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1. 发明申请

WO1998012234A1 PROCESS FOR THE POLYMERIZATION OF 'alpha'-OLEFINS, A CATALYST USED IN THE POLYMERIZATION AND ITS PREPARATION 审中-公开
标题翻译： α-烯烃的聚合方法，聚合反应中使用的催化剂及其制备方法
公开(公告)号：WO1998012234A1
公开(公告)日：1998-03-26
申请号：PCT/FI1997000562
申请日：1997-09-19
申请人： BOREALIS POLYMERS OY , GAROFF, Thomas , LEINONEN, Timo , ALA-HUIKKU, Sirpa
发明人： BOREALIS POLYMERS OY
IPC分类号： C08F04/654
CPC分类号： C08F10/00 , C08F4/6543 , C08F4/651
摘要： In the polymerization of C3-C12- alpha -olefins, the activity of the catalyst and the isotacticity and molecular weight of the polymer product can be adjusted and improved in a controlled manner by a new process wherein: A) a catalyst system is prepared by bringing a support which comprises magnesium chloride, a derivative thereof or a reagent forming it into contact with at least titanium tetrachloride or a reagent forming it, in order to produce a titanated support; by bringing the titanated support into contact with at least a group 1, 2 or 13 metal compound which contains a C1-C10-alkyl and activates titanium tetrachloride to a catalytically active titanium group, in order to produce an activated support; and by bringing a substance selected from among the said support, titanated support and activated support into contact with at least one donor or a reagent forming it, in order to produce a catalyst system; B) polymerization is carried out using the catalyst system by bringing it into contact with at least a C3-C12- alpha -olefin, whereupon poly-C3-C12- alpha -olefin chains are formed in the catalytically active titanium groups, and preferably by bringing the said catalyst system, the said C3-C12- alpha -olefin and the said poly-C3-C12- alpha -olefin chains into contact with hydrogen or some other similar chain transfer agent, whereupon a poly-C3-C12- alpha -olefin terminated with hydrogen or suchlike is formed. In the process the improvement is achieved so that, in step A), i) a first controlled amount of a less soluble internal donor and a second controlled amount of a more soluble internal donor are provided on the surface of the said support, titanated support or activated support, in order to produce an internal donoration product, and ii) the internal donoration product is brought into contact with at least one eluant eluting the more soluble internal donor and with at least one external donor or a reagent forming it, in order to produce an external donoration product, the catalyst system thereby formed having at least catalytically active titanium groups, the said first controlled amount of the less soluble internal donor and the said second controlled amount comprising external donor.
摘要翻译：在C3-C12-α-烯烃的聚合反应中，催化剂的活性和聚合物产物的全同立构规整度和分子量可以通过新方法以受控的方式进行调节和改进，其中：A）催化剂体系由得到包含氯化镁，其衍生物或形成它的试剂与至少四氯化钛或形成它的试剂接触的载体，以产生钛酸化载体; 通过使钛酸化的载体与至少一种含有C 1 -C 10 - 烷基的1,2或13族金属化合物接触并将四氯化钛活化成催化活性的钛基团，以便产生活化的载体; 并且通过将选自所述载体，钛酸化载体和活化载体的物质与形成它的至少一种供体或试剂接触，以便产生催化剂体系; B）使用催化剂体系使其与至少一种C 3 -C 12-α-烯烃接触进行聚合，由此在催化活性钛基团中形成聚-C3-C12-α-烯烃链，优选通过使所述催化剂体系，所述C3-C12-α-烯烃和所述聚C3-C12-α-烯烃链与氢或一些其它类似的链转移剂接触，因此，聚-C3-C12- 形成用氢等等终止的烯烃。在该过程中，实现改进，使得在步骤A）中，i）在所述载体的表面上提供第一受控量的较不溶的内部供体和第二受控量的更可溶内部供体，钛化载体或活化的载体，以产生内部赋形产品，和ii）使内部引发产物与至少一种洗脱洗脱更多可溶性内部供体的洗脱液接触，并与至少一种外部供体或形成它的试剂按顺序由此形成的催化剂体系至少具有催化活性的钛基团，所述第一受控量的较不溶的内部供体和所述第二受控量包含外部供体。

