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1. 发明申请

WO2006003094A2 MEROCYANINE DERIVATIVES 审中-公开
公开(公告)号：WO2006003094A2
公开(公告)日：2006-01-12
申请号：PCT/EP2005/052850
申请日：2005-06-20
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , WAGNER, Barbara , BIENEWALD, Frank , WOLLEB, Heinz , WALLQUIST, Olof , HERZOG, Bernd , EHLIS, Thomas , HAASE, Jürg
发明人： WAGNER, Barbara , BIENEWALD, Frank , WOLLEB, Heinz , WALLQUIST, Olof , HERZOG, Bernd , EHLIS, Thomas , HAASE, Jürg
IPC分类号： A61K7/42
CPC分类号： A61K8/498 , A61K8/4913 , A61K8/494 , A61Q17/04
摘要： Disclosed is the use of merocyanine derivatives of formula (I), wherein Q is hydrogen; C 1 -C 22 alkyl; -OH; -OR 7 ; -NR 7 R 8 ; or -N=R 9 ; R 1 is hydrogen; C 1 -C 22 alkyl; -OR 7 , -SR 7 ; -NR 7 R 8 ; C 1 -C 22 alkyl; C 2 -C 12 alkenyl; C 2 -C 12 alkinyl; C 3 -C 12 cycloalkyl; C 3 -C 12 cycloalkenyl; C 7 -C 12 aralkyl; C 1 -C 12 heteroalkyl, C 2 -C 11 heteroaralkyl; C 6 -C 10 aryl; or C 1 -C 9 heteroaryl; R 4 is cyano; COR 7 , COOR 7 ; CONR 7 R 8 ; SO 2 (C 6 -C 12 )aryl; C 2 -C 12 alk-1-enyl; C 3 -C 12 cycloalk-1-enyl; C 2 -C 12 alk-1-inyl; C 2 -C 12 heteroalkyl; C 3 -C 5 heterocycloalkyl; C 6 -C 10 aryl; or C 1 -C 9 heteroaryl; R 5 is -COR 7 ; -COOR 7 ; -OR 7 ; -SR 7 , -NHR 7 , -NR 7 R 8 ; C 1 -C 22 alkyl; C 2 -C 12 alkenyl; C 2 -C 12 alkinyl; C 3 -C 12 cycloalkyl; C 3 -C 12 cycloalkenyl; C 7 -C 12 aralkyl; C 1 -C 12 alkylphenyl; C 1 -C 12 alkoxy-C 6 -C 10 aryl; C 1 -C 12 heteroalkyl; C 2 -C 11 heteroaralkyl; C 3 -C 12 cycloheteroalkyl; C 6 -C 10 aryl; C 1 - C 12 alkoxy-C 6 -C 10 aryl; or C 1 -C 9 heteroaryl; R 6 is hydrogen; C 1 -C 22 alkyl; C 1 -C 22 alkoxy; or COR 7 ; R 7 and R 8 independently from each other are hydrogen; C 1 -C 22 alkyl; C 2 -C 12 alkenyl; C 2 -C 12 alkinyl; C 3 -C 12 cycloalkyl; C 3 -C 12 cycloalkenyl; -(CH 2 ) t COOH; C 7 -C 12 aralkyl; C 1 -C 12 heteroalkyl; C 2 -C 11 heteroaralkyl; C 6 -C 10 aryl; C 1 -C 9 heteroaryl; Si-R 10 R 11 R 12 ; Si(OR 10 )(OR 11 )(OR 12 ); SiR 10 (OR 11 )(OR 12 ); SiR 10 R 11 (OR 12 ); -(CH 2 ) u -O-(CH 2 ) v -SiR 10 R 11 R 12 ; or a radical X-Sil; t, u and v, independently from each other are a number from 1 to 5; R 9 is a (C 1 -C 6 )alkylidene radical; R 10 , R 11 , R 12 independently form each other are C 1 -C 22 alkyl; X is a linker; Sil is a silane-, oligosiloxane- or polysiloxane radical; R 1 and R 2 , R 1 and Q, R 1 and R 6 , R 1 and T, R 2 and R 3 , R 2 and R 4 , R 2 and R 6 , R 2 and Q, R 4 and R 6 , R 4 and T, R 6 and Q, T and Q, each independently, are linked together, so that 1, 2, 3 or 4 carbocyclic or N, O and/or S-heterocyclic rings are formed, wherein each of them, independently from each other, may be condensed with an aromatic or heteroaromatic ring, and/or more N-, O- and/or S-heterocyclic rings, and each N atom in a N-heterocyclic ring may be substituted by C 1 -C 22 alkyl; n is a number from 1 to 4; wherein at least one of the radicals R 1 , R 6 or Q is different from hydrogen; if n = 1 T is -COR 5 ; -CN; C 6 -C 10 aryl; -NHR 5 ; or -SO 2 -(C 6 -C 12 )aryl; R 2 and R 3 independently from each other are C 1 -C 22 alkyl; hydroxy-C 1 -C 22 alkyl; C 2 -C 12 alkenyl; C 2 -C 12 alkinyl; C 3 -C 12 cycloalkyl, C 3 -C 12 cycloalkenyl; C 7 -C 12 aralkyl; C 1 -C 12 heteroalkyl; C 3 -C 12 cycloheteroalkyl; C 6 -C 10 aryl; C 1 -C 9 heteroaryl; or a radical of formula (II); p is a number from 5 to 100; q is a number from 1 to 5; s is a number from 0 to 4; if n = 2 R 2 and R 3 are each C 1 -C 5 alkylene; and simultaneously T is defined as for n = 1; or T is a bivalent radical of formula -NR 7 -V-NR 7 -, wherin V is phenylene; or C 1 -C 5 alkylene; R 7 is hydrogen; or C 1 -C 5 alkyl; and R 2 and R 3 simultaneously are defined as for n = 1; if n = 3 one of R 2 , R 3 or T is a trivalent radical; if n = 4 one of R 2 , R 3 or T is a tetravalent radical; for protecting of human hair and skin against the damaging effect of UV radiation.

