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1. 发明授权

US07244034B1 Low CTE metal-ceramic composite articles, and methods for making same 失效
标题翻译：低CTE金属陶瓷复合制品及其制造方法
公开(公告)号：US07244034B1
公开(公告)日：2007-07-17
申请号：US10663359
申请日：2003-09-16
申请人： Prashant G. Karandikar , Jai R. Singh , Clarence A. Andersson
发明人： Prashant G. Karandikar , Jai R. Singh , Clarence A. Andersson
IPC分类号： G02B5/08 , D02G3/00
CPC分类号： C22C47/025 , B22F3/1103 , B22F2003/1106 , B22F2998/00 , B22F2999/00 , B82Y10/00 , B82Y30/00 , C22C47/08 , C22C49/14 , C22C2204/00 , H01L23/142 , H01L2924/0002 , H01L2924/09701 , Y10T428/249953 , Y10T428/249964 , Y10T428/249967 , Y10T428/24997 , B22F3/1112 , C22C47/04 , C22C47/06 , B22F3/11 , B22F2201/013 , B22F2201/02 , H01L2924/00
摘要： A mirror having low density, low CTE, high thermal conductivity, high elastic modulus, and a reflective, polishable surface. The instant mirror features a silicon-based metal coating as the reflective surface, and a composite body as a support or substrate for the reflecting surface. The composite body features carbon fibers reinforcing a matrix containing silicon metal and optionally some silicon carbide. The metal coating can be elemental silicon metal, possibly in amorphous form, and can be applied by a vapor deposition process such as chemical vapor deposition (e.g., plasma enhanced CVD) or physical vapor deposition such as evaporation or electron beam PVD.
摘要翻译：具有低密度，低CTE，高导热性，高弹性模量和反射性可抛光表面的镜子。该立体镜具有硅基金属涂层作为反射表面，以及复合体作为用于反射表面的支撑体或基底。该复合体具有加强含有硅金属和任选的一些碳化硅的基体的碳纤维。金属涂层可以是元素硅金属，可能是非晶态的，并且可以通过诸如化学气相沉积（例如等离子体增强CVD）或诸如蒸发或电子束PVD的物理气相沉积的气相沉积工艺来施加。

2. 发明授权

US4828774A Porous ceramic bodies 失效
标题翻译：多孔陶瓷体
公开(公告)号：US4828774A
公开(公告)日：1989-05-09
申请号：US011085
申请日：1987-02-05
申请人： Clarence A. Andersson , Deborah P. Partlow , Bulent E. Yoldas
发明人： Clarence A. Andersson , Deborah P. Partlow , Bulent E. Yoldas
IPC分类号： C04B14/46 , C04B30/02 , C04B35/14 , C04B35/80
CPC分类号： C04B35/80 , C04B14/46 , C04B30/02 , C04B35/14 , Y10T428/249956 , Y10T428/249957 , Y10T428/249964 , Y10T428/24997 , Y10T428/30
摘要： A porous body consisting of a felted fibrous skeleton covered with and bonded together by a ceramic material is provided. Also provided are methods for making such a porous body which comprise the use of ceramic polymer solutions.
摘要翻译：提供了由陶瓷材料覆盖并由陶瓷材料粘合在一起的被毡纤维骨架组成的多孔体。还提供了制造这种多孔体的方法，其包括使用陶瓷聚合物溶液。

