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    • 3. 发明申请
    • PROCESS FOR THE SELECTIVE RECOVERY OF TRANSITION METALS FROM ORGANIC RESIDUES
    • WO2020121220A1
    • 2020-06-18
    • PCT/IB2019/060668
    • 2019-12-11
    • ENI S.P.A.
    • GUIDETTI, StefaniaDE ANGELIS, Alberto Renato
    • B01D11/04C10G21/27C10G21/28C10G67/04C10C1/18C10C3/08C10C3/10B01D9/00
    • The present invention relates to a process for the selective recovery of transition metals from an organic stream containing transition metals. The organic stream and possibly a first extractor if solid, are melted up to the liquid state. The extractor consists of an ionic liquid or a mixture of two or more ionic liquids, wherein said ionic liquid contains an ammonium salt as cation and as anion an anion with chelating properties. A melted organic stream and a first extractor, optionally melted, are fed to a first liquid-liquid extraction unit working at a temperature of at least 150 °C where the liquid-liquid extraction is carried out obtaining a liquid mixture containing an ionic liquid, or a mixture of two or more ionic liquids, and metals. After extraction, the liquid mixture is cooled at a temperature between 0 °C and 70 °C and becomes biphasic; then the cooled mixture is sent to a first separation unit, to separate a liquid phase that contains ionic liquids and metals, and a metal-depleted solid phase. After the first separation, the separated metal-depleted solid phase is optionally sent to a washing unit to which a solvent is fed, so as to eliminate the residual ionic liquid by transferring it into the solvent and obtaining a metal-depleted solid phase. Then the separate liquid phase containing ionic liquids and metals is sent into a liquid-liquid precipitation and separation unit, adding a counter-solvent, thereby obtaining a solid phase containing the metals and a liquid stream containing counter-solvent and ionic liquids.
    • 4. 发明申请
    • PROCESS FOR POLYMER MIXTURE HYDROCONVERSION
    • WO2020129020A1
    • 2020-06-25
    • PCT/IB2019/061213
    • 2019-12-20
    • ENI S.P.A.VERSALIS S.P.A.
    • BALDUCCI, DanieleGUIDETTI, StefaniaSCAVELLO, FrancescoVECCHINI, NicolaMARIANI, Paolo
    • C10G1/00C10G1/08C10G1/10C10G47/02C10G47/26
    • The present invention relates to a process for the hydroconversion of mixtures of polymers or plastics which comprises the pre-treatment of the mixtures through methods selected from mechanical methods, chemical methods, thermal methods, or combinations thereof forming a pre-treated charge. The pre-treated charge is mixed with a hydrocarbon vacuum residue, optionally pre-heated, to form a reactant mixture. The reactant mixture is fed to a hydroconversion section in slurry phase, together with a catalyst precursor containing Molybdenum, and a stream containing hydrogen, forming a reaction effluent. The effluent is separated into at least one high-pressure and high-temperature separator in a vapour phase and a slurry phase. The separate vapour phase is sent to a gas treatment section with the function of separating a liquid fraction from the gas containing hydrogen and hydrocarbon gases having from 1 to 4 carbon atoms; said liquid fraction comprising naphtha, atmospheric gas oil (AGO), vacuum gas oil (VGO). The slurry phase is then sent to a separation section that has the function of separating the fractions of the Vacuum Gas Oil (VGO), Heavy Vacuum Gas Oil (HVGO), Light Vacuum Gas Oil (LVGO), Atmospheric Gas Oil (AGO), from a stream of heavy organic products which contains asphaltenes, unconverted charge, catalyst and solid formed during the hydroconversion reaction. This stream of heavy organic products is partly recirculated to the hydroconversion section and partly forms a purge stream.