2. 发明申请

WO2005106868A1 METAL CHELATES AND THEIR USE IN OPTICAL RECORDING MEDIA HAVING HIGH STORAGE CAPACITY 审中-公开
标题翻译：金属烧结及其在具有高储存能力的光记录介质中的应用
公开(公告)号：WO2005106868A1
公开(公告)日：2005-11-10
申请号：PCT/EP2005/051825
申请日：2005-04-25
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , WOLLEB, Heinz , WOLLEB, Annemarie , BIENEWALD, Frank , SCHMIDHALTER, Beat , BUDRY, Jean-Luc
发明人： WOLLEB, Heinz , WOLLEB, Annemarie , BIENEWALD, Frank , SCHMIDHALTER, Beat , BUDRY, Jean-Luc
IPC分类号： G11B7/24
CPC分类号： G11B7/246 , C07D277/64 , C07D277/84 , C07D417/06 , C07D513/04 , C07F17/02 , G11B7/2467 , G11B7/249 , G11B7/2492 , G11B7/2495 , G11B7/2534 , G11B7/259 , G11B2007/24612 , G11B2007/25706 , G11B2007/2571 , G11B2007/25713 , G11B2007/25715
摘要： The invention relates to novel optical recording media, which comprise particular novel metal chelates and have an excellent recording and playback quality, especially at a wavelength of from 300 to 500 nm.
摘要翻译：本发明涉及新颖的光学记录介质，其包含特别新颖的金属螯合物，并且具有优异的记录和回放质量，特别是在300-500nm的波长下。