3. 发明授权

US4376004A Method of manufacturing a transpiration cooled ceramic blade for a gas turbine 失效
标题翻译：制造用于燃气轮机的蒸腾冷却陶瓷刀片的方法
公开(公告)号：US4376004A
公开(公告)日：1983-03-08
申请号：US197318
申请日：1980-10-15
申请人： Raymond J. Bratton , Clarence A. Andersson
发明人： Raymond J. Bratton , Clarence A. Andersson
IPC分类号： F01D5/18 , F01D5/28 , C04B39/00 , F01D5/08
CPC分类号： F01D5/184 , F01D5/284 , Y10T29/49341
摘要： A transpiration cooled ceramic blade for a gas turbine is shown wherein a spar or strut member defining a root portion and an airfoil portion provides the main structural component of the blade. The air foil portion contains longitudinal grooves in the surface in flow communication with an air flow passage in the root portion and a flexible perforated ceramic tape is wrapped around the air foil portion with the perforations therein in registry with the grooves in the core. The flexible ceramic tape and the strut assembly are heated initially to a low temperature to drive off the binder forming the tape and then heated to a relatively high temperature to fuse the ceramic component of the tape together and to the strut to form a unitary blade structure with internal air flow paths and transpiration cooling orifices through the skin.
摘要翻译：示出了用于燃气轮机的蒸发冷却陶瓷刀片，其中限定根部部分和翼型部分的翼梁或支柱构件提供了叶片的主要结构部件。空气箔部分包含在表面中与根部中的空气流动通道流动连通的纵向凹槽，并且柔性穿孔陶瓷带缠绕在其上的穿孔中的空气箔部分与核心中的凹槽对齐。柔性陶瓷带和支柱组件首先被加热到低温以驱除形成带的粘合剂，然后加热到相对较高的温度以将带的陶瓷部件熔合在一起并与支柱熔合以形成整体的叶片结构具有内部空气流动路径和通过皮肤的蒸腾冷却孔。

4. 发明授权

US06841615B2 Composite Adhesive 失效
标题翻译：复合胶粘剂
公开(公告)号：US06841615B2
公开(公告)日：2005-01-11
申请号：US09978827
申请日：2001-10-17
申请人： Clarence A. Andersson , Philip J. Roach
发明人： Clarence A. Andersson , Philip J. Roach
IPC分类号： C08K3/00 , C08K3/14 , C08K3/20 , C08K3/28 , C08K3/38 , C08L79/00 , C09J7/00 , C09J11/04 , C09J179/04 , C08J3/00 , C08G63/44
CPC分类号： C09J11/04 , C08K3/013 , C08K3/14 , C08K3/20 , C08K3/28 , C08K3/38 , C08L79/00 , C09J7/10 , C09J179/04 , C09J2205/102 , C09J2479/08
摘要： A composite adhesive featuring a matrix phase that includes a cyanate ester and a filler or reinforcement phase that includes a plurality of bodies of at least one material comprising a high shear strength and/or high modulus material. Preferably, the filler also possesses at least one of high thermal conductivity and low coefficient of thermal expansion. Unlike certain commercially available cyanate esters, those of the instant invention substantially maintain or even increase in strength upon addition of the filler to the system. The instant composite adhesives may also display reduced coefficients of moisture expansion relative to the unfilled or “neat” resin. Such a composite adhesive is extremely useful for joining articles where high strength and minimal swelling in moist environments are required, such as in the precision equipment industry. In particular, the instant adhesives find great utility in joining components for semiconductor fabrication equipment, such as those that support the optics in a lithography machine.
摘要翻译：一种复合粘合剂，其特征在于基质相包括氰酸酯和填料或增强相，其包括多个至少一种包含高剪切强度和/或高模量材料的材料的主体。优选地，填料还具有高导热性和低热膨胀系数中的至少一种。与某些商业上可获得的氰酸酯不同，当将本发明的氰化物添加到体系中时，本发明的氰酸酯基本上维持甚至增加强度。本发明的复合粘合剂还可以相对于未填充或“纯”树脂显示减少的湿气膨胀系数。这种复合粘合剂对于连接在需要潮湿环境中的高强度和最小溶胀的制品（例如在精密设备工业中）是非常有用的。特别地，瞬时粘合剂在连接用于半导体制造设备的部件（例如那些支持光刻机中的光学器件）中发现了很大的用途。