2. 发明申请

WO1997036938A1 COMPOSITION CONTAINING MAGNESIUM, TITANIUM, HALOGEN AND AN INNER ELECTRON DONOR, ITS PREPARATION AND USE FOR THE POLYMERIZATION OF 'alpha'-OLEFINS 审中-公开
标题翻译：包含镁，钛，卤素和内在电子的组合物，其制备和用于α-烯烃聚合的用途
公开(公告)号：WO1997036938A1
公开(公告)日：1997-10-09
申请号：PCT/FI1997000191
申请日：1997-03-26
申请人： BOREALIS A/S , GAROFF, Thomas , LEINONEN, Timo , ALA-HUIKKU, Sirpa
发明人： BOREALIS A/S
IPC分类号： C08F04/654
CPC分类号： C08F10/00 , C07F7/003 , C08F10/06 , C08F110/06 , C08F210/06 , C08F4/651 , C08F4/6543 , C08F2500/18 , C08F2500/12 , C08F210/16
摘要： The invention relates to a composition containing magnesium, titanium, halogen and an inner electron donor. The composition is soluble, and it is prepared by bringing into contact with each other at a prescribed temperature and reacting the complex MgX 2.nR OH, where X is a halogen, R is a C1-C20 alkyl, and n is in the range 2.0-6.4, a titanium tetrahalide TiX 4, where X is a halogen, and a carboxylic acid ester, to yield a reaction product. The said reaction product is obtained in the liquid, preferably dissolved, state by using: (a) carboxylic acid ester that contains at least 8.j carbon atoms and is compatible with the following Formula (I): R (COOR )j, where R is a j-valen C1-C34 hydrocarbon group, R is a C6-C20 alkyl group, and j is an integer from 1 to 4; (b) a molar ratio R (COOR )j/MgX .nR OH that is >/= approximately 0.8/j; (c) a molar ratio TiX 4/MgX 2.nR OH that is >/= approximately n; (d) possibly an organic dissolvent substance S; and (e) a temperature that is in the range 40-200 DEG C.
摘要翻译：本发明涉及含有镁，钛，卤素和内电子给体的组合物。组合物是可溶的，并且通过在规定的温度下彼此接触并使复合物MgX 1·nR 1 OH反应来制备，其中X 1是卤素，R 1是 C 1 -C 20烷基，n在2.0-6.4范围内，四卤化钛TiX 2 4，其中X 2是卤素，和羧酸酯，得到反应产物。所述反应产物通过使用：（a）含有至少8.j个碳原子并与下式（I）相容的羧酸酯在液体中，优选溶解状态下获得：R 2（COOR < 3）j，其中R 2是j-戊烯C 1 -C 34烃基，R 3是C 6 -C 20烷基，j是1至4的整数; （b）摩尔比R 2（COOR 3）j / MgX 1·nR 1 OH，其大于/约为0.8 / j; （c）大于或等于n的摩尔比TiX 2 / MgX 1·nR 1 OH; （d）可能有机溶剂物质S; 和（e）温度在40-200℃

3. 发明申请

WO2003031486A1 PROCESS FOR THE PRODUCTION OF PROPYLENE COPOLYMERS 审中-公开
标题翻译：制备丙烯共聚物的方法
公开(公告)号：WO2003031486A1
公开(公告)日：2003-04-17
申请号：PCT/EP2002/011092
申请日：2002-10-02
申请人： BOREALIS TECHNOLOGY OY , ALASTALO, Kauno , PITKÄNEN, Päivi , SUTELA, Marita , PELCKMANS, Lucas , ALA-HUIKKU, Sirpa , HOKKANEN, Harri
发明人： ALASTALO, Kauno , PITKÄNEN, Päivi , SUTELA, Marita , PELCKMANS, Lucas , ALA-HUIKKU, Sirpa , HOKKANEN, Harri
IPC分类号： C08F210/06
CPC分类号： C08F210/16 , C08F210/06 , C08F4/022 , C08F4/651 , C08F4/6543 , C08F210/08 , C08F2500/12 , C08F2500/26
摘要： Polymers of propylene with one or two olefin comonomers are produced through the use of a poymerisation catalyst supported on a carrier produced by spray crystallisation and having a maximum dimension of μm. Copolymers of superior properties are obtained, and the production process is de-snagged.
摘要翻译：丙烯与一种或两种烯烃共聚单体的聚合物通过使用负载在由喷雾结晶产生并具有μm最大尺寸的载体上的催化剂催化剂来制备。获得优异性能的共聚物，并且生产过程脱钩。