3. 发明申请

WO2009077349A1 PROCESS FOR THE PREPARATION OF SEMICONDUCTING LAYERS 审中-公开
标题翻译：制备半导体层的过程
公开(公告)号：WO2009077349A1
公开(公告)日：2009-06-25
申请号：PCT/EP2008066839
申请日：2008-12-05
申请人： CIBA HOLDING INC , BRADLEY GORDON , BUERGI LUKAS , BIENEWALD FRANK
发明人： BRADLEY GORDON , BUERGI LUKAS , BIENEWALD FRANK
IPC分类号： H01L51/10
CPC分类号： H01L51/0545 , B82Y20/00 , B82Y30/00 , H01L51/0004 , H01L51/0558 , H01L2251/5369 , Y02E10/549 , Y02P70/521
摘要： A convenient way for preparing thin layers of organic semiconducting materials comprises application or deposition of particles of a semiconducting material containing an organic semiconductor on a suitable surface, and converting these particles into a semiconducting layer on a substrate by application of pressure and optionally elevated temperatures.
摘要翻译：用于制备有机半导体材料薄层的便利方式包括在合适的表面上施加或沉积含有有机半导体的半导体材料颗粒，并且通过施加压力和任选升高的温度将这些颗粒转变成衬底上的半导体层。

4. 发明申请

WO2003004456A1 PROCESS FOR THE PREPARATION OF 7-AMINO SYN 3,5-DIHYDROXY HEPTANOIC ACID DERIVATIVES VIA 6-CYANO SYN 3,5-DIHYDROXY HEXANOIC ACID DERIVATIVES 审中-公开
标题翻译：通过6-氰基合成3,5-二羟基HEXANOIC酸衍生物制备7-氨基-3,5-二羟基丙酸衍生物的方法
公开(公告)号：WO2003004456A1
公开(公告)日：2003-01-16
申请号：PCT/EP2002/007309
申请日：2002-07-02
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ÖHRLEIN, Reinhold , BAISCH, Gabriele , KIRNER, Hans Jörg , BIENEWALD, Frank , BURKHARDT, Stephan , STUDER, Martin
发明人： ÖHRLEIN, Reinhold , BAISCH, Gabriele , KIRNER, Hans Jörg , BIENEWALD, Frank , BURKHARDT, Stephan , STUDER, Martin
IPC分类号： C07C227/32
CPC分类号： C07C69/67 , C07C69/716 , C07C69/732 , C07C69/738 , C07C227/32 , C07C229/22 , C07C235/06 , C07C235/74 , C12P7/62 , Y02P20/55
摘要： The invention relates to novel synthesis methods for the preparation of the intermediates, which are suitable for the preparation of statin derivatives, especially to novel synthesis methods of the intermediate of formula VI wherein R a and R c are each independently of the other hydrogen or a hydroxy-protecting group or together are a bridging hydroxy-protecting group, and R b is a carboxy-protecting group ,which methods are carried out by conversion of the intermediate of formula XIX wherein R a and R c are each independently of the other hydrogen or a hydroxy-protecting group, and R b is a carboxy-protective group.
摘要翻译：本发明涉及适用于制备他汀类衍生物的中间体的新型合成方法，特别是式VI中间体的新合成方法，其中R a和R c各自独立地为氢或羟基 - 保护基或一起是桥接羟基保护基，Rb是羧基保护基，该方法通过式XIX的中间体转化而进行，其中R a和R c各自独立地为氢或羟基保护基基团，Rb是羧基保护基。

5. 发明申请

WO2003004455A2 SYNTHESIS AND INTERMEDIATES 审中-公开
标题翻译：合成与中间体
公开(公告)号：WO2003004455A2
公开(公告)日：2003-01-16
申请号：PCT/EP2002/007308
申请日：2002-07-02
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ÖHRLEIN, Reinhold , BAISCH, Gabriele , KIRNER, Hans, Jörg , BIENEWALD, Frank , BURKHARDT, Stephan , STUDER, Martin
发明人： ÖHRLEIN, Reinhold , BAISCH, Gabriele , KIRNER, Hans, Jörg , BIENEWALD, Frank , BURKHARDT, Stephan , STUDER, Martin
IPC分类号： C07C227/32
CPC分类号： C07C69/67 , C07C69/716 , C07C69/732 , C07C69/738 , C07C227/32 , C07C229/22 , C07C235/06 , C07C235/74 , C12P7/62 , Y02P20/55
摘要： The invention relates to novel synthesis methods for the preparation of the intermediates, which are suitable for the preparation of statin derivatives, especially to novel synthesis methods of the intermediate of formula VI wherein R a ' and R c ' are each independently of the other hydrogen or a hydroxy-protecting group or together are a bridging hydroxy-protecting group, and R b is a carboxy-protecting group, which methods are carried out by conversion of the intermediate of formula XVI wherein R a ' and R c ' are each independently of the other hydrogen or a hydroxy-protecting group, R* and R** are each independently of the other hydrogen or an amide-protecting group, and R b is a carboxy-protecting group; which methods proceed to further new intermediates and methods for their preparation.
摘要翻译：本发明涉及制备适于制备他汀类衍生物的中间体的合成方法，特别是式（Ⅵ）中间体的合成方法，其中R a'和R c'各自独立地为氢或羟基保护基团或一起是桥接羟基保护基团，Rb是羧基保护基团，该方法通过式（XVI）的中间体的转化来进行，其中R a'和R c'各自独立地为氢或羟基保护基，R *和R **各自独立地为氢或酰胺保护基，Rb为羧基保护基; 哪些方法进行进一步的中间体及其制备方法。

