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    • 2. 发明授权
    • Aqueous coating material, especially aqueous filler or protective base against stones
    • 水性涂​​料,特别是水性填料或防锈底物
    • US06815494B2
    • 2004-11-09
    • US10396893
    • 2003-03-25
    • Georg WiggerUlrike RöckrathBärbel WiatrMarita SchillingRalf Stein
    • Georg WiggerUlrike RöckrathBärbel WiatrMarita SchillingRalf Stein
    • C08J303
    • C08G18/12C08G18/0823C08G18/348C08G18/4288C08G18/6659C09D175/04Y10T428/31511Y10T428/31551C08G18/42C08G18/286C08G18/792C08L75/04C08L67/00
    • Aqueous coating material comprising (A) water-dispersible hydroxy-functional binder component containing urethane groups, (B) water-dispersible binder component containing urethane groups and blocked isocyanate groups, (C) water-dispersible amino resin, and optionally (D) water-dispersible hydroxy-functional polyester, the binder component (B) being preparable by (B1) preparing a polyurethane prepolymer containing isocyanate groups from at least one polyol and at least one polyisocyanate, (B2) reacting the polyurethane prepolymer (B1) containing isocyanate groups with a chain extender to give a hydroxyl-containing chain-extended polyurethane prepolymer, (B3) reacting the hydroxyl-containing chain-extended polyurethane prepolymer (B2) with at least one polyisocyanate to give a further polyurethane prepolymer containing isocyanate groups, and (B4) blocking some or all of the isocyanate groups of the chain-extended polyurethane prepolymer (B3) containing isocyanate groups with a blocking agent to give a polyurethane containing blocked isocyanate groups, and then, where appropriate, (B5) reacting remaining free isocyanate groups in the polyurethane (B4) with a chain extender.
    • 包含(A)含有氨基甲酸酯基的水分散性羟基官能粘合剂组分的水性涂料,(B)含有氨基甲酸酯基和封端异氰酸酯基的水分散性粘合剂组分,(C)水分散性氨基树脂和任选的(D)水 可分解的羟基官能的聚酯,(B1)由至少一种多元醇和至少一种多异氰酸酯制备含有异氰酸酯基团的聚氨酯预聚物(B2)制备的粘合剂组分(B),(B2)使含有异氰酸酯基团的聚氨酯预聚物 与扩链剂一起得到含羟基的链延长的聚氨酯预聚物,(B3)使含羟基的链延长的聚氨酯预聚物(B2)与至少一种多异氰酸酯反应,得到另外的含异氰酸酯基团的聚氨酯预聚物,和(B4 )阻断含有异氰酸酯基团的链延长聚氨酯预聚物(B3)的一部分或全部异氰酸酯基团 得到含有封端异氰酸酯基团的聚氨酯,然后在适当的情况下(B5)使聚氨酯(B4)中剩余的游离异氰酸酯基与扩链剂反应。