4. 发明申请

WO1993013141A1 PROCATALYST COMPOSITION FOR HOMO- AND COPOLYMERIZATION OF ALPHA OLEFINS, ITS PREPARATION AND ITS USE 审中-公开
标题翻译： ALPHA烯烃的共聚合和其共聚物的制备及其使用的方法
公开(公告)号：WO1993013141A1
公开(公告)日：1993-07-08
申请号：PCT/FI1992000362
申请日：1992-12-23
申请人： NESTE OY , ALA-HUIKKU, Sirpa , LOMMI, Marjaana
发明人： NESTE OY
IPC分类号： C08F04/654
CPC分类号： C08F10/00 , C08F4/6546 , C08F4/6555
摘要： A procatalyst composition which is suitable for the homo- and copolymerization of alpha olefins together with an organometallic cocatalyst compound and which is prepared by treating an inorganic carrier with a component system containing a complex of a magnesium halide and a tetraalkyl titanate, and a chlorinating compound which does not contain a transition metal compound. In order to raise the Mg:Ti ratio, the component system additionally contains an organomagnesium compound.
摘要翻译：一种适用于α-烯烃与有机金属助催化剂化合物同时和共聚合的主催化剂组合物，其通过用含有卤化镁和钛酸四烷基酯的络合物的组分体系和氯化化合物处理无机载体而制备其不含过渡金属化合物。为了提高Mg:Ti比，组分体系另外含有有机镁化合物。

5. 发明申请

WO1991008239A1 PROCATALYST COMPOSITION FOR THE POLYMERIZATION OF 'alpha'-OLEFINES, PREPARATION AND USE 审中-公开
标题翻译： α-烯烃聚合的制备和使用的处理组合物
公开(公告)号：WO1991008239A1
公开(公告)日：1991-06-13
申请号：PCT/FI1990000287
申请日：1990-11-27
申请人： NESTE OY , ALA-HUIKKU, Sirpa , LOMMI, Marjaana , IISKOLA, Eero
发明人： NESTE OY
IPC分类号： C08F04/638
CPC分类号： C08F10/00 , C08F4/6367 , C08F4/6383
摘要： The present invention relates to a procatalyst composition for the polymerization of alfa-olefines, which has been prepared in steps, in which is arranged a carrier agent based on at least one inorganic oxide, having few or no hydroxyl groups on its surface, and the carrier agent is reacted with the magnesium compound and one or more transition metal compounds of the groups IVB an VB of the periodic table. It has been observed that such a catalyst is most advantageous when a) this carrier agent is impregnated with a mixture of the Mg compound and one or more compounds of a transition metal of the groups IVb or Vb of the periodic table, which dissolves the Mg compound, and b) by chlorinating with a compound that does not contain titanium so that 1) the carrier is first treated with a mixture in the form of a solution of the Mg compound and the transition metal compound and the product thus obtained is chlorinated, or 2) the carrier is first chlorinated and subsequently treated with the above mixture in the form of a solution, or 3) the Mg compound and the transition metal compound are impregnated into the carrier without any separate dissolving and the product thus obtained is chlorinated.
摘要翻译：本发明涉及用于α-烯烃聚合的前催化剂组合物，其已经按步骤制备，其中在其表面上布置有基于至少一种在其表面上具有很少或不含羟基的无机氧化物的载体剂，载体剂与镁化合物和一种或多种元素周期表的IVB族和VB族的过渡金属化合物反应。已经观察到，当a）用Mg化合物与周期表IVb或Vb族的过渡金属的一种或多种化合物的混合物浸渍该载体剂时，这种催化剂是最有利的，其溶解Mg 化合物，和b）通过用不含钛的化合物进行氯化，使得1）载体首先用Mg化合物和过渡金属化合物的溶液形式的混合物处理，并将所得产物氯化，或2）首先将载体氯化并随后用溶液形式的上述混合物处理，或3）将Mg化合物和过渡金属化合物浸渍到载体中而不会单独溶解，并将得到的产物进行氯化。

