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    • 5. 发明授权
    • Zirconia based ceramic material
    • 氧化锆基陶瓷材料
    • US5728636A
    • 1998-03-17
    • US544285
    • 1995-10-17
    • Masahiro NawaShoichi NakamotoKeiichi YamasakiKoichi NiiharaAtsushi NakahiraTohru Sekino
    • Masahiro NawaShoichi NakamotoKeiichi YamasakiKoichi NiiharaAtsushi NakahiraTohru Sekino
    • C04B35/49C04B35/119C04B35/48C04B35/488
    • C04B35/488C04B35/119
    • A zirconia based ceramic material having improved and well-balanced mechanical strength and toughness consists essentially of 0.5 to 50 vol % of Al.sub.2 O.sub.3 having an average grain size of 2 .mu.m or less and the balance of a partially stabilized zirconia having an average grain size of 5 .mu.m or less. The partially stabilized zirconia consists essentially of 8 to 12 mol % of CeO.sub.2, 0.05 to 4 mol % of TiO.sub.2 and the balance of ZrO.sub.2. Fine Al.sub.2 O.sub.3 grains having an average grain size of 1 .mu.m or less are dispersed within the grains of the partially stabilized zirconia at a dispersion ratio. The dispersion ratio is defined as a ratio of the number of Al.sub.2 O.sub.3 grains dispersed within the grains of the partially stabilized zirconia relative to the number of the entire Al.sub.2 O.sub.3 grains dispersed in the ceramic material, and at least 2% in the present invention. The ceramic material can be made by the following process. A first constituent formed of the partially stabilized zirconia is mixed with a second constituent formed of Al.sub.2 O.sub.3 to obtain a mixture. The mixture is molded into a desired shape, and then sintered in the air under an atmospheric pressure to obtain the ceramic material.
    • 具有改善的良好平衡的机械强度和韧性的氧化锆基陶瓷材料基本上由平均粒径为2μm或更小的0.5至50vol%的Al 2 O 3组成,平均晶粒尺寸为 5亩以下。 部分稳定的氧化锆基本上由8〜12mol%的CeO 2,0.05〜4mol%的TiO 2和余量的ZrO 2组成。 平均粒径为1μm以下的细Al​​ 2 O 3粒子以分散比分散在部分稳定化的氧化锆的晶粒内。 分散比定义为分散在部分稳定的氧化锆的晶粒内的Al 2 O 3颗粒的数量相对于分散在陶瓷材料中的整个Al 2 O 3颗粒的数量的比率,并且在本发明中至少为2%。 陶瓷材料可以通过以下方法制成。 由部分稳定的氧化锆形成的第一组分与由Al 2 O 3形成的第二组分混合以获得混合物。 将混合物成型为所需形状,然后在大气压下在空气中烧结,得到陶瓷材料。