6. 发明申请

WO2009047104A2 PYRROLOPYRROLE DERIVATIVES, THEIR MANUFACTURE AND USE 审中-公开
标题翻译：吡咯烷酮衍生物及其制备和使用
公开(公告)号：WO2009047104A2
公开(公告)日：2009-04-16
申请号：PCT/EP2008/062586
申请日：2008-09-22
申请人： CIBA HOLDING INC. , HAO, Zhimin , SCHMIDHALTER, Beat , BUDRY, Jean-Luc , FONTANA, Margherita , TURBIEZ, Mathieu G. R. , BIENEWALD, Frank , DÜGGELI, Mathias , AEBISCHER, Olivier Frédéric , HAYOZ, Pascal , FONRODONA TURON, Marta
发明人： HAO, Zhimin , SCHMIDHALTER, Beat , BUDRY, Jean-Luc , FONTANA, Margherita , TURBIEZ, Mathieu G. R. , BIENEWALD, Frank , DÜGGELI, Mathias , AEBISCHER, Olivier Frédéric , HAYOZ, Pascal , FONRODONA TURON, Marta
IPC分类号： C07D487/04 , H01L51/00
CPC分类号： H01L51/0071 , C07D487/04 , C09B57/004 , H01L51/0053 , H01L51/0058 , H01L51/0068 , H01L51/0095 , Y02E10/549
摘要： The present invention relates to compounds of the formula (I) wherein the substituents are as defined in claim 1, and their use as organic semiconductor in organic devices, like diodes, organic field effect transistors and/or a solar cells. The compounds of the formula I have excellent solubility in organic solvents. High efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when said compounds are used in semiconductor devices or organic photovoltaic (PV) devices (solar cells).
摘要翻译：本发明涉及式（I）化合物，其中取代基如权利要求1中所定义，及其作为有机半导体在有机器件中的用途，如二极管，有机场效应晶体管和/或太阳能电池。式I的化合物在有机溶剂中具有优异的溶解性。当所述化合物用于半导体器件或有机光伏（PV）器件（太阳能电池））时，可以观察到高效率的能量转换，优异的场效应迁移率，良好的导通/截止电流比和/或优异的稳定性。

