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    • 3. 发明申请
    • NON-AQUEOUS REDOX FLOW BATTERIES
    • WO2022112932A1
    • 2022-06-02
    • PCT/IB2021/060847
    • 2021-11-23
    • ENI S.P.A.
    • ABBONDANZA, LuigiSCHIMPERNA, GiulianaTACCA, Alessandra
    • H01M8/18H01M10/627
    • Non-aqueous redox flow battery (RFB) comprising: - a positive compartment in which a positive electrode is placed and in which a non-aqueous liquid positive electrolyte is made to flow; - a negative compartment in which a negative electrode is placed and in which a non-aqueous liquid negative electrolyte is made to flow; - an ion exchange membrane placed between the positive compartment and the negative compartment; wherein: - said non-aqueous liquid positive electrolyte comprises a solution of copper triflate or tetrafluoroborate complexes [Cu(I) or Cu(II)] in at least one organic solvent; - said non-aqueous liquid negative electrolyte comprises a solution of at least one benzothiadiazole having general formula (I): wherein: - R1 and R2, equal or different from each other, represent a hydrogen atom; or represent a C1-C20 alkyl group, preferably C1-C10, linear or branched, saturated or unsaturated; or represent a -O-R3 group wherein R3 is selected from C1-C20 alkyl groups, preferably C1-C10, linear or branched, saturated or unsaturated, or R3 is selected from -(CH2)nCOOR4 groups wherein R4 is selected from C1-C20 alkyl groups, preferably C1-C10, linear or branched, saturated or unsaturated, and n is an integer comprised between 1 and 10, preferably comprised between 1 and 8, or R3 is selected from -(CH2)nOR4 groups wherein R4 and n have the same meanings reported above, or R3 is selected from -(CH2CH2O)nR4 groups wherein R4 and n have the same meanings reported above, or R3 is selected from -(CH2)nCN groups wherein n has the same meanings reported above, or R3 is selected from -(CH2)nNR4R5 groups wherein R4 and n have the same meanings reported above and R5 is selected from C1-C20 alkyl groups, preferably C1-C10, linear or branched, saturated or unsaturated, or R3 is selected from -(CH2)nCONR4R5 groups wherein R4, R5 and n have the same meanings reported above, or R3 is selected from -(CH2)nSi(R4)3 groups wherein R4 and n have the same meanings reported above, or R3 is selected from -(CH2)nSi(OR4)3 groups wherein R4 and n have the same meanings reported above; provided that at least one of R1 and R2 is different from hydrogen and at least one of R1 and R2 is in position 2 of the phenyl; in at least one organic solvent. Said non-aqueous redox flow battery (RFB) can be advantageously used in devices that require medium to high power output (e.g., about 10 kW - 100 MW) for several hours (i.e. > 1 hour) such as, for example, devices for storing energy from industrial plants or from alternative energy sources (such as solar or wind power) for later use (for example, for civil or industrial uses such as, for example, domestic or commercial use) or for sale.