5. 发明授权

US5290737A Fiber-reinforced metal or ceramic matrices 失效
标题翻译：纤维增强金属或陶瓷基体
公开(公告)号：US5290737A
公开(公告)日：1994-03-01
申请号：US757718
申请日：1985-07-22
申请人： Clarence A. Andersson , Deborah P. Partlow , Bulent E. Yoldas , Raymond J. Bratton
发明人： Clarence A. Andersson , Deborah P. Partlow , Bulent E. Yoldas , Raymond J. Bratton
IPC分类号： C03C14/00 , C04B35/628 , C04B35/80 , C22C47/04 , B22F9/16 , C03C13/00
CPC分类号： C04B35/803 , C03C14/002 , C04B35/62847 , C22C47/04 , C03C2214/02 , C03C2214/03 , C04B2235/441 , C04B2235/524 , Y10T428/12014 , Y10T428/12035
摘要： A composite material having a fiber system embedded in a host matrix material. The fiber system has a protective reaction barrier around the embedded fibers to prevent deleterious chemical or mechanical reaction between the fiber and matrix. The fiber coating is applied by immersion of the fiber system into an alkoxide solution of the desired oxide precursor with controlled immersion and withdrawal rates with subsequent drying, heating to convert to a pure oxide state, and where required, post processing, to convert the oxide coating to a carbide or nitride, for example.
摘要翻译：具有嵌入主体基质材料中的纤维体系的复合材料。纤维系统在嵌入的纤维周围具有保护性反应屏障，以防止纤维和基质之间的有害的化学或机械反应。通过将纤维体系浸渍到所需氧化物前体的醇盐溶液中，以受控的浸渍和萃取速率浸渍，随后干燥，加热转化成纯氧化物状态，并且在需要时进行后处理以转化氧化物涂覆到例如碳化物或氮化物。

6. 发明授权

US4311433A Transpiration cooled ceramic blade for a gas turbine 失效
标题翻译：用于燃气轮机的蒸腾冷却陶瓷刀片
公开(公告)号：US4311433A
公开(公告)日：1982-01-19
申请号：US3849
申请日：1979-01-16
申请人： Raymond J. Bratton , Clarence A. Andersson
发明人： Raymond J. Bratton , Clarence A. Andersson
IPC分类号： F01D5/18 , F01D5/28
CPC分类号： F01D5/184 , F01D5/284 , Y10T29/49341
摘要： A transpiration cooled ceramic blade for a gas turbine is shown wherein a spar or strut member defining a root portion and an airfoil portion provides the main structural component of the blade. The air foil portion contains longitudinal grooves in the surface in flow communication with an air flow passage in the root portion and a flexible perforated ceramic tape is wrapped around the air foil portion with the perforations therein in registry with the grooves in the core. The flexible ceramic tape and the strut assembly are heated initially to a low temperature to drive off the binder forming the tape and then heated to a relatively high temperature to fuse the ceramic component of the tape together and to the strut to form a unitary blade structure with internal air flow paths and transpiratin cooling orifices through the skin.
摘要翻译：示出了用于燃气轮机的蒸发冷却陶瓷刀片，其中限定根部部分和翼型部分的翼梁或支柱构件提供了叶片的主要结构部件。空气箔部分包含在表面中与根部中的空气流动通道流动连通的纵向凹槽，并且柔性穿孔陶瓷带缠绕在其上的穿孔中的空气箔部分与核心中的凹槽对齐。柔性陶瓷带和支柱组件首先被加热到低温以驱除形成带的粘合剂，然后加热到相对较高的温度以将带的陶瓷部件熔合在一起并与支柱熔合以形成整体的叶片结构具有内部空气流动路径和透明质酸冷却孔通过皮肤。