6. 发明申请

WO1998022514A1 PROCESS FOR MAKING PROPYLENE HOMO OR COPOLYMERS 审中-公开
标题翻译：制备丙烯共聚物的方法
公开(公告)号：WO1998022514A1
公开(公告)日：1998-05-28
申请号：PCT/FI1997000702
申请日：1997-11-17
申请人： BOREALIS A/S , ALA-HUIKKU, Sirpa , GAROFF, Thomas , LEINONEN, Timo , HARLIN, Ali , BERGMANN, Fred
发明人： BOREALIS A/S
IPC分类号： C08F02/00
CPC分类号： C08F10/06 , C08F110/06 , Y10S526/903 , C08F2/14 , C08F4/651 , C08F2/001 , C08F2500/12 , C08F2500/18 , C08F2500/15
摘要： A process for homo or copolymerizing propylene, wherein propylene is polymerized in the presence of a catalyst at an elevated temperature in a reaction medium, in which a major part is formed by propylene. The polymerization is carried in at least one slurry reactor in the presence of liquid propylene at a temperature between 80-91 DEG C and a catalyst system producing within said temperature range a high productivity and essentially constant isotacticity within wide melt index range.
摘要翻译：丙烯均聚或共聚的方法，其中丙烯在催化剂存在下在升高的温度下在反应介质中聚合，其中主要部分由丙烯形成。在液体丙烯存在下，在80-91℃的温度和在所述温度范围内产生的催化剂体系中的聚合反应在高熔点指数范围内产生高生产率和基本恒定的全同立构规整度。

7. 发明申请

WO1997036939A1 A NOVEL COMPOSITION, ITS PREPARATION AND USE 审中-公开
标题翻译：新型组合物，其制备和使用
公开(公告)号：WO1997036939A1
公开(公告)日：1997-10-09
申请号：PCT/FI1997000192
申请日：1997-03-26
申请人： BOREALIS A/S , GAROFF, Thomas , LEINONEN, Timo , ALA-HUIKKU, Sirpa
发明人： BOREALIS A/S
IPC分类号： C08F04/654
CPC分类号： C08F10/00 , C07F7/003 , C08F10/06 , C08F110/06 , C08F210/06 , C08F4/651 , C08F4/6543 , C08F2500/18 , C08F2500/12 , C08F210/16
摘要： A novel soluble composition containing magnesium, titanium, a halogen and a carboxylic acid ester has been invented. The composition has mainly the composition according to the formula (I): (MgX 2)xTiX 4 (R(COOR')n)y wherein X is a halogen, X is a halogen, R(COOR')n is a carboxylic acid higher alkyl ester containing at least 8.n carbon atoms, wherein R is an n-valent substituted or unsubstituted C1-C34 hydrocarbon group, R' is a C1-C20 alkyl group, and n is an integer from 1 to 4, x is between 0.5 and 4.0, and y is between 0.8/n and 2.4/n.
摘要翻译：已经发明了含有镁，钛，卤素和羧酸酯的新型可溶性组合物。该组合物主要具有式（I）的组成：（MgX 3）x TiX 4（R（COOR'）n）y，其中X 3为卤素，X 4为卤素，R（COOR'）n是含有至少8.n个碳原子的羧酸高级烷基酯，其中R是n价取代或未取代的C 1 -C 34烃基，R'是C 1 -C 20烷基， n为1〜4的整数，x为0.5〜4.0，y为0.8 / n〜2.4 / n。

8. 发明申请

WO1991016361A1 PROCATALYST COMPOSITION FOR THE POLYMERIZATION OF OLEFINS, ITS PREPARATION AND USE 审中-公开
标题翻译：烯烃聚合的方法组合物及其制备和使用
公开(公告)号：WO1991016361A1
公开(公告)日：1991-10-31
申请号：PCT/FI1991000111
申请日：1991-04-12
申请人： NESTE OY , ALA-HUIKKU, Sirpa , SORMUNEN, Pekka
发明人： NESTE OY
IPC分类号： C08F04/02
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08F4/6567 , C08F4/6141 , C08F4/6155 , C08F2500/12 , C08F2500/18 , C08F210/08
摘要： According to the invention a novel procatalyst composition suitable for polymerization of olefins has been prepared. It is prepared by treating a solid carrier with (a) a magnesium halide compound, (b) such a magnesium halide dissolving transition metal compound, which contains no chlorine, and (c) an electron donor compound dissolving/suspending said magnesium halide compound. The precursor product which is obtained after the said steps (a)-(c) which are carried out in different sequences, has additionally been treated with a chlorine compound containing no transition metal, or with a mixture of said chlorine compound and an organometallic compound.
摘要翻译：根据本发明，已经制备了适用于烯烃聚合的新型前催化剂组合物。通过用（a）卤化镁化合物，（b）不含氯的卤化镁溶解的过渡金属化合物处理固体载体和（c）溶解/悬浮所述卤化镁化合物的电子给体化合物来制备。在以不同顺序进行的所述步骤（a） - （c）之后获得的前体产物另外用不含过渡金属的氯化合物或所述氯化合物和有机金属化合物的混合物。

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