7. 发明申请

WO2007118799A1 QUINOID SYSTEMS AS ORGANIC SEMICONDUCTORS 审中-公开
标题翻译： QUINOID系统作为有机半导体
公开(公告)号：WO2007118799A1
公开(公告)日：2007-10-25
申请号：PCT/EP2007/053314
申请日：2007-04-04
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , BERENS, Ulrich , STASSEN, Arno , SCHMIDHALTER, Beat , KALB, Wolfgang , BIENEWALD, Frank
发明人： BERENS, Ulrich , STASSEN, Arno , SCHMIDHALTER, Beat , KALB, Wolfgang , BIENEWALD, Frank
IPC分类号： H01L51/00
CPC分类号： H01L51/0074 , C07D493/04 , C07D493/22 , C07D495/04 , H01L51/0055 , H01L51/0073 , H01L51/0529 , H01L51/0533 , H01L51/0545 , Y02E10/549
摘要： A semiconducting layer comprising a non-polymeric quinoid heteroacene compound of the formula (I) wherein X stands for O, S or NR, each of R, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 being independently selected from hydrogen and an organic residue, or 2 or more thereof together forming one or more annealed rings, which may be substituted or unsubstituted, carbocyclic or heterocyclic, aromatic, quinoid or aliphatic, may be used e.g. for the manufacture of a diode, an organic field effect transistor, an organic thin film transistor, or a device containing a diode and/or an organic field effect transistor and/or organic thin film transistor.
摘要翻译：一种半导体层，其包含式（I）的非聚合醌型杂并烯化合物，其中X代表O，S或NR，R，R 1，R 2， R 3，R 4，R 5，R 6，R 7， R 8独立地选自氢和有机残基，或其中2个或更多个一起形成一个或多个退火环，其可以是取代或未取代的，碳环或杂环的，芳族的，醌型的或脂族的，可以使用例如用于制造二极管，有机场效应晶体管，有机薄膜晶体管或包含二极管和/或有机场效应晶体管和/或有机薄膜晶体管的器件。

8. 发明申请

WO2006120143A1 AZAPERYLENES AS ORGANIC SEMICONDUCTORS 审中-公开
标题翻译： AZAPERYLENES作为有机半导体
公开(公告)号：WO2006120143A1
公开(公告)日：2006-11-16
申请号：PCT/EP2006/062007
申请日：2006-05-03
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , BIENEWALD, Frank , SCHMIDHALTER, Beat , BERENS, Ulrich , KIRNER, Hans, Jürg
发明人： BIENEWALD, Frank , SCHMIDHALTER, Beat , BERENS, Ulrich , KIRNER, Hans, Jürg
IPC分类号： H01L51/00
CPC分类号： C09B5/028 , C07D471/06 , H01L51/0067 , H01L51/0069 , H01L51/0071 , H01L51/0072 , H01L51/0512 , H01L51/0541 , H01L51/5012 , Y10S428/93
摘要： A novel semiconductor device comprises an azaperylene organic semiconductor of the formula I (I) wherein each of R1 , R2, R3 and R4 independently is selected from H, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl, halogen, Si(RH ) 3, XR6; or one or more of R1 and R2, R2 and R3, R3 and R4, together with the carbon atoms they are bonding to, form a saturated or unsaturated, unsubstituted or substituted carbocyclic or heterocyclic ring; R5 is OR7, SR7, NR7R8, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, or unsubstituted or substituted aryl; R6 is Si(R11 ) 3, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl; R7 is H, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl; X is O, S, NR8; Rδ is H, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl, R11 being C 1 -C 20 -alkyl or -alkoxy.
摘要翻译：一种新颖的半导体器件包括式I（I）的氮杂伯有机半导体，其中R1，R2，R3和R4各自独立地选自H，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，未取代或取代的芳基，卤素，Si（RH）3，XR6; 或R 1和R 2，R 2和R 3，R 3和R 4中的一个或多个与它们键合的碳原子一起形成饱和或不饱和的未取代或取代的碳环或杂环; R5是OR7，SR7，NR7R8，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，或未取代或取代的芳基; R6是Si（R11）3，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，未取代或取代的芳基; R 7为H，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，未取代或取代的芳基; X是O，S，NR8; Rd为H，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，未取代或取代的芳基，R11为C 1 -C 20 - 烷基或 - 烷氧基。