7. 发明授权

US07169465B1 Low expansion metal-ceramic composite bodies, and methods for making same 有权
标题翻译：低膨胀金属 - 陶瓷复合体及其制造方法
公开(公告)号：US07169465B1
公开(公告)日：2007-01-30
申请号：US10073818
申请日：2002-02-11
申请人： Prashant G. Karandikar , Jai R. Singh , Clarence A. Andersson
发明人： Prashant G. Karandikar , Jai R. Singh , Clarence A. Andersson
IPC分类号： B32B9/00
CPC分类号： C22C47/025 , B22F3/1103 , B22F2003/1106 , B22F2998/00 , B22F2999/00 , B82Y10/00 , B82Y30/00 , C22C47/08 , C22C49/14 , C22C2204/00 , H01L23/142 , H01L2924/0002 , H01L2924/09701 , Y10T428/249953 , Y10T428/249964 , Y10T428/249967 , Y10T428/24997 , B22F3/1112 , C22C47/04 , C22C47/06 , B22F3/11 , B22F2201/013 , B22F2201/02 , H01L2924/00
摘要： A low CTE metal-ceramic composite material featuring carbon fibers reinforcing a matrix featuring silicon metal or silicon alloy. The fibers have a low coefficient of thermal expansion (CTE) in the axial direction, and preferably negative. The principles of making Si/SiC composites can be adapted to produce the instant Si matrix composites. The CTE of the composite body depends not only upon the relative CTE's of the fibers and matrix, and their relative amounts (e.g., loadings), but also upon the relative elastic moduli of the fibers and matrix. Thus, Si/SiC matrices produced by a reaction-bonding process inherently possess low CTE, but the instant inventors prefer to make such composites having relatively large fractions of unreacted silicon, thereby driving composite CTE lower still. Here, the carbon fibers are protected from reaction with the silicon infiltrant with one or more materials disposed between the fibers and the infiltrant. Providing at least a degree of toughness or impact resistance can also be realized in these composites. Laminates produce Isotropic or quasi-isotropic properties in the composite body can be realized by, for example, providing the fibers in the form of cross-plied laminates featuring the fibers in parallel or woven arrays.
摘要翻译：低CTE金属陶瓷复合材料，其特征在于碳纤维增强了具有硅金属或硅合金的基体。纤维在轴向上的热膨胀系数（CTE）优选为负。制备Si / SiC复合材料的原理可以适用于生产即时Si基复合材料。复合体的CTE不仅取决于纤维和基体的相对CTE以及它们的相对量（例如载荷），而且取决于纤维和基体的相对弹性模量。因此，通过反应连接工艺产生的Si / SiC基体固有地具有低CTE，但是本发明人优选制备具有相对大的未反应硅的分数的复合材料，从而驱动复合CTE较低。这里，保护碳纤维免受与硅浸润剂的反应，其中一种或多种材料设置在纤维和浸润剂之间。提供至少一定程度的韧性或抗冲击性也可以在这些复合材料中实现。通过例如提供以平行或编织阵列的纤维为特征的交叉层叠体的形式的纤维，可以实现层合体在复合体中产生各向同性或准各向同性的特性。

8. 发明授权

US4482913A Semiconductor device soldered to a graphite substrate 失效
标题翻译：半导体器件焊接到石墨基板
公开(公告)号：US4482913A
公开(公告)日：1984-11-13
申请号：US351809
申请日：1982-02-24
申请人： Michael A. Burke , Clarence A. Andersson
发明人： Michael A. Burke , Clarence A. Andersson
IPC分类号： H01L23/14 , H01L21/52 , H01L23/15 , H01L23/488 , H01L21/58 , H01L23/32
CPC分类号： H01L23/15 , H01L23/488 , H01L24/32 , H01L2924/01029
摘要： The present invention is directed to a semiconductor device in which a wafer of semiconductor material is soldered to a graphite substrate.
摘要翻译：本发明涉及将半导体材料的晶片焊接到石墨基板上的半导体器件。

