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    • 8. 发明申请
    • IMPACT-MODIFIED MOLDING COMPOSITION AND METHOD
    • 冲击改性成型组合物和方法
    • WO2006127223A1
    • 2006-11-30
    • PCT/US2006/016988
    • 2006-05-03
    • GENERAL ELECTRIC COMPANYDHAWAN, SandeepBERZINIS, Albin, PeterKALYANARAMAN, Viswanathan
    • DHAWAN, SandeepBERZINIS, Albin, PeterKALYANARAMAN, Viswanathan
    • C08F291/02C08F265/04C08F285/00
    • C08F285/00
    • A method is disclosed for preparing an acrylic-styrene-acrylonitrile (ASA) resin, which comprises the steps of: (a) polymerizing a mixture comprising at least one acrylate monomer and at least one crosslinking agent to form a rubber substrate, followed by (b) polymerizing a mixture of monomers in the presence of the rubber substrate, at least one of which monomers is selected from the group consisting of vinyl aromatic monomers and at least one of which monomers is selected from the group consisting of monoethylenically unsaturated nitrile monomers, and optionally followed by (c) polymerizing one or more monomers in at least one subsequent stage in the presence of the rubber substrate from (b), wherein the one or more monomers comprise at least one monomer selected from the group consisting of (C 1 -C 12 ) alkyl- and aryl-(meth)acrylate monomers; wherein the amount of unreacted crosslinking agent remaining in the rubber substrate before step (b) is less than 5.6 micromoles per gram based on the dry weight of the rubber substrate. The invention also relates to a molding composition comprising an ASA resin comprising an elastomeric phase derived from a rubber substrate comprising structural units derived from at least one crosslinking agent; wherein the rubber substrate comprises less than 5.6 micromoles of unreacted crosslinking agent per gram of rubber substrate based on dry weight of the rubber substrate. Articles comprising said ASA resin and/or made from said molding composition are also disclosed.
    • 公开了一种用于制备丙烯酸 - 苯乙烯 - 丙烯腈(ASA)树脂的方法,其包括以下步骤:(a)使包含至少一种丙烯酸酯单体和至少一种交联剂的混合物聚合以形成橡胶基材,然后( b)在橡胶基质的存在下聚合单体的混合物,其中至少一种单体选自乙烯基芳族单体,并且其中至少一种单体选自单烯属不饱和腈单体, (c)在(b)中在橡胶基质存在下的至少一个后续阶段中聚合一种或多种单体,其中所述一种或多种单体包含至少一种选自(C 1〜 (甲基)丙烯酸烷基酯和/或(甲基)丙烯酸酯单体; 其中在步骤(b)之前残留在橡胶基材中的未反应交联剂的量相对于橡胶基材的干重小于5.6微摩尔/克。 本发明还涉及包含ASA树脂的模塑组合物,其包含衍生自橡胶基质的弹性体相,其包含衍生自至少一种交联剂的结构单元; 其中所述橡胶基材基于所述橡胶基材的干重,每克橡胶基材包含小于5.6微摩尔的未反应交联剂。 还公开了包含所述ASA树脂和/或由所述模塑组合物制成的制品。
    • 9. 发明申请
    • IMPACT-MODIFIED COMPOSITIONS AND METHOD
    • 影响改性的组合物和方法
    • WO2005000938A1
    • 2005-01-06
    • PCT/US2004/014343
    • 2004-05-07
    • GENERAL ELECTRIC COMPANYBERZINIS, Albin, PeterGAGGAR, Satish, Kumar
    • BERZINIS, Albin, PeterGAGGAR, Satish, Kumar
    • C08G63/00
    • C08F285/00C08L51/003C08L51/04Y10T428/31507C08F220/10C08L2666/02
    • The present invention relates to a rubber modified thermoplastic resin composition comprising a discontinuous elastomeric phase dispersed in a rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is grafted to the elastomeric phase, which is prepared by a method comprising the steps of. (a) polymerizing a mixture of monomers in a first stage in the presence of the elastomeric phase, at least one of which monomers is selected from the group consisting of vinyl aromatic monomers and at least one of which monomers is selected from the group consisting of monoethylenically unsaturated nitrile monomers, followed by (b) polymerizing one or more monomers in at least one subsequent stage in the presence of the elastomeric phase from (a), wherein the one or more monomers comprise at least one monomer selected from the group consisting of (C 1 -C 12 )alkyl- and aryl­(meth)acrylate monomers. The method is also provided.
    • 本发明涉及一种橡胶改性的热塑性树脂组合物,其包含分散在刚性热塑性相中的不连续的弹性体相,其中刚性热塑性相的至少一部分接枝到弹性体相,其通过包括以下步骤的方法制备: 。 (a)在弹性体相存在下在第一阶段聚合单体的混合物,其中至少一种单体选自乙烯基芳族单体,并且其中至少一种单体选自: 单烯属不饱和腈单体,然后(b)在来自(a)的弹性体相存在下的至少一个后续阶段中聚合一种或多种单体,其中所述一种或多种单体包含至少一种选自以下的单体: (C1-C12)烷基 - 和(甲基)丙烯酸芳基酯单体。 还提供了该方法。