9. 发明申请

WO2005000972A3 OPTICAL RECORDING MATERIALS HAVING HIGH STORAGE DENSITY 审中-公开
标题翻译：具有高储存密度的光学记录材料
公开(公告)号：WO2005000972A3
公开(公告)日：2005-10-27
申请号：PCT/EP2004051256
申请日：2004-06-25
申请人： CIBA SC HOLDING AG , SCHMIDHALTER BEAT , ZAMBOUNIS JOHN S , WOLLEB HEINZ , WOLLEB ANNEMARIE , BIENEWALD FRANK , BUDRY JEAN-LUC , SPAHNI HEINZ
发明人： SCHMIDHALTER BEAT , ZAMBOUNIS JOHN S , WOLLEB HEINZ , WOLLEB ANNEMARIE , BIENEWALD FRANK , BUDRY JEAN-LUC , SPAHNI HEINZ
IPC分类号： C09B47/26 , G11B7/248 , C09B47/00 , G11B7/24
CPC分类号： G11B7/248 , C09B47/26
摘要： The invention relates to an optical recording medium comprising a substrate, a recording layer and optionally one or more reflecting layers, wherein the recording layer comprises a compound of formula (I). For the detailed definitions of the further substituents, see the description. Recording and playback are effected especially at a wavelength of from 300 to 500 nm, for example using a blue laser. The recording and playback quality is excellent and allows a high storage density even at high speeds.
摘要翻译：本发明涉及一种光学记录介质，其包括基底，记录层和任选地一个或多个反射层，其中所述记录层包含式（I）的化合物。有关其他取代基的详细定义，请参阅说明。记录和回放特别是在300-500nm的波长下进行，例如使用蓝色激光。录制和播放质量非常好，即使在高速下也可以实现高存储密度。

10. 发明申请

WO2005012228A1 O-COORDINATED METAL CHELATES AND THEIR USE IN OPTICAL RECORDING MEDIA HAVING HIGH STORAGE CAPACITY 审中-公开
标题翻译： O协调金属制品及其在具有高储存能力的光记录介质中的使用
公开(公告)号：WO2005012228A1
公开(公告)日：2005-02-10
申请号：PCT/EP2004/051447
申请日：2004-07-12
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , BIENEWALD, Frank , BUDRY, Jean-Luc , SCHMIDHALTER, Beat , WOLLEB, Annemarie , WOLLEB, Heinz
发明人： BIENEWALD, Frank , BUDRY, Jean-Luc , SCHMIDHALTER, Beat , WOLLEB, Annemarie , WOLLEB, Heinz
IPC分类号： C07C225/18
CPC分类号： G11B7/246 , C07C225/14 , C07D207/20 , C07D209/12 , C07D209/34 , C07D211/86 , C07D213/69 , C07D233/48 , C07D235/30 , C07D239/62 , C07D239/66 , C07D263/14 , C07D277/64 , C07D277/82 , C07D309/32 , C07D309/38 , C07D319/06 , C07D403/06 , G11B7/247 , G11B7/249 , G11B7/2534 , G11B7/259
摘要： The invention relates to novel o ptical recording materials that comprise specific and in some cases novel diketone enamines or metal chelates thereof and that have excellent recording and playback quality especially ata wavelength of 350-500 nm. The invention accordingly relates to an optical recording medium comprising a substrate, a recording layer and optionally a reflecting layer, wherein the recording layer comprises a compound of formula (I), wherein M is hydrogen, aluminium or, preferably, a transition metal, which may in addition be coordinated with one or more further ligands and/or, for balancing out an excess charge, where applicable, may have an electrostatic interaction with one or more further ions inside or outside the coordination sphere, but M in formulae (Ib) and (Ic) is not hydrogen, Q is C-H, N or C-R 6 , it being possible for the stereochernistry of the C=Q double bond to be either E or Z. For the exact definitions of R 1 to R 6 reference should be made to the description. Also claimed are the novel compounds, especially tetracoordinated chelates, and a process for the preparation thereof.
摘要翻译：本发明涉及新颖的记录材料，其特别包括新颖的二酮烯胺或其金属螯合物，并且具有优异的记录和回放质量，特别是在350-500nm的波长。因此，本发明涉及一种包括基底，记录层和任选地反射层的光学记录介质，其中记录层包含式（I）化合物，其中M是氢，铝或优选的过渡金属，其中可以另外与一个或多个其它配位体配位和/或用于平衡过量电荷（如果适用的话）可以与配位球内部或外部的一个或多个另外的离子具有静电相互作用，而式（Ib）和（Ic）不是氢，Q是CH，N或C-R6，C = Q双键的立体选择可能是E或Z。对于R1至R6的确切定义，应该进行参考的描述。还要求的是新化合物，特别是四配位螯合物，以及其制备方法。

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