9. 发明授权

US06355340B1 Low expansion metal matrix composites 失效
标题翻译：低膨胀金属基复合材料
公开(公告)号：US06355340B1
公开(公告)日：2002-03-12
申请号：US09378367
申请日：1999-08-20
申请人： Jai R. Singh , Clarence A. Andersson
发明人： Jai R. Singh , Clarence A. Andersson
IPC分类号： B32B900
CPC分类号： C22C47/025 , B22F3/1103 , B22F2003/1106 , B22F2998/00 , B22F2999/00 , C22C47/08 , C22C49/14 , C22C2204/00 , H01L23/142 , H01L2924/0002 , H01L2924/09701 , Y10T428/249953 , Y10T428/249964 , Y10T428/249967 , Y10T428/24997 , B22F3/1112 , C22C47/04 , C22C47/06 , B22F2201/02 , B22F3/11 , B22F2201/013 , H01L2924/00
摘要： A low to near-zero metal matrix composite material featuring high modulus carbon fibers reinforcing a lightweight metal or semimetal. The fibers have a negative coefficient of thermal expansion in the axial direction. Laminates featuring parallel arrays of fibers may be cross-plied to produce quasi-isotropic properties in the composite body. The CTE of the composite body depends not only upon the relative CTE's of the fibers and matrix, and their relative amounts (e.g., loadings), but also upon the relative elastic moduli of the fibers and matrix. By intentionally introducing porosity into the matrix, the elastic modulus of the matrix is reduced, and thus the CTE of the composite body is influenced more by the CTE contribution of the fibers. In effect, the composite CTE is shifted toward that of the fibers, which shifting represents a reduction in composite CTE. Hydrogen outgassing upon solidification of the metallic matrix is one technique for producing such porosity.
摘要翻译：一种低至接近零的金属基复合材料，具有高模量碳纤维，增强了轻质金属或半金属。纤维在轴向上具有负的热膨胀系数。具有平行的纤维阵列的层压板可以交叉层叠以在复合体中产生准各向同性的性质。复合体的CTE不仅取决于纤维和基体的相对CTE以及它们的相对量（例如载荷），而且取决于纤维和基体的相对弹性模量。通过有意地将孔隙率引入基体，基体的弹性模量降低，因此复合体的CTE受到纤维的CTE贡献的影响更大。实际上，复合CTE向纤维的转移，这种转移代表了复合CTE的降低。金属基体凝固时的氢气除气是产生这种孔隙率的一种技术。

10. 发明授权

US4234343A Structural silicon nitride materials containing rare earth oxides 失效
标题翻译：含有稀土氧化物的结构氮化硅材料
公开(公告)号：US4234343A
公开(公告)日：1980-11-18
申请号：US1033
申请日：1979-01-04
申请人： Clarence A. Andersson
发明人： Clarence A. Andersson
IPC分类号： C04B35/593 , C04B35/597 , C04B35/50 , C04B35/58
CPC分类号： C04B35/593 , C04B35/597
摘要： A ceramic composition suitable for use as a high-temperature structural material, particularly for use in apparatus exposed to oxidizing atmospheres at temperatures of 400 to 1600.degree. C., is found within the triangular area ABCA of the Si.sub.3 N.sub.4 --SiO.sub.2 --M.sub.2 O.sub.3 ternary diagram depicted in FIG. 1. M is selected from the group of Yb, Dy, Er, Sc, and alloys having Yb, Y, Er, or Dy as one component and Sc, Al, Cr, Ti, (Mg +Zr) or (Ni+Zr) as a second component, said alloy having an effective ionic radius less than 0.89 A.
摘要翻译：适用于高温结构材料的陶瓷组合物，特别用于暴露于氧化性气氛的设备中，在400至1600℃温度下的陶瓷组合物可见于所示的Si3N4-SiO2-M2O3三元图的三角形区域ABCA内在图中。 M选自Yb，Dy，Er，Sc和Yb，Y，Er或Dy作为一种组分的合金，Sc，Al，Cr，Ti，（Mg + Zr）或（Ni + Zr ）作为第二组分，所述合金的有效离子半径小于0.89A。

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