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    • 1. 发明授权
    • Refrigerant compositions including 1,1,2-trifluoroethane and
hexafluoropropane
    • 包括1,1,2-三氟乙烷和六氟丙烷的制冷剂组合物
    • US5626790A
    • 1997-05-06
    • US213339
    • 1994-03-14
    • Barbara H. Minor
    • Barbara H. Minor
    • C11D7/50C07C9/08C07C9/10C07C19/08C07C211/15C07C381/00C08J9/14C09K3/00C09K3/30C09K5/04
    • C08J9/149C09K5/045C09K2205/12C09K2205/132C09K2205/134C09K2205/22C09K2205/32
    • Refrigerant compositions include mixtures of 1,1,2-trifluoroethane and a second component wherein the second component is (CF.sub.3).sub.2 NF, (CF.sub.3).sub.3 N, N(CHF.sub.2).sub.2 (CF.sub.3), N(CH.sub.2 F)(CF.sub.3).sub.2, SF.sub.5 CF.sub.2 H.sub.5, SF.sub.5 C.sub.2 F.sub.5, HFC-236ca, HFC-236cb, HFC-236ea, HFC-254cb, HFC-254eb, HFC-263fb, HFC-272ca, HFC-281ea, HFC-281fa, HFC-338mf, HFC-4310mee, butane, cyclopropane, isobutane or propane.Except for FIG. 7, the invention also relates to azeotropic or azeotrope-like compositions which comprise admixtures of effective amounts of 1,1,2-trifluoroethane and (CF.sub.3).sub.2 NF, (CF.sub.3).sub.3 N, N(CHF.sub.2).sub.2 (CF.sub.3), N(CH.sub.2 F)(CF.sub.3).sub.2, SF.sub.5 CF.sub.2 H, SF.sub.5 C.sub.2 F.sub.5, HFC-236ca, HFC-236cb, HFC-236ea, HFC-254cb, HFC-254eb, HFC-263fb, HFC-272ca, HFC-281ea, HFC-281fa, HFC-338mf, HFC-4310mee, butane, cyclopropane, isobutane or propane to form an azeotropic or azeotrope-like composition.
    • 制冷剂组合物包括1,1,2-三氟乙烷和第二组分的混合物,其中第二组分是(CF 3)2 NHF,(CF 3)3 N,N(CHF 2)2(CF 3),N(CH 2 F)(CF 3)2,SF 5 CF 2 H 5 ,SF5C2F5,HFC-236ca,HFC-236cb,HFC-236ea,HFC-254cb,HFC-254eb,HFC-263fb,HFC-272ca,HFC-281ea,HFC-281fa,HFC-338mf,HFC-4310mee,丁烷,环丙烷 ,异丁烷或丙烷。 除了图 如图7所示,本发明还涉及共沸或类共沸组合物,其包含有效量的1,1,2-三氟乙烷和(CF 3)2 NHF,(CF 3)3 N,N(CHF 2)2(CF 3),N(CH 2 F )CF3)2,SF5CF2H,SF5C2F5,HFC-236ca,HFC-236cb,HFC-236ea,HFC-254cb,HFC-254eb,HFC-263fb,HFC-272ca,HFC-281ea,HFC-281fa,HFC-338mf, HFC-4310mee,丁烷,环丙烷,异丁烷或丙烷,以形成共沸或类共沸组合物。
    • 3. 发明授权
    • Octafluorobutane compositions
    • 八氟丁烷组合物
    • US5562854A
    • 1996-10-08
    • US315020
    • 1994-09-29
    • Barbara H. Minor
    • Barbara H. Minor
    • A62D1/02A62D1/00A62D3/00C07C19/08C07C43/04C07C43/12C07D305/06C07D307/18C08J9/14C09K3/30C09K5/04C10M105/50C10N40/08C11D7/26C11D7/28C11D7/30C11D7/50C23G5/028C23G5/032
    • C11D7/5018A62D1/0057C08J9/149C09K3/30C09K5/045C11D7/5063C11D7/5086C23G5/02803C23G5/032C08J2203/142C08J2203/146C08J2207/04C09K2205/11C09K2205/112C09K2205/116C09K2205/22C09K2205/32C11D7/263C11D7/28
    • The invention includes compositions of 1,2,2,3,3,4,4,4-octafluorobutane and bis(fluoromethyl) ether, 2,2,4,4-tetrafluorooxetane, 2,2,3,3-tetrafluorooxetane, 1-difluoromethoxy-1,1,2,2-tetrafluoroethane, 1-difluoromethoxy-1,2,2,2-tetrafluoroethane, 2,2,3,3,4,5,5-heptafluorotetrahydrofuran or 2,2,3,3,4,4,5-heptafluorotetrahydrofuran; 1,1,1,2,3,4,4,4-octafluorobutane and bis(fluoromethyl) ether, 2,2,4,4-tetrafluorooxetane, 2,2,3,3-tetrafluorooxetane, 1-difluoromethoxy-1,1,2,2-tetrafluoroethane, 1-difluoromethoxy- 1,2,2,2-tetrafluoroethane, 2,2,3,3,4,5,5-heptafluorotetrahydrofuran, or 2,2,3,3,4,4,5-heptafluorotetrahydrofuran; 1,1,1,2,2,4,4,4-octafluorobutane and bis(fluoromethyl) ether, 2,2,4,4-tetrafluorooxetane or 2,2,3,3-tetrafluorooxetane; or 1,1,2,2,3,3,4,4-octafluorobutane and methyl tert-butyl ether, bis(fluoromethyl) ether or 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2,2-tetrafluoroethoxy)propane. These compositions, which may be azeotropic or azeotrope-like, may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.
