR测量的低于0.50%的插入; 优选低于0.40%; c)eta *,频率ωm满足以下关系:ω= 0.1和1:ηa> 3700m(-0.13)d)熔体流动速率(MFR)(ISO 1133)低于5; 优选低于4; 更优选低于3; 其中所述聚丙烯树脂包含:(i)10至100重量%的丙烯均聚物或含有0.1至10摩尔%的衍生单元的乙烯或式CH 2 -CHZ的α-烯烃的丙烯共聚物,其中Z 是直链或支链C2-C20基; 和(ii)0至90重量%的含有0.1至10摩尔%的乙烯或式CH2-CHZ的α-烯烃的衍生单元的丙烯共聚物,其中Z为直链或支链C 2 -C 20基团 所述丙烯共聚物具有不同于丙烯共聚物(i)的乙烯或式CH 2 -CHZ的α-烯烃的含量。