    • 本发明包括1,2,2,3,3,4,4,4-八氟丁烷和双(氟甲基)醚,2,2,4,4-四氟氧杂环丁烷,2,2,3,3-四氟氧杂环丁烷,1 二氟甲氧基-1,1,2,2-四氟乙烷,1-二氟甲氧基-1,2,2,2-四氟乙烷,2,2,3,3,4,5,5-七氟四氢呋喃或2,2,3,3 ,4,4,5-七氟四氢呋喃; 1,1,1,2,3,4,4,4-八氟丁烷和双(氟甲基)醚,2,2,4,4-四氟氧杂环丁烷,2,2,3,3-四氟氧杂环丁烷,1-二氟甲氧基-1, 1,2,2-四氟乙烷,1-二氟甲氧基-1,2,2,2-四氟乙烷,2,2,3,3,4,5,5-七氟四氢呋喃或2,2,3,3,4,4 ,5-七氟四氢呋喃; 1,1,1,2,2,4,4,4-八氟丁烷和双(氟甲基)醚,2,2,4,4-四氟氧杂环丁烷或2,2,3,3-四氟氧杂环丁烷; 或1,1,2,2,3,3,4,4-八氟丁烷和甲基叔丁基醚,双(氟甲基)醚或1,1,1,2,2,3,3-七氟-3-( 1,2,2,2-四氟乙氧基)丙烷。 这些可以共沸或类共沸的组合物可用作制冷剂,清洁剂,聚烯烃和聚氨酯的膨胀剂,气溶胶推进剂,制冷剂,传热介质,气体电介质,灭火剂,动力循环工作流体,聚合 介质,微粒去除液,载液,抛光磨料或置换干燥剂。
    • 6. 发明授权
    • Refrigerant compositions including an acylic fluoroether
    • 包含酰基氟醚的制冷剂组合物
    • US5484546A
    • 1996-01-16
    • US242511
    • 1994-05-13
    • Barbara H. MinorTuneen E. C. ChisolmGlenn S. Shealy
    • Barbara H. MinorTuneen E. C. ChisolmGlenn S. Shealy
    • A62D1/00C07C9/12C07C11/06C07C13/04C07C19/08C07C43/04C07C43/12C07C211/15C08J9/14C08L23/02C08L75/04C09K3/30C09K5/04C11D7/50
    • C09K3/30C08J9/149C09K5/045C08J2203/12C08J2203/14C08J2203/146C09K2205/11C09K2205/112C09K2205/116C09K2205/12C09K2205/132C09K2205/22Y10S264/05
    • Refrigerant compositions include mixtures of hexafluorodimethyl ether and cyclopropane, dimethylether or propylene; bis(difluoromethyl) ether and 2,2,3,4,4-pentafluorooxetane; fluoromethyl trifluoromethyl ether and 2,2,4,4,5,5-hexafluoro-1,3-dioxolane, 1-trifluoromethoxy-1,2,2,2-tetrafluoroethane, dimethylether or tris(trifluoromethyl)amine; trifluoromethyl methyl ether and perfluorooxetane, 2,2,4,4,5,5-hexafluoro-1,3-dioxolane, perfluoromethyl ethyl ether, perfluorodinethoxymethane, 1-trifluoromethoxy-1,2,2,2-tetrafluoroethane, dimethylether or tris(trifluoromethyl)amine; perfluoromethyl ethyl ether and dimethylether, propylene or 1-trifluoromethoxy-1,2,2,2-tetrafluoroethane; perfluorodirnethoxymethane and dimethylether or isobutane; 1-trifluoromethoxy-1,1,2,2-tetrafluoroethane and tris(trifluoromethyl)amine or dimethylether; difluoromethoxy pentafluoroethane and dimethylether, isobutane or tris(trifluoromethyl)amine; 1-trifluoromethoxy-1,2,2,2-tetrafluoroethane and dimethylether or isobutane; 1-difluoromethoxy-1,1,2,2-tetrafluoroethane and N(CHF.sub.2).sub.2 (CF.sub.3); or 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2,2-tetrafluoroethoxy)propane and 1,1,2,2,3-pentafluoropropane or 1,1,1,2,3-pentafluoropropane.
    • 制冷剂组合物包括六氟二甲醚和环丙烷的混合物,二甲醚或丙烯; 双(二氟甲基)醚和2,2,3,4,4-五氟氧杂环丁烷; 氟代甲基三氟甲基醚和2,2,4,4,5,5-六氟-1,3-二氧戊环,1-三氟甲氧基-1,2,2,2-四氟乙烷,二甲醚或三(三氟甲基)胺; 三氟甲基甲基醚和全氟氧杂环丁烷,2,2,4,4,5,5-六氟-1,3-二氧戊环,全氟甲基乙基醚,全氟二乙氧基甲烷,1-三氟甲氧基-1,2,2,2-四氟乙烷,二甲醚或三 三氟甲基)胺; 全氟甲基乙基醚和二甲醚,丙烯或1-三氟甲氧基-1,2,2,2-四氟乙烷; 全氟二乙氧基甲烷和二甲醚或异丁烷; 1-三氟甲氧基-1,1,2,2-四氟乙烷和三(三氟甲基)胺或二甲醚; 二氟甲氧基五氟乙烷和二甲醚,异丁烷或三(三氟甲基)胺; 1-三氟甲氧基-1,2,2,2-四氟乙烷和二甲醚或异丁烷; 1,1-二氟甲氧基-1,1,2,2-四氟乙烷和N(CHF 2)2(CF 3); 或1,1,1,2,2,3,3-七氟-3-(1,2,2,2-四氟乙氧基)丙烷和1,1,2,2,3-五氟丙烷或1,1,1, 2,3-五氟丙烷。